Question

What are the equilibrium constant expressions (Kc) for the following reactions

1. Write the equilibrium constant expressions (Kc) for the following reactions:

(a)  CO (g)  +  H2O (g)     CO2 (g)  +  H2 (g)



(b)  CH4 (g)  +  2H2S (g)     CS2 (g)  +  4H2 (g)



(c)  COCl2 (g)     Cl2 (g)  +  CO (g)



(d)  2HI (g)     H2 (g)  +  I2 (g)



(e)  PCl3  +  Cl2 (g)     PCl5 (g)



(f)  2H2 (g)  +  O2 (g)     2H2O (l)



(g)  3Ca2+ (aq)  +  2PO43-   ⮂   Ca3(PO4)2 (s)



2. In what direction would the equilibrium be shifted if the following changes are made:

(a)  CO2 is added to reaction (a) in Question 1


(b)  COCl2 is added to reaction (c) in Question 1


(c)  PCl5 is removed from reaction (e) in Question 1


(d)  Partial pressure of CO (PCO) is reduced from reaction (c) in Question 1


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