Use the tabulated electrode potentials to calculate K for the oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g)...
Use the tabulated electrode potentials to calculate K for the oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g) Express your answer using two significant figures.
Standard reduction half-cell potentials at 25∘C
| Half-reaction | E∘ (V) | Half-reaction | E∘ (V) | |
| Au3+(aq)+3e−→Au(s) | 1.50 | Fe2+(aq)+2e−→Fe(s) | −0.45 | |
| Ag+(aq)+e−→Ag(s) | 0.80 | Cr3+(aq)+e−→Cr2+(aq) | −0.50 | |
| Fe3+(aq)+3e−→Fe2+(aq) | 0.77 | Cr3+(aq)+3e−→Cr(s) | −0.73 | |
| Cu+(aq)+e−→Cu(s) | 0.52 | Zn2+(aq)+2e−→Zn(s) | −0.76 | |
| Cu2+(aq)+2e−→Cu(s) | 0.34 | Mn2+(aq)+2e−→Mn(s) | −1.18 | |
| 2H+(aq)+2e−→H2(g) | 0.00 | Al3+(aq)+3e−→Al(s) | −1.66 | |
| Fe3+(aq)+3e−→Fe(s) | −0.036 | Mg2+(aq)+2e−→Mg(s) | −2.37 | |
| Pb2+(aq)+2e−→Pb(s) | −0.13 | Na+(aq)+e−→Na(s) | −2.71 | |
| Sn2+(aq)+2e−→Sn(s) | −0.14 | Ca2+(aq)+2e−→Ca(s) | −2.76 | |
| Ni2+(aq)+2e−→Ni(s) | −0.23 | Ba2+(aq)+2e−→Ba(s) | −2.90 | |
| Co2+(aq)+2e−→Co(s) | −0.28 | K+(aq)+e−→K(s) | −2.92 | |
| Cd2+(aq)+2e−→Cd(s) | −0.40 | Li+(aq)+e−→Li(s) | −3.04 |
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Use the tabulated electrode potentials to calculate K for the
oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g)...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
Standard reduction half-cell potentials at 25°C E (V) E (V) 1.50 -0.45 0.80 -0.50 0.77 -0.73...
Standard reduction half-cell potentials at 25°C E (V) E (V) 1.50 -0.45 0.80 -0.50 0.77 -0.73 0.52 -0.76 0.34 -1.18 Half-reaction Aut (aq) + 3e +Au(s) Ag+ (aq) + +Ag(s) Fe3+ (aq) +34 Fo+ (aq) Cut(aq) + Cu(s) Cu²+ (aq) + 2e +Cu(s) 2H+ (aq) - 2e +H2 (6) Fe3+ (aq) + 3e Fe(s) Pb2+ (aq) + 2e →Pb(s) Sn-(aq) + 2e +Sn(s) Ni2+ (aq) + 2e →Ni(s) Co2(aq) +2e + Co(s) ca? (aq) + 2e +Cd(s) 0.00 Half-reaction Fe(aq)...
use tabulated standard electrode potential to calculate the standard cell potential for the reaction occurring in an el...
use tabulated standard electrode potential to calculate the
standard cell potential for the reaction occurring in an
electrochemical cell at 25 C. (The equation is balanced.)
3Ni^2+(aq)+2Cr(s)--->3Ni(s)2Cr^3+(aq)
Express your answer to two significant figures and include the
appropriate units.
em 26 E (V) -0.45 -0.50 -0.73 -0.76 -1.18 Standard reduction half-cell potentials at 25°C Half-reaction E° (V) Half-reaction Aul+ (aq) + 3e +Au(s) 1.50 Fe2+ (aq) + 2eFe(s) Ag+ (aq) +e-Ag(s) 0.80 Cr3+ (aq) + Cr²+ (aq) Fe+(aq) + 3e...
4. (a) Use the standard reduction potentials at 25° C in Table 18.1 in Tro, Fridgen...
4. (a) Use the standard reduction potentials at 25° C in Table 18.1 in Tro, Fridgen and Shaw, and calculate the standard emf E° of an electrochemical cell described by the following reaction: 3 Zn + 2 Cr3+ + 2 Cr + 3 Zn? (b) What is n? (c) What is AGº for this reaction at 25°? (d) What is the equilibrium constant for this reaction at 25°? TABLE 18.1 Standard Reduction Potentials at 25°C EV) 2.87 1.61 1.51 1.36...
For all of the following experiments, under standard conditions, which species could be spontaneously produced? A...
For all of the following
experiments, under standard conditions, which species could be
spontaneously produced?
A lead wire is placed in a solution containing
Cu2+
yes no Cu
yes no PbO2
yes no No reaction
Crystals of I2 are added to a solution of
NaCl.
yes no I-
yes no No reaction
yes no Cl2
A silver wire is placed in a solution containing
Cu2+
no yes Cu
no yes No reaction
no yes Ag+
Half-Reaction 8° (V) Half-Reaction 8° (V) 2.87 1.99 1.82 1.78 1.70 1.69 1.68 1.60...
Consider the following species. Cut Ce3+ Ag+ Zn2+ What is the standard potential for the reaction...
Consider the following species. Cut Ce3+ Ag+ Zn2+ What is the standard potential for the reaction of Cut with Zn2+ to produce Cu2+ and Zn? E = 0.28 X v Will Cut be able to reduce Zn2+ to Zn? no (yes or no) What is the standard potential for the reaction of Ce3+ with Ag! to produce Ag? Ex= 0.90 x v Will Cell be able to reduce Ag! to Ag? yes (yer or no) Ered (V) 0.68 0.52 0.40...
Candidate l: Zn(s) | Zn2+(aq,0.500 M) I Cu2+(aq, 1.00 M) Cu(s) Candidate 2: Pb(s) | Pb2+(aq,...
Candidate l: Zn(s) | Zn2+(aq,0.500 M) I Cu2+(aq, 1.00 M) Cu(s) Candidate 2: Pb(s) | Pb2+(aq, 0.500 M) || Cu2+(aq, 1.00 M) Cu(s) Candidate 3: Mg(s) | Mg2+(aq, 0.500 M) | Pb2+(aq, 1.00 M)| Pb(s) (a) 6 pts) Choose one of the candidate voltaic cells #1, #2, or #3. Draw a schematic cell diagram for the candidate voltaic cell of choice. Clearly label anode, cathode, electrodes, ions and their concentrations, salt bridge, and the flow of electrons. (b) (5 pts)...
12. Using two half reactions that have NEGATIVE standard reduction potentials results results in a battery...
12. Using two half reactions that have NEGATIVE standard reduction potentials results results in a battery that... Reduction Half-Reaction F2(g) + 2e →2F(aq) S2082 (aq) + 2e- → 25042 (aq) O2(g) + 4H+ (aq) + 4e → 2H2O(1) Br2(1) + 2e + 2Br (aq) Agt(aq) + e → Ag(s) Fe3+ (aq) + e- → Fe2+ (aq) 126) + 2e → 21 (aq) Cu2+ (aq) + 2e → Cu(s) Sn4+ (aq) + 2e → Sn2+ (aq) S(s) + 2H+ (aq) +...
HQ18.28 Homework • Unanswered Some electrode combinations that the Phoenix spacecraft designers may have considered for...
HQ18.28 Homework • Unanswered Some electrode combinations that the Phoenix spacecraft designers may have considered for use in their design are given in the table below. Assume the ambient Martian temperature is -67.5*C, 205.7 K. What electrode combination (assume 0.1 M solutions) would provide the 1.317 V required by the spacecraft electronics? Use Appendix 11 for your standard cell potentials. А Rh+ +e- Rh/Ni2+ + 2e + NI O B Rh+ + e + Rh/Cr3+ + 3e - Cr C...
Post Lab Questions: To receive full credit, you must SHOW ALL YOUR WORK!! Use the table...
Post Lab Questions: To receive full credit, you must SHOW ALL YOUR WORK!! Use the table of reduction half reactions to answer the following Post-Lab questions: Table 3. Example reduction Reduction Potential Chart half reactions. The easiest to Ce+(aq) + 3e - Ce3+ (aq) reduce is at the top. The more Au3+ (aq) + 3e Au(s) difficult to reduce is at the bottom. Cl2(g) + 2e 2CH(ag) Ag+ (aq) + e- Ag(s) Fe3+ (aq) + e- Fe2+ (aq) AgCl(s) +...
Standard reduction half-cell potentials at 25°C E (V) E (V) 1.50 -0.45 0.80 -0.50 0.77 -0.73 0.52 -0.76 0.34 -1.18 Half-reaction Aut (aq) + 3e +Au(s) Ag+ (aq) + +Ag(s) Fe3+ (aq) +34 Fo+ (aq) Cut(aq) + Cu(s) Cu²+ (aq) + 2e +Cu(s) 2H+ (aq) - 2e +H2 (6) Fe3+ (aq) + 3e Fe(s) Pb2+ (aq) + 2e →Pb(s) Sn-(aq) + 2e +Sn(s) Ni2+ (aq) + 2e →Ni(s) Co2(aq) +2e + Co(s) ca? (aq) + 2e +Cd(s) 0.00 Half-reaction Fe(aq)...
use tabulated standard electrode potential to calculate the
standard cell potential for the reaction occurring in an
electrochemical cell at 25 C. (The equation is balanced.)
