Benzene reacts in step 1 with 4-chlorobutanoyl chloride in the presence of aluminum chloride. The product of this reaction (P1) reacts then with a mixture of nitric and sulfuric acid. What is the main product formed in this reaction sequence?
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Benzene reacts in step 1 with 4-chlorobutanoyl chloride in the
presence of aluminum chloride. The product...
How would you perform the following multistep synthesis ? Benzene to 1,3,5-trimethyl benzene Step 1 HBr,...
How would you perform the following multistep synthesis ? Benzene to 1,3,5-trimethyl benzene Step 1 HBr, Step 2 Sodium ethoxide, Ethanol, Step 3 Thionyl Chloride, Step 4 KOH Step 1 NaOH, Step 2 Water, Sulfuric acid, Mercury sulfate Step 1 HNO3/H2SO4, Step 2 Sn, HCl followed by NaOH, Step 3 3moles CH3Br, AICI3 b) Step 4 NaNO2, H2SO4, Step 5 Ethanol Step 1 3moles CH3B, AIC13, Step2 HNO3/H2SO4, Step 3 NVH2, Step 4 NaNO2, H2SO4, Step 5 Ethanol, 3Moles CH3Br,...
1. Predict the major products formed when benzene reacts with the following reagents. (a). tert-butyl bromide,...
1. Predict the major products formed when benzene reacts with the following reagents. (a). tert-butyl bromide, ALCl3 (b) bromine + a nail (c) iodine + HNO3 (d) carbon monoxide, HCl, and AlCl3/CuCl (e) nitric acid + sulfuric acid. 2. Predict the major products of the following reactions. (a.) nitrobenzene + ethyl chloride/AlCl3 (b). p-methylanisole + acetyl chloride + AlCl3 (c). nitrobenzene + fuming sulfuric acid (d) benzene + CH3CH2COCl in the presence of (1) ALCl3 followed by...
5) When benzene reacts with isopropyl chloride in the presence of AlCl3, a compound with a...
5) When benzene reacts with isopropyl chloride in the presence of AlCl3, a compound with a molecular mass of 162 g/mol is isolated. In HNMR, this compound has the following spectrum. What is it and why is it formed? PPM
3. Aluminum chloride reacts with sulfuric acid to form aluminum sulfate and hydrochloric acid according to...
3. Aluminum chloride reacts with sulfuric acid to form aluminum sulfate and hydrochloric acid according to the balanced chemical equation below. 2A1C13(aq) + 3H2SO4(aq) → Al2(SO4)3(aq) + 6HCl(aq) 133.340 g/mol 98.079 g/mol 342.150 g/mol 36.460 g/mol Molar Masses: a) How many grams of sulfuric acid react with 25.0 grams of aluminum chloride? b) What is the theoretical yield of HCl if sulfuric acid is in excess?
5) Sulfuric acid reacts with nitric acid as shown to form the nitronium ion. HNO3 (aq)...
5) Sulfuric acid reacts with nitric acid as shown to form the
nitronium ion.
HNO3 (aq) + 2H2SO4 (aq) --->
NO2+ (aq) + H3O+ (aq) +
2HSO4- (aq)
Part 2 (1 point)
Identify the acid and conjugate base in the reaction. (Hint:
Draw the Lewis structures for each.)
Choose one:H2SO4/H3O+
HNO3/H3O+
HNO3/H2SO4
HNO3/HSO4-
H2SO4/NO2+
H2SO4/HSO4-
HNO3/NO2+
Part 3 (1 point)
Identify the base and conjugate acid in the reaction. (Hint:
Draw the Lewis structures for each.)
Choose one:HNO3/H2SO4
HNO3/HSO4-
HNO3/NO2+
H2SO4/H3O+
H2SO4/NO2+...
Are these right? 18.-22. Starting with benzene, what is the major product of each reaction sequence?...
Are these right?
18.-22. Starting with benzene, what is the major product of each reaction sequence? Answer may be repeated. 18. /AICI3, Cl2/Fecla, H2NNH2/ OH 19. Cl2/Fecla, /AICI b. 20 /AICI 3, HS (CH2)2SH/H", H2/Ni, cl2/Fecl3 21. HNO3/ H2SO4, /AICI 3, H2/Pd, NaNO2/HCI, Cuc 22. /AICI3, Zn/HCI, H2SO4, Cl2/FeCla, H20 e. not a.-d.
2,2-dimethylpropanoyl chloride reacts with 4-methylpentanoic acid in the presence of pyridine. (a) Draw the skeletal structure...
2,2-dimethylpropanoyl chloride reacts with 4-methylpentanoic acid in the presence of pyridine. (a) Draw the skeletal structure of the major organic product resulting from this reaction. Marvin JS Help Edit drawing
What reagents would be necessary to produce the following product from benzene? 06:42 Multiple Choice CH3CI,...
