Question

Pb2. Consider the case of a canonical ensemble of N gas particles confined to a t rectangular parallelepiped of lengths: a, b, and c. The energy, which is the translational kinetic energy, is given by: o a where h is the Plancks constant, m the mass of the particle, and nx, ny ,nz are integer numbers running from 1 to +oo, (a) Calculate the canonical partition function, qi, for one particle by considering an integral approach for the calculation of the series and using the following result 1 元 (b) Calculate the canonical partition function, Q, of a gas composed of N such indistinguishable particles. (c) Calculate the internal energy, U, of a gas composed of N such particles. (d) Calculate the free energy, A, of the gas. (e) Calculate the pressure, P, of the gas as a function of the volume. Compare the case of the equation of a perfect gas. (1 Calculate the entropy of the gas. Does the expression for the entropy satisfy the extensive nature of entropy?
0 0
Add a comment Improve this question Transcribed image text
Answer #1

DATE C PAGE Yoitonos ingle Pashe Paride » 2n2 76 ma ng dea rou qiveh in the quem gma2 2. 2 h 2 2. 2 3 212 2 ab( nWRITE2 DATE : 3 NI In 2 GOOD WRITEDATE PAGE onleunal en 스1 2 T 0111주 Avagadro No GOOD WRITEIf u find it helpful please rate it

Add a comment
Know the answer?
Add Answer to:
Pb2. Consider the case of a canonical ensemble of N gas particles confined to a t...
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for? Ask your own homework help question. Our experts will answer your question WITHIN MINUTES for Free.
Similar Homework Help Questions
  • 1. N identical particles of mass m is confined to move only about a surface of...

    1. N identical particles of mass m is confined to move only about a surface of area A, and thus can be considered as a “two-dimensional gas.” In the classical limit what is the single particle partition function of one of the particles in this ideal two-dimensional gas? What is the partition function of the N particle gas? What is the mean thermal energy of this gas, and what is the entropy of this gas?

  • Pls show full working thank you Problem 4.1 Ideal gas equation of state from the Grand...

    Pls show full working thank you Problem 4.1 Ideal gas equation of state from the Grand potential The Grand Canonical ensemble can make some calculations particularly simple. To derive the ideal gas equation of state, we first note that the canonical partition function of a set of N identical and indistinguishable particles is given by Z-z/N! , where z is the single particle partition function in the canonical ensemble a) Show that the Grand Canonical partition function is -žte®)" b...

  • 1 The Gibbs Paradox Consider N particles, each of mass m, in a 3-dimensional volume V at temperature T. Each particle i...

    1 The Gibbs Paradox Consider N particles, each of mass m, in a 3-dimensional volume V at temperature T. Each particle i has momentum pi. Assume that the particles are non-interacting (ideal gas) and distinguishable. a) (2P) Calculate the canonical partition function N P for the N-particle system. Make sure to work out the integral. b) (2P) Calculate the free energy F--kBTlnZ from the partition function Z. Is F an extensive quantity? c) (2P) Calculate the entropy S F/oT from...

  • Problem 3: (40 points) One-dimensional relativistic gas: Here we consider a non-interacting gas of N relativistic...

    Problem 3: (40 points) One-dimensional relativistic gas: Here we consider a non-interacting gas of N relativistic particles in one dimension. The gas is confined in a container of length L, i.e., the coordinate of each particle is limited to 0 <q < L. The energy of the ith particle is given by ε = c (a) Calculate the single particle partition function Z(T,L) for given energy E and particle number N. [12 points] (b) Calculate the average energy E and...

  • 3. It can be shown that the canonical partition function of an N-particle monatomic ideal gas con...

    Please be specific about the solution and thank you so much! 3. It can be shown that the canonical partition function of an N-particle monatomic ideal gas confined to a container of volume V at temperature T is given by 3 Use this partition function to derive an expression for the average energy and the constant- volume heat capacity of the monatomic ideal gas. Note that in classical thermodynamics these quantities were simply given. Your calculations show that these quantities...

  • 1. Quick Exercises (a) In lecture 15, we showed that the canonical partition function, Q, is...

    1. Quick Exercises (a) In lecture 15, we showed that the canonical partition function, Q, is related to the Helmholz free energy: A = -kTinQ. Using the fundamental thermo- dynamic relation of Helmheltz free energy i.e. dA = -SAT - PDV + pdN), express P, and p in terms of Q. (b) The canonical partition function for N non-interacting, indistinguishable parti- cles in volume V at temperature T is given by Q(N,V,T) = where where q(V.T) is the partition function...

  • 1. Quick Exercises (a) In lecture 15, we showed that the canonical partition function, Q, is related to the Helmhol...

    1. Quick Exercises (a) In lecture 15, we showed that the canonical partition function, Q, is related to the Helmholz free energy: A = -kTinQ. Using the fundamental thermo- dynamic relation of Helmheltz free energy (i.e. dA = -SIT - PdV + pdN), express P, and u in terms of Q. (b) The canonical partition function for N non-interacting, indistinguishable parti- cles in volume V at temperature T is given by Q(N, V,T) = where where 9(V, T) is the...

  • 1. Quick Exercises (a) In lecture 15, we showed that the canonical partition function, Q, is related to the Helmholz fr...

    1. Quick Exercises (a) In lecture 15, we showed that the canonical partition function, Q, is related to the Helmholz free energy: A = -kTinQ. Using the fundamental thermo- dynamic relation of Helmheltz free energy i.e. dA = -SAT - PDV + udN), express P, and u in terms of Q. (b) The canonical partition function for N non-interacting, indistinguishable parti- cles in volume V at temperature T is given by ON Q(N,V,T) = where where q(VT) is the partition...

  • Statistical_Mechanics 2 20 points) 2D ideal Fermi gas 24 Consider an ideal Fermi gas in 2D....

    Statistical_Mechanics 2 20 points) 2D ideal Fermi gas 24 Consider an ideal Fermi gas in 2D. It is contained in an area of dimensions L x L. The particle mass is m. (a) Find the density of states D(e) N/L2 (b) Find the Fermi energy as a function of the particle density n = (c) Find the total energy as a function of the Fermi energy ef. (d) Find the chemical potential u as a function of n and T....

  • min The grand canonical partition function ofan ideal gas is 3ega with q-( and λ-e".kr. Derive...

    min The grand canonical partition function ofan ideal gas is 3ega with q-( and λ-e".kr. Derive the entropy, pressure, number of particles, internal energy and heat capacity. Comment on the link between p and N. v

ADVERTISEMENT
Free Homework Help App
Download From Google Play
Scan Your Homework
to Get Instant Free Answers
Need Online Homework Help?
Ask a Question
Get Answers For Free
Most questions answered within 3 hours.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT