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Bond Dissociation Energies (for A-B Bond broken AH, kJ/mol Bond broken → A A4, kJ/mol + B) Bond broken mo H-H CH3CH2CH2-H (CH3)2CH-H (CH3)3C-H 436 423 413 400. H-Br 366 CH3CH2CH2-Br 294 (CH3)2CH-Br 298 (CH3)3C-Br292 Br-Br 193 H-CI 432 CH3CH2CH2-CI 354 (CH3)2CH-CI 355 (CH3)3C-CI 349 CI-CI 243 Alkane halogenation is a two-step reaction, as shown below. Using the table of bond dissociation energies, calculate the enthalpy of each step and the enthalpy of the overall reaction. Step 1: Number CH3CHCH3...
2). Consider the following intramolecular S2 reaction. no ♡ + HI A) (5 pts) Use the table of Bond Dissociation Enthalpies (at the back of the exam) to calculate the approximate ΔΗπη. B) (3 pts) Is the reaction endothermic or exothermic? Why? C) (6 pts) Draw the Reaction Energy Coordinate Diagram. Label the axes, reactant(s), product(s), transition state(s), intermediate(s), activation energy, and reaction enthalpy. D) (3 pts) In regards to entropy, would you expect the reaction to be favorable, or...
Predict the enthalpy (ΔH) value for the theoretical reaction below, and indicate whether it is endothermic or exothermic. The bond dissociation energy for each bond in Kcal/mol is shown below each reactant and product. (3p) A-B + C-D → A-C + B-D 63 88 47 96 A) +8 Kcal/mol, endothermic B) -8 Kcal/mol, exothermic C) +16 Kcal/mol, endothermic D) +8 Kcal/mol, exothermic
1. For the following substitution reaction, please (a) calculate the AHn. (b) Is this reaction an exothermic or endothermic process? (5 pts) Bond dissociation energies CH3 CH3 Н-с-он (CH3)2CH-Br 285 kJ/mol H-OH Н-с -Br Н-Bг (CH3)2CH-OH 401 kJ/mol CH3 CH3 H-OH 498 kJ/mol 368 kJ/mol Н-Вг
1. For the following substitution reaction, please (a) calculate the AHran. (b) is this reaction an exothermic or endothermic process? (5 pts) CHE CH3 H-C-Br + H-O-H + H-Br CHE н-с-он сн. Bond dissociation energies (CH3)2CH-Br 285 kJ/mol (CH),CH-OH 401 kJ/mol H-OH 498 kJ/mol H-Br 368 kJ/mol
1. Based on the following energy diagram: free energy, kJ/mol reaction coordinate C. D. The reaction is exothermic and the first step is rate limiting. The reaction is exothermic and the second step is rate limiting. The reaction is endothermic and the first step is rate limiting. The reaction is endothermic and the second step is rate limiting. The reaction is one step endothermic.
1) In the reaction of Cl2 with ethane and UV light, which of the following reactions would be a chain termination event(s)? 1) CI: + CH3-CH3 - CH3-CH2-CI+H II) CI+ CH3-CH3 CH3-H2C + HCI III) Cl. + CH3-H2C-CH3-CH2-CI IV) Cl2 + CH3-H2C - CH3-CH2-CI+CI- V) Cl2 + UV light -CI+CI: A) reaction V B) reactions I and IV C) reactions III and IV D) reactions I and II E) reaction III 2) Given the chlorination of acetone shown below, choose...
the answers i circled are incorrect except for 19. can you please tell me why this is correct. can you give me the correct answers and explain why? actions usually proceed with amounts of inversion and retention at the center undergoing sustitution more inversion than retention at the center undergoing substitution y more retention then in version at the center undergoing substitution lete inversion at the center undergoing sostituti plete retention at the center undergoing substitution Which of the following...
If the conversion of A to B is slow and B to C is fast, what is the rate equation for this reaction? ü i. M + et . HCI + HCI Cl H2O - step 2 step 3 A. rate = K[CH3)2CHCI][H20] B. rate = k[CH3)2CH]*[ H20] C. rate = K[CH3)2CHCI] D. rate = K[CH3)2CH]t
For the reaction below: a. Determine whether the reaction is energetically favorable at room temperature. Assume that ΔS=O. Calculate the gas phase enthalpy change using bond dissociation enthalpies at 25°C from the table below. Hint: Be aware that the bond energy for the C-H bond varies considerably and may change during the reaction; therefore, you will find several entries for C-H bonds in the table. Include the algebraic sign and specify units, e.g. -45 kJ/mol. Calculate to the nearest single...