A reaction sequence and the final product is given. The reagents need to be selected from the given set of reagents. A chemical reaction involves the reaction between two or more substances. The reaction process is helped by the reagents that help in bringing about the transformation of the reactant into product.
Every reagent has a specific role and help in achieving the final product.
Periodic acid is an important reagent that is used in the oxidation of vicinal diols to corresponding carbonyl compounds.
that is osmium tetroxide is used for cis hydroxylation of alkenes.
Na in liquid is used for the conversion of alkynes to trans alkenes.
The reaction is as follows:
The trans alkene is converted to syn diols as follows:
The syn diol undergoes oxidation as follows:
Hence, the given transformation can be carried out by using following set of reagents:
Identify the missing reagents 1 & 2; draw the final organic product(s) C.
Identify the missing reagents 1 & 2; draw the final organic
product(s) C.
Identify the missing reagents 1 & 2; draw the final organic product(s) C.
Identify the missing reagents 1 & 2 draw the final organic product(s) C Reagent 2 Reagent 1 Al NaNH3 1) oso4 2) NaHSO3, H20 CEC Incorrect Periodic acid causes oxidative cleavage of the diol, yielding two carbonyl compounds. HO Reagent 3 HIO4 OH Map dt
Draw the missing major organic product(s), starting
material(s), or reagents for each of the following reactions (DO
NOT WRITE +EN AS A PRODUCT (ie draw everything out!)! And remember
stereo and regiochemistry.) Assume reagents are in excess unless
otherwise indicated. **To make things simple, I indicated what is
needed for each section! Please don't just put the answers, but
explanations as well on why. Thanks!
a) draw the starting material for this reaction.
b) draw the product for this reaction....
For each of the following reactions supply the missing starting
material(s) or final organic product(s) in the bobxes provided.
HO Ph 1) LiAlH4 2) H20 Me Me Mel Br2 H30 1) PBr3, Br2 2) H20 OH excess NaOH 1) excess Br2 2) H30 Reaction Name:
For each of the following reactions supply the missing starting
material(s) or final organic product(s) in the bobxes provided.
Eto 1) 0.9 equiv LDA 3) H30 NaOMe MeOH 1) KOEt OEt 2) H30 OEt Reaction Name: 1) NaH O O OEt 3) H30 A Reaction Name:
Draw the organic product for this reaction. NaOET Draw the organic product for this reaction. C-S
Draw the final organic product of the reaction. CH3CH2NH2
Draw the final organic product of the reaction.
here are the reagents
Identify the reagents for all three steps. Draw the structures of organic compounds A and B. Omit byproducts.
1. Provide the missing starting material, reagents, or major organic product for each of the following reactions. (No more than two steps are required in any case where we ask you to fill in reagents.) 1. Mgo, Et20 2. H20 a) Cl b) MgBr OH , Et20 2. H* workup c) OH d) NaOH (cat.) e) OH NaBH4, CeCl3, MeOH