Part A :
Eo = 0.45-0.26 = 0.19 V
lnk = nFE / RT
n = 2
F = 98500
R = 8.314
T =298K
K = 2.74*10^-7
part B :
lnK = nFEo / RT
we know all values except Eo
Eo = RTlnK/nF = - 0.12V
Cell Potential and Equilibrium Standard reduction potentials The equilibrium constant, K, for a redox reaction is...
The equilibrium constant, K, for a redox reaction is related to the standard potential, Eº, by the equation In K = nFE° RT where n is the number of moles of electrons transferred, F (the Faraday constant) is equal to 96,500 C/(mol e), R (the gas constant) is equal to 8.314 J/(mol · K), and T is the Kelvin temperature. Standard reduction potentials Reduction half-reaction E° (V) Ag+ (aq) + e +Ag(s) 0.80 Cu²+ (aq) + 2e + Cu(s) 0.34...
Review I Constants I Periodic Table The equilibrium constant, K, for a redox reaction is related to the standard potential, E°, by the equation Standard reduction potentials nFE RT In K E° (V) Reduction half-reaction Agt(aq)eAg(s) Cu2+(aq)2eCu(s) 0.80 where n is the number of moles of electrons transferred, F (the Faraday constant) is equal to 96,500 C/(mol e), R (the gas constant) is equal to 8.314 J/(mol - K) , and T is the Kelvin temperature. 0.34 Sn4t (aq)4eSn(s) 0.15...
Use standard reduction potentials to calculate the equilibrium constant for the reaction: Fe(a 2Fe(a) Fe(s)+2Fe (aq) Hint: Carry at least Equilibrium constant: than zero. AO for this reaction would be 9 more group a Submit Answer Retry Entire Group ing Use standard reduction potentials to calculate the equilibrium constant for the reaction: Sn2+(aq) + Fe(s)-→ Sn(s) + Fe2+(aq) Hint: Carry at least S significant figures during intermediate calculations to avoid round off error when taking the antilogarithnm. Equilibrium constant AG°...
consider the following standard reduction potentials. Reduction Half-Reaction Eo (volts) Al3+(aq) + 3e− → Al(s) − 1.66 Fe2+(aq) + 2e− → Fe(s) − 0.44 Sn2+(aq) + 2e− → Sn(s) − 0.14 The Al/Al3+ half-reaction can be paired with the other two to produce voltaic cells because ________ A) Al is a more powerful oxidizing agent B) Fe and Sn are readily oxidized Al is a more powerful reducing agent C) Al3+ is a more powerful oxidizing agent D) Al3+...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
Selective Reduction The standard reduction potential for the half-reaction: Sn4+ + 2e - Sn2+ is +0.15 V. Consider data from the table of standard reduction potentials for common half-reactions, in your text. For a galvanic cell under standard conditions, which of the following anodic half reactions would produce, at the cathode a spontaneous reduction of Sn4+ to Sn2+ but not Sn2+ to Sn. no yes yes yes yes yes Fe — Fe2+ + 2e- Sn2+ Sn4+ + 2e- Sn Sn2+...
The equilibrium constant, K. for a redox reaction is related to the standard potential, E, by the equation Fe(s) + Ni+ (aq) +Fe?+ (aq) + NI(s) FE In K = Express your answer numerically. View Available Hints) where n is the number of moles of electrons transferred, F (the Faraday constant) is equal to 96,500 C/(mole). R (the gas constant) is equal to 8.314 J/(mol-K). and T is the Kelvin temperature. ΟΙ ΑΣΦ h ? KK- Submit Previous Answers *...
use tabulated standard electrode potential to calculate the standard cell potential for the reaction occurring in an electrochemical cell at 25 C. (The equation is balanced.) 3Ni^2+(aq)+2Cr(s)--->3Ni(s)2Cr^3+(aq) Express your answer to two significant figures and include the appropriate units. em 26 E (V) -0.45 -0.50 -0.73 -0.76 -1.18 Standard reduction half-cell potentials at 25°C Half-reaction E° (V) Half-reaction Aul+ (aq) + 3e +Au(s) 1.50 Fe2+ (aq) + 2eFe(s) Ag+ (aq) +e-Ag(s) 0.80 Cr3+ (aq) + Cr²+ (aq) Fe+(aq) + 3e...
4. (a) Use the standard reduction potentials at 25° C in Table 18.1 in Tro, Fridgen and Shaw, and calculate the standard emf E° of an electrochemical cell described by the following reaction: 3 Zn + 2 Cr3+ + 2 Cr + 3 Zn? (b) What is n? (c) What is AGº for this reaction at 25°? (d) What is the equilibrium constant for this reaction at 25°? TABLE 18.1 Standard Reduction Potentials at 25°C EV) 2.87 1.61 1.51 1.36...
Use the tabulated electrode potentials to calculate K for the oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g) Express your answer using two significant figures. Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V) Half-reaction E∘ (V) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) −0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) −0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) −0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) −0.76 Cu2+(aq)+2e−→Cu(s) 0.34 Mn2+(aq)+2e−→Mn(s) −1.18 2H+(aq)+2e−→H2(g) 0.00 Al3+(aq)+3e−→Al(s) −1.66 Fe3+(aq)+3e−→Fe(s) −0.036 Mg2+(aq)+2e−→Mg(s) −2.37 Pb2+(aq)+2e−→Pb(s) −0.13 Na+(aq)+e−→Na(s) −2.71 Sn2+(aq)+2e−→Sn(s) −0.14 Ca2+(aq)+2e−→Ca(s) −2.76 Ni2+(aq)+2e−→Ni(s) −0.23 Ba2+(aq)+2e−→Ba(s) −2.90 Co2+(aq)+2e−→Co(s) −0.28 K+(aq)+e−→K(s) −2.92 Cd2+(aq)+2e−→Cd(s)...