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The properties of alkanes related to boiling point, melting, polarity and solubility

The properties of alkanes related to boiling point, melting, polarity and solubility

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The properties of alkanes :

(1) Boiling point : Alkanes experience intermolecular van der Waals forces. Stronger intermolecular van der Waals forces give rise to greater boiling points of alkanes.

(2) Melting point : The melting points of the alkanes follow a similar trend to boiling points for the same reason as outlined above.There is one significant difference between boiling points and melting points. Solids have more rigid and fixed structure than liquids. This rigid structure requires energy to break down. Thus the better put together solid structures will require more energy to break apart.

(3) Polarity :Alkanes do not have polarity due to they do not form hydrogen bonds and are insoluble in polar solvents such as water.

(4) Solubility : Due to lack of polarity they soluble in non-polar solvents.Since we know that "like dissolve like".

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