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Problem 4.1 Ideal gas equation of state from the Grand potential The Grand Canonical ensemble can make some calculations particularly simple. To derive the ideal gas equation of state, we first note that the canonical partition function of a set of N identical and indistinguishable particles is given by Z-z/N! , where z is the single particle partition function in the canonical ensemble a) Show that the Grand Canonical partition function is -žte®) b Use the Taylor series for an exponential to show c Then use pVkTInE and the expression for the average number of particles in the Grand Canonical ensemble to obtain the ideal gas equation of state.
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