What reagents would be necessary to produce the following product from benzene? 06:42 Multiple Choice CH3CI, AICI3 2. HNO3 H2SO4 3. KMnO4 O KMNO4 2. CH3CI, AICI3 3. HNO3. H2804 O KMnO4 2. HNO3, H2S04 3.CHZCI, AICI3 HNO3, H2SO4 2. CH3CI, AICI3 3. KMnO4 < Prev 71 of 81 Next >
Question 28 (4 points) The product formed by the following reaction sequence is 1) C12, AIC13...
Question 28 (4 points) The product formed by the following reaction sequence is 1) C12, AIC13 2) HNO3/H2SO4 3) Fe, HCI 4) NaNO2, HCI 5) KCN CI CN NH2 CI CN O CI NH2
Show in step-by-step detail the mechanism by which: either toluene is nitrated by nitric acid, HNO3,...
Show in step-by-step detail the mechanism by which: either toluene is nitrated by nitric acid, HNO3, in the presence of sulfuric acid catalyst, H2S04; or acetone (2-propanone) is converted to an imine by reaction with ethylamine, CH3CH2NH, in aqueous buffer.
How would you perform the following multistep synthesis ? Benzene to 1,3,5-trimethyl benzene Step 1 HBr, Step 2 Sodium ethoxide, Ethanol, Step 3 Thionyl Chloride, Step 4 KOH Step 1 NaOH, Step 2 Water, Sulfuric acid, Mercury sulfate Step 1 HNO3/H2SO4, Step 2 Sn, HCl followed by NaOH, Step 3 3moles CH3Br, AICI3 b) Step 4 NaNO2, H2SO4, Step 5 Ethanol Step 1 3moles CH3B, AIC13, Step2 HNO3/H2SO4, Step 3 NVH2, Step 4 NaNO2, H2SO4, Step 5 Ethanol, 3Moles CH3Br,...
5) When benzene reacts with isopropyl chloride in the presence of AlCl3, a compound with a molecular mass of 162 g/mol is isolated. In HNMR, this compound has the following spectrum. What is it and why is it formed? PPM
3. Aluminum chloride reacts with sulfuric acid to form aluminum sulfate and hydrochloric acid according to the balanced chemical equation below. 2A1C13(aq) + 3H2SO4(aq) → Al2(SO4)3(aq) + 6HCl(aq) 133.340 g/mol 98.079 g/mol 342.150 g/mol 36.460 g/mol Molar Masses: a) How many grams of sulfuric acid react with 25.0 grams of aluminum chloride? b) What is the theoretical yield of HCl if sulfuric acid is in excess?
5) Sulfuric acid reacts with nitric acid as shown to form the
nitronium ion.
HNO3 (aq) + 2H2SO4 (aq) --->
NO2+ (aq) + H3O+ (aq) +
2HSO4- (aq)
Part 2 (1 point)
Identify the acid and conjugate base in the reaction. (Hint:
Draw the Lewis structures for each.)
Choose one:H2SO4/H3O+
HNO3/H3O+
HNO3/H2SO4
HNO3/HSO4-
H2SO4/NO2+
H2SO4/HSO4-
HNO3/NO2+
Part 3 (1 point)
Identify the base and conjugate acid in the reaction. (Hint:
Draw the Lewis structures for each.)
Choose one:HNO3/H2SO4
HNO3/HSO4-
HNO3/NO2+
H2SO4/H3O+
H2SO4/NO2+...
Are these right?
18.-22. Starting with benzene, what is the major product of each reaction sequence? Answer may be repeated. 18. /AICI3, Cl2/Fecla, H2NNH2/ OH 19. Cl2/Fecla, /AICI b. 20 /AICI 3, HS (CH2)2SH/H", H2/Ni, cl2/Fecl3 21. HNO3/ H2SO4, /AICI 3, H2/Pd, NaNO2/HCI, Cuc 22. /AICI3, Zn/HCI, H2SO4, Cl2/FeCla, H20 e. not a.-d.
2,2-dimethylpropanoyl chloride reacts with 4-methylpentanoic acid in the presence of pyridine. (a) Draw the skeletal structure of the major organic product resulting from this reaction. Marvin JS Help Edit drawing
What reagents would be necessary to produce the following product from benzene? 06:42 Multiple Choice CH3CI, AICI3 2. HNO3 H2SO4 3. KMnO4 O KMNO4 2. CH3CI, AICI3 3. HNO3. H2804 O KMnO4 2. HNO3, H2S04 3.CHZCI, AICI3 HNO3, H2SO4 2. CH3CI, AICI3 3. KMnO4 < Prev 71 of 81 Next >
Question 28 (4 points) The product formed by the following reaction sequence is 1) C12, AIC13 2) HNO3/H2SO4 3) Fe, HCI 4) NaNO2, HCI 5) KCN CI CN NH2 CI CN O CI NH2
Show in step-by-step detail the mechanism by which: either toluene is nitrated by nitric acid, HNO3, in the presence of sulfuric acid catalyst, H2S04; or acetone (2-propanone) is converted to an imine by reaction with ethylamine, CH3CH2NH, in aqueous buffer.
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