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5. A) (12 pts) Draw...
5. For the following reaction: a) draw the substitution product. Br. но CH, b) Draw the...
5. For the following reaction: a) draw the substitution product. Br. но CH, b) Draw the full mechanism of the reaction above, showing an SN2 pathway. Include all relevant electrons and curved arrows showing electron movement, AND draw the transition state. c) Draw the full mechanism of the reaction above, showing an Sn1 pathway. Include all relevant electrons and curved arrows showing electron movement, AND all intermediates in the reaction. d) Draw the energy diagrams of the Sw2 pathway and...
7. Write a mechanism for the following reaction. Use curved arrows to show the movement of electrons. Include all forma...
7. Write a mechanism for the following reaction. Use curved arrows to show the movement of electrons. Include all formal charges (if any). Also, draw a free energy diagram for the reaction. Assume the reaction is exergonic. CH,CH,OH Br 75 °C Free energy Reaction coordinate
4 and 5 PLEASE HELP curved arrows to indicate electron movement for each step. Draw all...
4 and 5 PLEASE HELP
curved arrows to indicate electron movement for each step. Draw all the resonance structures of the sigma complex intermediate. 4. (6 pts) a) Draw the complete mechanism to account for the following reaction. Make sure to show OCH3 Ords CI AICI 5. (6 pts) Draw the step-by-step mechanism for the reaction below, using curved arrows to show the flow of electrons and draw any resonance intermediates. Br Bг NO2 HNO3 H2SO4
Predict the product of the following reaction and draw a detailed step-wise mechanism for the transformation....
Predict the product of the following reaction and draw a
detailed step-wise mechanism for the transformation. Be sure to
show to all intermediates, formal charges, and show the movement of
electrons with curved arrows.
HA (pH 4-5)
Provide a full mechanism for the following reaction. Include intermediates, formal charges, and curved arrows to...
Provide a full mechanism for the following reaction. Include
intermediates, formal charges, and curved arrows to show electron
flow.
Provide a full mechanism for the following reaction. Include intermediates, formal charges, and curved arrows to show electron flow. H20, H о нон, он вме OH HN
3 (15 marks). Draw a reasonable mechanism that accounts for the formation of the unexpected product...
3 (15 marks). Draw a reasonable mechanism that accounts for the formation of the unexpected product shown below. Use curved arrows to show the movement of electrons and show the structures of all intermediates. Do not draw the structures of transition states. Do not include stereochemistry. Be sure to include formal charges and lone pairs of electrons where appropriate. OH HCI ether
Hydration of alkenes under aqueous acidic conditions. Draw the detailed stepwise mechanism for this reaction. Be...
Hydration of alkenes under aqueous acidic conditions. Draw the detailed stepwise mechanism for this reaction. Be sure to show all steps, intermediates, formal charges, and show the movement of electrons with curved arrows. You do not need to draw transition states. H2SO4 H20 ?? The hydration of alkynes can also occur under aqueous acidic conditions however, instead of forming the alcohol, a ketone is formed. Draw the detailed stepwise mechanism for the conversion of the alkyne to the ketone (one...
2. (5 pts) Draw out the mechanism for the acid-catalyzed dehydration shown below. Include all steps,...
2. (5 pts) Draw out the mechanism for the acid-catalyzed dehydration shown below. Include all steps, clearly show all charges, and all unshared electron pairs. Use curved arrows to show electron movement in all making and breaking of bonds. NOTE: To show the breaking of a bond you must draw the bond explicitly so that you can clearly draw an arrow from the electrons in the bond. : OH Q" - W H;0* -H;0
31. (8) Provide a mechanism for the reaction below. Illustrate the role played by pyridine in...
31. (8) Provide a mechanism for the reaction below. Illustrate the role played by pyridine in the reaction. Your mechanism must use curved arrows to represent electron movement and it must show all non-zero formal charges. NH N pyridine 32.(4) The reaction of acid chlorides with thiolates gives thioesters. Provide a mechanism for the following transformation. S Nat ethyl thiolate SCH,CH: a thioester 33. (4) Describe how the following acts as a soap. Na 34. (4) The following synthesis is...
