Using your infrared spectrum, determine the structure of the oxidation product. Is the oxidation selective? Did the hypochlorite oxidize both alcohol functional groups? If the oxidation was selective, which functional group was transformed?
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Using your infrared spectrum, determine the structure of the
oxidation product. Is the oxidation selective? Did...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
Experiment 8 - Addition to Alkenes What is Markovnikov's Rule? Chem 2321 In this experiment you...
Experiment 8 - Addition to Alkenes What is Markovnikov's Rule? Chem 2321 In this experiment you will synthesize a brom ohydrin according to the reaction shown below. Using infrared (IR) spectroscopy and a simple chemical test, you will determine which product (Markovnikov or anti-Markovnikov) is formed. N-bromosuccinimide Br (NBS) но or н.о, THF ""сн, он "Br CH3 CH3 1-methylcyclohexene Markovnikov product anti-Markovnikov product Halogenation of alkenes is an important reaction in organic chemistry. When carried out in an aqueous solution,...
Butanone is formed by oxidation of Butan-2-ol using acidified potassium dichromate (VI) as shown by the...
Butanone is formed by oxidation of Butan-2-ol using acidified potassium dichromate (VI) as shown by the following equation. CH:CH-CH(OH)CH3 + [0] → CH3CH,COCH3 + H2O (a) Is butan-2-ol Primary, secondary or tertiary alcohol? Explain your answer. (2) (b) Look at the infrared spectrum below and see whether the compound is butanone or butan-2-ol. Use your knowledge of spectroscopy to identify and explain your answer(3) Table A Infrared absorption data Bond Wavenumber Icm-1 N-H 3300-3500 (amines) O-H 3230-3550 (alcohols) C-H 2850-3300...
which of the following is the structure of 2-ethylbenzamide 3. (20 points) The following alcohol undergo...
which of the following is the structure of
2-ethylbenzamide
3. (20 points) The following alcohol undergo chromic acid test. Complete the blank for each alcohol Color after reaction is test positive or negative? Class of Alcohol CH₂ - CHCH, CH, CH, ан,— —днан, Color after reaction is test positive or negative? Class of Alcohol Color after reaction is test positive or negative? Class of Alcohol at CH2OH & CH₂ CH3 6th c Color after reaction is test positive or negative?...
INFRARED SPECTROSCOPY 1. Circle AND label the functional groups in each molecule. Then predict the signal(s)...
INFRARED SPECTROSCOPY
1. Circle AND label the functional groups in
each molecule. Then predict the signal(s) that
would result from each functional group in the IR.
PLEASE ANSWER (C) and (D please follow the directions
and write neatly
Но, ес -CEC-H Infrared Absorption Bands Type of Vibration Frequency (cm21) Intensity C-H Alkanes CH CH- Alkenes (stretch) (bend) (bend) (stretch) (out-of-plane bend) (stretch) (out-of-plane bend) (stretch) Aromatics 3000-2850 1450 and 1375 1465 3100-3000 1000-650 3150-3050 900-690 ca. 3300 2900-2800 2800-2700 Alkyne...
AUS. I 3. Compare glycerol with ethanol. a. They both contain 3 carbons in the skeleton....
AUS. I 3. Compare glycerol with ethanol. a. They both contain 3 carbons in the skeleton. b. They both have the hydroxy on an interior carbon. Glycerol is a long chain alcohol; ethanol is a short chain alcohol. d. Glycerol is a triol; ethanol is not a triol. Ans: C 4. What is the correct IUPAC name for the following compound? CH3CH2CHCH2 CH3 CH2 он a. 3-methylpentanol b. 2-ethyl-1-butanol C. 2-ethylbutanol d. 1-ethyl-2-butanol Ans: 5. What is the correct IUPAC...
____ 1. The diagram below represents serine, a polar, uncharged amino acid. Which functional group gives...
____ 1. The diagram below represents serine, a polar, uncharged
amino acid. Which functional group gives serine its
distinct property?
a. H3
b. CH2OH
c. –H
d. COO–
____ 2. The monomers shown below are monomers for which of the
following natural polymers?
a. polysaccharides
b. plastics
c. DNA
d. proteins
____ 3. Which of the following processes illustrates the production
of a protein?
a. specific code for amino acids --> amino acid chain -->
gene --> DNA --> specific...
Which is the correct name for 2-3-iedopentan-2-alb-2-ledopeatan-3-one .B.Iodopentan-2-one 4-2-iodopentanal FLED THIS Which is the correct name...
Which is the correct name for 2-3-iedopentan-2-alb-2-ledopeatan-3-one .B.Iodopentan-2-one 4-2-iodopentanal FLED THIS Which is the correct name for a 2-lodobutan-3-al b-3-lodobutan-2-one c-2-lodobutan-3-one d-3-lodobutan-2-al Which is the correct name for? -butanone d-methylpropanal a ethylpropanalb-propanone 9. Which is the correct name for CH3CH2COCH2CH32 diethyl ketone b-pentan-4-one c-pentan-3-al d-pentan-3-one c.pentan-2-one 10 Which is the correct name for - CH3CH03 -ethanal a. Ethone b-ethanol c-vinger d-ketanal ICH-CH2-C-CH2-CH3 Which is the correct name for a. 5-iodopentan-2-one b. 1-iodopentan-2-one c-1-iodopentan-3-one d-5-iodopentan-3-one 12. Which of the following properly...
PART 1 - For the following compounds A. Predict how many signals would be detected in...
