Question

1. Name the following molecules: a) [PtBr(NH3)3]I3 b) [Ir(CO)2(OH)2]Cl c) K2[FeCl4(NO3)2] d) [((CH3)3N)3PdBr]Cl e) CoCl3H(dabco)2 2....

1. Name the following molecules:

a) [PtBr(NH3)3]I3

b) [Ir(CO)2(OH)2]Cl

c) K2[FeCl4(NO3)2]

d) [((CH3)3N)3PdBr]Cl

e) CoCl3H(dabco)2

2. Draw and give the point group for all the geometrical isomers of a molecule with the general formula:

a) MA2B2 (square planar and tetrahedral)

b) MA2B (“T”‐shaped and trigonal planar)

c) MAB4 (trigonal bipyramidal and square pyramidal)

d) MA2B3 (trigonal bipyramidal and square pyramidal)

4. Draw four distinct geometrical isomers of a metal complex of the type M(A‐CH2‐CH2‐B)2. Which of these is chiral? Give supporting evidence for each isomer considered.

(Note: The ligand is bidentate. Also, please ignore the detail in the CH2‐CH2 chain).

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Answer #1

The names of the given compounds is per (NH3 )3J1,-Tnamminebrom oplatímum (П)iodide [1r(CO)2 (OH)2ja-dicarbonyl di hydrox oin

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1. Name the following molecules: a) [PtBr(NH3)3]I3 b) [Ir(CO)2(OH)2]Cl c) K2[FeCl4(NO3)2] d) [((CH3)3N)3PdBr]Cl e) CoCl3H(dabco)2 2....
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