which reaction is faster and why ? (0.1 ml 2-Chlorobutane and 1% ethanolic silver nitrate solution)...
which reaction is faster and why ? (0.1 ml 2-Chlorobutane and 1% ethanolic silver nitrate solution) or (0.1 ml 2-Chlorobutane and silver nitrate in a mixture of 50% ethanol-50% water)
Homework Answers
2-chlorobutane is secondary alkyl halide. The ease of the SN1 and SN2 is same with this substrate. Therefore, it would undero both to rpoduce 2-nitro butane with AgNO3. In addition to the SN2, SN1 gets faster with the increased polarity of the system i.e. 50% of water and 50% of ethanol is used and hence the second reaction is faster
Add Answer to:
which reaction is faster and why ? (0.1 ml 2-Chlorobutane and 1%
ethanolic silver nitrate solution)...
Reaction equations for each of the following with silver nitrate in ethanol (SN1): - 2-Chlorobutane -2-bromobutane...
Reaction equations for each of the following with silver nitrate in ethanol (SN1): - 2-Chlorobutane -2-bromobutane - Bromobenzene - 2-Bromo- 2-methylpropane
Provide a reasonable mechanism for the reaction of 2-chloro-2-methylpropane with ethanolic silver nitrate.
Provide a reasonable mechanism for the reaction of 2-chloro-2-methylpropane with ethanolic silver nitrate.
1. What would you observe if you tested 3-bromopropene with: a) the ethanolic silver nitrate solution?...
1. What would you observe if you tested 3-bromopropene with: a) the ethanolic silver nitrate solution? Explain briefly. Propose an arrow pushing mechanism for this reaction using proper Lewis structures b) the sodium iodide in acetone solution? Explain briefly. Propose an arrow pushing mechanism for this reaction using proper Lewis structures
1. In both the sodium iodide test and the silver nitrate test, why does 2-bromobutane react faster...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
indicate which reaction will occur faster. explain your reasoning. reaction of 1 chlorobutane with sodium iodide...
indicate which reaction will occur faster. explain
your reasoning. reaction of 1 chlorobutane with sodium iodide or
sodium p toluenesulfonate in aqueous ethanol.
Indicate which reaction will occur faster. Explain your reasoning. Select the single best answer Reaction of 1-chlorobutane with sodium iodide or sodium p-toluenesulfonate in aqueous ethanol Sodium iodide will react faster because the leaving group encounters less sterle hindrance. Sodium iodide will react faster because the intermediate is more stabilized in the solvent. Sodium p-toluenesulfonate will react...
need help with question 8 9 10 Part B. Silver Nitrate in Ethanol (Sul mechanisms) 7....
need help with question 8 9 10
Part B. Silver Nitrate in Ethanol (Sul mechanisms) 7. Write an Spi mechanism with curved arrows for the general reaction. Make sure you draw out the bond-line structures to show mechanism. (CH),CCI + CH3CH2OH (CH3),OC,Hs + HCI - Stor-) CH3 CH2 - HEc6+ HC ct cus CHO-H HC - c-o-qus - HCl + H₂4-1 s church 8. a) What is the formula of the precipitate that indicates a reaction has taken place? He...
SHOW ALL WORK!!! ?the addition of hydrochoric acid to silver nitrate solution precipitate silver chloride according...
SHOW ALL WORK!!!
?the addition of hydrochoric acid to silver nitrate solution
precipitate silver chloride according to the following
reaction:
when 50.0 ml of 0.1 M AgNO_3 is combined with 50.0 ml of 0.1 M
HCl in a coffee cup calorimeter, the tempertature changes from 23.4
to 24.21*C. Calculate the
for the reaction per mole of HCl. Use 1.0 g/ml as the dnsity of
the solution and 4.184 j/g*C as the specific heat capacity.
Two unknown compounds were tested in a sodium iodide in acetone test and a silver nitrate...