PART 1 - For the following compounds A. Predict how many signals would be detected in the expected 'H NMR spectrum. B. Label proton groups and determine their multiplicity. c. Predict the chemical shifts of each signal in the expected 'H NMR spectrum of the following compounds from the correlation chart in the last page. <Example> Number of signals O Proton groups Multiplicity Triplet B Multiplet (sextet) c Triplet D Singlet Chemical Shirt (ppm) 0.8-1.0 1.2 - 1.5 3.2 4.0...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
ChemActivity 10: Oxidation and Reduction 145 Model 7: Primary (1°), Secondary (2°), and Tertiary (3°) Carbons The words methyl (0'), primary (1), secondary (2"), and tertiary (3) were used to describe the number of (nonhydrogen) R groups attached to a carbocation carbon (see CA 8). This same naming strategy is used to describe any carbon with one attached "heteroatom," Z (hetero other). H R Z any atom other than C or H (hetroatom) R- -z -Z н- alkyl (not H)...
Experiment 8 - Addition to Alkenes What is Markovnikov's Rule? Chem 2321 In this experiment you will synthesize a brom ohydrin according to the reaction shown below. Using infrared (IR) spectroscopy and a simple chemical test, you will determine which product (Markovnikov or anti-Markovnikov) is formed. N-bromosuccinimide Br (NBS) но or н.о, THF ""сн, он "Br CH3 CH3 1-methylcyclohexene Markovnikov product anti-Markovnikov product Halogenation of alkenes is an important reaction in organic chemistry. When carried out in an aqueous solution,...
Butanone is formed by oxidation of Butan-2-ol using acidified potassium dichromate (VI) as shown by the following equation. CH:CH-CH(OH)CH3 + [0] → CH3CH,COCH3 + H2O (a) Is butan-2-ol Primary, secondary or tertiary alcohol? Explain your answer. (2) (b) Look at the infrared spectrum below and see whether the compound is butanone or butan-2-ol. Use your knowledge of spectroscopy to identify and explain your answer(3) Table A Infrared absorption data Bond Wavenumber Icm-1 N-H 3300-3500 (amines) O-H 3230-3550 (alcohols) C-H 2850-3300...
which of the following is the structure of
2-ethylbenzamide
3. (20 points) The following alcohol undergo chromic acid test. Complete the blank for each alcohol Color after reaction is test positive or negative? Class of Alcohol CH₂ - CHCH, CH, CH, ан,— —днан, Color after reaction is test positive or negative? Class of Alcohol Color after reaction is test positive or negative? Class of Alcohol at CH2OH & CH₂ CH3 6th c Color after reaction is test positive or negative?...
INFRARED SPECTROSCOPY
1. Circle AND label the functional groups in
each molecule. Then predict the signal(s) that
would result from each functional group in the IR.
PLEASE ANSWER (C) and (D please follow the directions
and write neatly
Но, ес -CEC-H Infrared Absorption Bands Type of Vibration Frequency (cm21) Intensity C-H Alkanes CH CH- Alkenes (stretch) (bend) (bend) (stretch) (out-of-plane bend) (stretch) (out-of-plane bend) (stretch) Aromatics 3000-2850 1450 and 1375 1465 3100-3000 1000-650 3150-3050 900-690 ca. 3300 2900-2800 2800-2700 Alkyne...
AUS. I 3. Compare glycerol with ethanol. a. They both contain 3 carbons in the skeleton. b. They both have the hydroxy on an interior carbon. Glycerol is a long chain alcohol; ethanol is a short chain alcohol. d. Glycerol is a triol; ethanol is not a triol. Ans: C 4. What is the correct IUPAC name for the following compound? CH3CH2CHCH2 CH3 CH2 он a. 3-methylpentanol b. 2-ethyl-1-butanol C. 2-ethylbutanol d. 1-ethyl-2-butanol Ans: 5. What is the correct IUPAC...
____ 1. The diagram below represents serine, a polar, uncharged
amino acid. Which functional group gives serine its
distinct property?
a. H3
b. CH2OH
c. –H
d. COO–
____ 2. The monomers shown below are monomers for which of the
following natural polymers?
a. polysaccharides
b. plastics
c. DNA
d. proteins
____ 3. Which of the following processes illustrates the production
of a protein?
a. specific code for amino acids --> amino acid chain -->
gene --> DNA --> specific...
Which is the correct name for 2-3-iedopentan-2-alb-2-ledopeatan-3-one .B.Iodopentan-2-one 4-2-iodopentanal FLED THIS Which is the correct name for a 2-lodobutan-3-al b-3-lodobutan-2-one c-2-lodobutan-3-one d-3-lodobutan-2-al Which is the correct name for? -butanone d-methylpropanal a ethylpropanalb-propanone 9. Which is the correct name for CH3CH2COCH2CH32 diethyl ketone b-pentan-4-one c-pentan-3-al d-pentan-3-one c.pentan-2-one 10 Which is the correct name for - CH3CH03 -ethanal a. Ethone b-ethanol c-vinger d-ketanal ICH-CH2-C-CH2-CH3 Which is the correct name for a. 5-iodopentan-2-one b. 1-iodopentan-2-one c-1-iodopentan-3-one d-5-iodopentan-3-one 12. Which of the following properly...
PART 1 - For the following compounds A. Predict how many signals would be detected in the expected 'H NMR spectrum. B. Label proton groups and determine their multiplicity. c. Predict the chemical shifts of each signal in the expected 'H NMR spectrum of the following compounds from the correlation chart in the last page. <Example> Number of signals O Proton groups Multiplicity Triplet B Multiplet (sextet) c Triplet D Singlet Chemical Shirt (ppm) 0.8-1.0 1.2 - 1.5 3.2 4.0...
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