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent...
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. heat NCH) CH, OH CH 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37.(4) Draw the 4 possible organic products for each reaction. Lly CH,NH 38. (4) Draw a structure for the expected product of the following reactions. wila + HN OH Gila OH
5. For the following reaction: a) draw the substitution product. Br. но CH, b) Draw the full mechanism of the reaction above, showing an SN2 pathway. Include all relevant electrons and curved arrows showing electron movement, AND draw the transition state. c) Draw the full mechanism of the reaction above, showing an Sn1 pathway. Include all relevant electrons and curved arrows showing electron movement, AND all intermediates in the reaction. d) Draw the energy diagrams of the Sw2 pathway and...
7. Write a mechanism for the following reaction. Use curved arrows to show the movement of electrons. Include all formal charges (if any). Also, draw a free energy diagram for the reaction. Assume the reaction is exergonic. CH,CH,OH Br 75 °C Free energy Reaction coordinate
4 and 5 PLEASE HELP
curved arrows to indicate electron movement for each step. Draw all the resonance structures of the sigma complex intermediate. 4. (6 pts) a) Draw the complete mechanism to account for the following reaction. Make sure to show OCH3 Ords CI AICI 5. (6 pts) Draw the step-by-step mechanism for the reaction below, using curved arrows to show the flow of electrons and draw any resonance intermediates. Br Bг NO2 HNO3 H2SO4
Predict the product of the following reaction and draw a
detailed step-wise mechanism for the transformation. Be sure to
show to all intermediates, formal charges, and show the movement of
electrons with curved arrows.
HA (pH 4-5)
Provide a full mechanism for the following reaction. Include
intermediates, formal charges, and curved arrows to show electron
flow.
Provide a full mechanism for the following reaction. Include intermediates, formal charges, and curved arrows to show electron flow. H20, H о нон, он вме OH HN
3 (15 marks). Draw a reasonable mechanism that accounts for the formation of the unexpected product shown below. Use curved arrows to show the movement of electrons and show the structures of all intermediates. Do not draw the structures of transition states. Do not include stereochemistry. Be sure to include formal charges and lone pairs of electrons where appropriate. OH HCI ether
Hydration of alkenes under aqueous acidic conditions. Draw the detailed stepwise mechanism for this reaction. Be sure to show all steps, intermediates, formal charges, and show the movement of electrons with curved arrows. You do not need to draw transition states. H2SO4 H20 ?? The hydration of alkynes can also occur under aqueous acidic conditions however, instead of forming the alcohol, a ketone is formed. Draw the detailed stepwise mechanism for the conversion of the alkyne to the ketone (one...
2. (5 pts) Draw out the mechanism for the acid-catalyzed dehydration shown below. Include all steps, clearly show all charges, and all unshared electron pairs. Use curved arrows to show electron movement in all making and breaking of bonds. NOTE: To show the breaking of a bond you must draw the bond explicitly so that you can clearly draw an arrow from the electrons in the bond. : OH Q" - W H;0* -H;0
31. (8) Provide a mechanism for the reaction below. Illustrate the role played by pyridine in the reaction. Your mechanism must use curved arrows to represent electron movement and it must show all non-zero formal charges. NH N pyridine 32.(4) The reaction of acid chlorides with thiolates gives thioesters. Provide a mechanism for the following transformation. S Nat ethyl thiolate SCH,CH: a thioester 33. (4) Describe how the following acts as a soap. Na 34. (4) The following synthesis is...
35. (4) Provide a mechanism for the following transformation. You must use curved arrows to represent electron movement and show all formal +/- charges to get full credit. heat NCH) CH, OH CH 36. (6) Provide a synthesis for the following amine using a Gabriel synthesis. NH 37.(4) Draw the 4 possible organic products for each reaction. Lly CH,NH 38. (4) Draw a structure for the expected product of the following reactions. wila + HN OH Gila OH
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