12
34
5
Problem 3: (40 points) One-dimensional relativistic gas: Here we consider a non-interacting gas of N relativistic...
Consider a two-dimensional non-interacting and non-relativistic gas of N spin-1/2 fermions at T 0 in a box of area A. (a) Find the Fermi energy εF. (b) Show that the total energy is given by E- NE. 2
Pb2. Consider the case of a canonical ensemble of N gas particles confined to a t rectangular parallelepiped of lengths: a, b, and c. The energy, which is the translational kinetic energy, is given by: o a where h is the Planck's constant, m the mass of the particle, and nx, ny ,nz are integer numbers running from 1 to +oo, (a) Calculate the canonical partition function, qi, for one particle by considering an integral approach for the calculation of...
3. Consider an ideal gas of N particles, each of mass M, confined to a one- dimensional line of length a. Find the entropy at temperature T 3. Consider an ideal gas of N particles, each of mass M, confined to a one- dimensional line of length a. Find the entropy at temperature T
Problem 4. Low-dimensional materials play an important role in nanotechnology. Consider a two-dimensional Fermi gas of N non-interacting electrons confined to a plane of area A. Find the Fermi energy &r (in terms of A and N) and the average electron energy. Find (analytically) the chemical potential p as a function of er and T.
(80 pts) Entropy of the ideal gas: Consider a monatomic gas of identical non-interacting particles of mass m. The kinetic energy of each particle is given in terms of its momentum p by Ekinp2/(2m). For a given total energy U, volume V and total particle number N (with N » 1) calculate the entropy S(U, V,N)-klog Ω(U, V,N), where Ω(U, V,N) counts the number of different microscopic configurations for given N, U and V. To get a finite number for...
Consider N non-interacting electrons confined to a two-dimensional square well of dimensions a × a. Derive an expression for the Fermi energy of this system in terms of the areal density σ = N/a2 and calculate the corresponding density of states. Show all steps.
Consider translational motion of single molecule (mass = 5.314 * 10-26 kg) trapped in one-dimensional box potential ("particle in a box), which has a width of 5 cm. A) What is the energy difference between the two lowest quantized energy levels? B) The amount of classical translational thermal energy for a molecule confined in one dimension is 1/2kT where T is the temperature and k is the Boltzmann constant (1.381 * 10-23 J/K). If the temperature is 300 K, at...
1-r' Problem 16.12 (30 pts) This chapter examines the two-state system but consider instead the infinite-state system consisting of N non-interacting particles. Each particle i can be in one of an infinite number of states designated by an integer, n; = 0,1,2, .... The energy of particle i is given by a = en; where e is a constant. Note: you may need the series sum Li-ori = a) If the particles are distinguishable, compute QIT,N) and A(T,N) for this...
1 The Gibbs Paradox Consider N particles, each of mass m, in a 3-dimensional volume V at temperature T. Each particle i has momentum pi. Assume that the particles are non-interacting (ideal gas) and distinguishable. a) (2P) Calculate the canonical partition function N P for the N-particle system. Make sure to work out the integral. b) (2P) Calculate the free energy F--kBTlnZ from the partition function Z. Is F an extensive quantity? c) (2P) Calculate the entropy S F/oT from...
Problem C The partition function for an ideal gas is given by integrating over all possible position and momen- tum configurations, weighted by a Boltzmann factor, for each particle (6 integrals per particle over z, v, z, pz, py, pz _ each running from-oo to +oo) and multiplying all N of these together (the factor of h is included to cancel the dimensions of dpdr; the factor of N! is included to divide out the multiplicity of particle-particle exchange) a)...