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09. [16 marks; 2, 1,8,5] The phase diagram of bismuth and gold is given below. 1100 Liquid Solution L 700 E- CS: 1/°C L = Au(

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Answer #1

(a ) determining the formula of 'C' :

at this point: mole fraction 0.50 % Bi +  mole fraction 0.50 % Au

thus Au : Bi ratio : 1: 1

thus formula of 'C' : AuBi .

(b) area marked by 'X' : Bi(s) + L

(c) isolepth x(Au) : 0.45 ; 700 K :

  • at S : Liquid solution
  • S to T : on cooling at constant composition we towards two phase system
  • at T : it is phase change line : L ==> L <==> Au (s)
  • T to U : we further cooling at constant composition we towards another two phase system
  • at U :   it is phase change line : L <==> Au (s) ====> L <==> C (s)
  • U to V : we further cooling at constant composition we towards another two phase system
  • at V :   it is phase change line : L <==> C (s) ==> Bi(S) + C(s)
  • below V : two phases :  Bi(S) + C(s)
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