Chirals: are the ones that if we take the mirror image it would be different in some way
Achirals: are objects that have a plane of simmetry and the mirror image is the same
chirals: the roll of tape, the screw (the threads go to the right if you take a mirror image of it it will go the left) The interior of the human body (heart is at the left and the liver is at the right if you take the mirror image you will have the opposite)
achirals: nail and the exterior of human body (mirror image is exactly the same, even though the hands are chirals if you take the mirror of all the exterior of the human body you will get another body with 1 right hand and 1 left hand and so on)
The human body is achiral and meso, hands are chiral, feet are chiral... but the whole human body is achiral (the mirror image is the same)
Hands and gloves are chiral
a regular glass of water is achiral
3. Consider the real world objects below exterior interior of human of human bod bod A...
please solve them clear & be sure thank you . 1. (21 points) Is the following compound a meso-compound? If yes, show it in 3D in the box below using wedged and dashed bonds to indicate the substituent bond direction and draw the internal mirror plane of symmetry (if any). (3 points) HOOC-CHOH-CHOH-COOH Draw the 3D structures of the stereoisomers of the compound above. Use wedged and dashed bonds to indicate the substituent bond direction in each stereoisomer. [Hint: if...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that are not mirror images can exist; these are called diastereoisomers. Within this general class, there are special types of stereoisomers that are always optically inactive and are called meso forms. Construct a model with four different colored balls about a carbon center. Construct another identical to the first and verify this by the superimposition test. Now remove the same colored balls, blue (C from...
3. Diastereomers and Meso Forms. When a molecule has two or more stereogenic centers, stereoisomers that are not mirror images can exist; these are called diastereoisomers. Within this general class, there are special types of stereoisomers that are always optically inactive and are called meso forms. Construct a model with four different colored balls about a carbon center. Construct another identical to the first and verify this by the superimposition test. Now remove the same colored balls, blue (C from...
Solve 12-14 12. Consider the molecule shown below. OH OH f. How many stereoisomers are possible? g. Draw each of these stereoisomers. h. Identify pairs of enantiomers and pairs of diastereomers. i. Build a model of the stereoisomer that has both OH groups pointing out. Also, build a model of the mirror image of this molecule. j. Do your two molecules represent enantiomers? Are they chiral? Fischer Projections 13. Build a model of 1-bromo-1-chloroethane. a. Draw a3D representation of this...
3. Cyclic compounds The presence of the ring in all but very large ring cyclic molecules prevents full rotation of the ring atoms. For this reason, stereoisomerism may also occur in cyclic molecules. a) Prepare a model of cyclohexane, C6H12. Draw the condensed formula. b) Build a model of methylcyclohexane (C7H14) by replacing one of the hydrogens of cyclohexane with a methyl group. Draw the skeletal formula for methylcyclohexane. 2 c) How many different isomers exist for methylcyclohexane (CyH34)? d)...
A. Enantiomers: Certain substances have the unique property of rotating the plane of plane-polarized light. Such light rotation is detectable with the aid of a polarimeter. In order for a molecule to be optically active it must be chiral. Chiral objects lack a plane of symmetry and are non-superimposable on their mirror images. A sp?- hybridized carbon atom can fulfill these requirements if all four of its substituents are different. 1. Methane a) Prepare a methane molecule and then substitute...
19-26 thanks! 19-29* PART 3: 2,3-BUTANEDIOL CH-CH(OH)-CH(OH)-CH, mirror images, not superimposable Build as many models of 2,3-butanediol as you can. First, attach two carbons with a single bond. To each carbon add one carbon, one hydrogen, and one oxygen. To complete the structure, Ti the remaining hydrogen atoms. Remember, a model is not different if it is completely superimposable on one already constructed! 13. How many stereochemically different models are possible for 2,3-butanediol? 14. What characteristic does one of these...
PLEASE HELP WITH ALL. A. Which of the following Newman projections would represent the least stable conformer of 2,2,3.3-tetramethylbutane, looking down the 2,3 bond? H3C H3C H3C H3C CH3 b) CH3 H3C e) a) c) CH3 H3C CH3 CH CH3 CH о он B. which one of the following compounds would be chiral? Br он о он a) но HO O он HO C C. which of the following could potentially be used to distinguish between enantiomers? b) NMR c)...
Please complete for Tuesday, we will go through the questions and mark them in class. pg 156 - 4.23, 4.24, 4.26 pg 170 - 4.29, 4.31, pg 171-4.36 pg 175 - 4.59 pg 176- 4.74, 4.75, 4.80 pg 177-4.81, 4.82 pg 188- 5.1, 5.4, 5.5, 5.6, 5.11 - Using Table 5.1 pg 198-5.22, 5.25 pg 203 - 5.29 pg 206 - 5.37 pg 209 - 5.39 pg 2.14 5.61 pg 235-6.11, 6.14, 6.16 156 CHAPTER 4 Introduction to Organic Compounds...