Question

One mole of each of the following coordination compounds is dissolved in one liter of water:...

One mole of each of the following coordination compounds is dissolved in one liter of water:

(a) [Co(NH3)6]Cl3; (b) K4[Fe(CN)6]; (c) [Ni(NH3)6]Cl2; and (d) [Ru(NH3)4Cl2]Cl.

Rank the solutions in order of increasing electrical conductivity.

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Answer #1

Electrical conductivity of complex compounds is mainly originates from ionic conductivity of anions and cations. The complex which produce more number of ions will show more electrical conductivity.

In any complex the chemical groups or ions which are present out side of the coordination sphere ionize as individual ions.

So, among all complexes, complex (b) produce total five ions(1cation+3anions), complex (a) produce 4 ions, complex (c) produce 3 ions and complex (d) gives two ions.

Therefore, conductivity order b>a>c>d

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