1.) a) molar mass of NaHCO3=23+1+12+16*3=84 g/mol
b) molar mass of Na2CO3 =23*2+12+16*3=106 g/mol
c) molar mass of H2CO3=2*1+12+16*3=62 g/mol
2.) Reaction of thermal decomposition of NaHCO3:
2 NaHCO3=Na2CO3+H2O+CO2.
2 mole NaHCO3 produces 1 mole of Na2CO3.
2.765 g NaHCO3=2.765/84=0.03292 mole.
1.234 g Na2CO3=1.234/106=0.01164 mole.
Theoretically, 0.03292 mole NaHCO3 should produce 0.03292/2 mole=0.01646 mole Na2CO3.
So, theoretical yield=0.01646 mole=0.01646*106 g=1.745 g.
% yield=(1.234)*100/1.745 %=70.7 %.
3.) 84*2=168 g NaHCO3 yields 106 g Na2CO3. (Other products are in not solid) So, loss of mass for 168 g NaHCO3 decomposition is (168-106) g=62 g. Therefore, 0.453 g loss is for( 168/62)*0.453=1.23 g NaHCO3.
% of NaHCO3 in mixture of 2.968 g=(1.23/2.968)*100%=41.4%
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