Two unknown compounds were tested in a sodium iodide in acetone test and a silver nitrate in ethanol test. The observations of these tests are given below. Use structures A-E to the right to answer the following questions. Given these observations, what are the identities of Unknowns 1 and 2? Unknown 1 Unknown 2 Do you except reaction of bromobenzene (B) in the silver nitrate in ethanol test to be fast, slow or nonreactive? Why? Do you except Structure E...
Silver chloride is not very soluble. The reaction by which it goes into solution is: AgCl(s)...
Silver chloride is not very soluble. The reaction by which it goes into solution is: AgCl(s) <==> Ag^+ (aq) + Cl^- (aq) A.) suppose a saturated solution of silver chloride were present. What would happen if you added a few ml of Jack solution and why? B.) What would happen if you added a few ml of Silver Nitrate solution and why? C.) If this reaction is known to be endothermic, what would happen if the solution were heated? What...
Calculate the volume in milliliters of a 4.3M silver nitrate solution that contains 100. g of...
Calculate the volume in milliliters of a 4.3M silver nitrate solution that contains 100. g of silver nitrate (AgNO,). Round your answer to 2 significant digits. XI ? Wine goes baill soon after opening because the ethanol (CH.CH,OH) in it reacts with oxygen gas (0) from the air to form water (HO) and acetic acid (CH,COOH), the main ingredient of vinegar. What mass of ethanol is consumed by the reaction of 8.35 g of oxygen gas? Round your answer to...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
indicate which reaction will occur faster. explain
your reasoning. reaction of 1 chlorobutane with sodium iodide or
sodium p toluenesulfonate in aqueous ethanol.
Indicate which reaction will occur faster. Explain your reasoning. Select the single best answer Reaction of 1-chlorobutane with sodium iodide or sodium p-toluenesulfonate in aqueous ethanol Sodium iodide will react faster because the leaving group encounters less sterle hindrance. Sodium iodide will react faster because the intermediate is more stabilized in the solvent. Sodium p-toluenesulfonate will react...
need help with question 8 9 10
Part B. Silver Nitrate in Ethanol (Sul mechanisms) 7. Write an Spi mechanism with curved arrows for the general reaction. Make sure you draw out the bond-line structures to show mechanism. (CH),CCI + CH3CH2OH (CH3),OC,Hs + HCI - Stor-) CH3 CH2 - HEc6+ HC ct cus CHO-H HC - c-o-qus - HCl + H₂4-1 s church 8. a) What is the formula of the precipitate that indicates a reaction has taken place? He...
SHOW ALL WORK!!!
?the addition of hydrochoric acid to silver nitrate solution
precipitate silver chloride according to the following
reaction:
when 50.0 ml of 0.1 M AgNO_3 is combined with 50.0 ml of 0.1 M
HCl in a coffee cup calorimeter, the tempertature changes from 23.4
to 24.21*C. Calculate the
for the reaction per mole of HCl. Use 1.0 g/ml as the dnsity of
the solution and 4.184 j/g*C as the specific heat capacity.
Two unknown compounds were tested in a sodium iodide in acetone test and a silver nitrate in ethanol test. The observations of these tests are given below. Use structures A-E to the right to answer the following questions. Given these observations, what are the identities of Unknowns 1 and 2? Unknown 1 Unknown 2 Do you except reaction of bromobenzene (B) in the silver nitrate in ethanol test to be fast, slow or nonreactive? Why? Do you except Structure E...
Calculate the volume in milliliters of a 4.3M silver nitrate solution that contains 100. g of silver nitrate (AgNO,). Round your answer to 2 significant digits. XI ? Wine goes baill soon after opening because the ethanol (CH.CH,OH) in it reacts with oxygen gas (0) from the air to form water (HO) and acetic acid (CH,COOH), the main ingredient of vinegar. What mass of ethanol is consumed by the reaction of 8.35 g of oxygen gas? Round your answer to...
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