3Ni^2+(aq)+2Cr(s)--->3Ni(s)2Cr^3+(aq)
Express your answer to two significant figures and include the
appropriate units.
em 26 E (V) -0.45 -0.50 -0.73 -0.76 -1.18 Standard reduction half-cell potentials at 25°C Half-reaction E° (V) Half-reaction Aul+ (aq) + 3e +Au(s) 1.50 Fe2+ (aq) + 2eFe(s) Ag+ (aq) +e-Ag(s) 0.80 Cr3+ (aq) + Cr²+ (aq) Fe+(aq) + 3e...
4. (a) Use the standard reduction potentials at 25° C in Table 18.1 in Tro, Fridgen and Shaw, and calculate the standard emf E° of an electrochemical cell described by the following reaction: 3 Zn + 2 Cr3+ + 2 Cr + 3 Zn? (b) What is n? (c) What is AGº for this reaction at 25°? (d) What is the equilibrium constant for this reaction at 25°? TABLE 18.1 Standard Reduction Potentials at 25°C EV) 2.87 1.61 1.51 1.36...
For all of the following
experiments, under standard conditions, which species could be
spontaneously produced?
A lead wire is placed in a solution containing
Cu2+
yes no Cu
yes no PbO2
yes no No reaction
Crystals of I2 are added to a solution of
NaCl.
yes no I-
yes no No reaction
yes no Cl2
A silver wire is placed in a solution containing
Cu2+
no yes Cu
no yes No reaction
no yes Ag+
Half-Reaction 8° (V) Half-Reaction 8° (V) 2.87 1.99 1.82 1.78 1.70 1.69 1.68 1.60...
Consider the following species. Cut Ce3+ Ag+ Zn2+ What is the standard potential for the reaction of Cut with Zn2+ to produce Cu2+ and Zn? E = 0.28 X v Will Cut be able to reduce Zn2+ to Zn? no (yes or no) What is the standard potential for the reaction of Ce3+ with Ag! to produce Ag? Ex= 0.90 x v Will Cell be able to reduce Ag! to Ag? yes (yer or no) Ered (V) 0.68 0.52 0.40...
Candidate l: Zn(s) | Zn2+(aq,0.500 M) I Cu2+(aq, 1.00 M) Cu(s) Candidate 2: Pb(s) | Pb2+(aq, 0.500 M) || Cu2+(aq, 1.00 M) Cu(s) Candidate 3: Mg(s) | Mg2+(aq, 0.500 M) | Pb2+(aq, 1.00 M)| Pb(s) (a) 6 pts) Choose one of the candidate voltaic cells #1, #2, or #3. Draw a schematic cell diagram for the candidate voltaic cell of choice. Clearly label anode, cathode, electrodes, ions and their concentrations, salt bridge, and the flow of electrons. (b) (5 pts)...
12. Using two half reactions that have NEGATIVE standard reduction potentials results results in a battery that... Reduction Half-Reaction F2(g) + 2e →2F(aq) S2082 (aq) + 2e- → 25042 (aq) O2(g) + 4H+ (aq) + 4e → 2H2O(1) Br2(1) + 2e + 2Br (aq) Agt(aq) + e → Ag(s) Fe3+ (aq) + e- → Fe2+ (aq) 126) + 2e → 21 (aq) Cu2+ (aq) + 2e → Cu(s) Sn4+ (aq) + 2e → Sn2+ (aq) S(s) + 2H+ (aq) +...
HQ18.28 Homework • Unanswered Some electrode combinations that the Phoenix spacecraft designers may have considered for use in their design are given in the table below. Assume the ambient Martian temperature is -67.5*C, 205.7 K. What electrode combination (assume 0.1 M solutions) would provide the 1.317 V required by the spacecraft electronics? Use Appendix 11 for your standard cell potentials. А Rh+ +e- Rh/Ni2+ + 2e + NI O B Rh+ + e + Rh/Cr3+ + 3e - Cr C...
Post Lab Questions: To receive full credit, you must SHOW ALL YOUR WORK!! Use the table of reduction half reactions to answer the following Post-Lab questions: Table 3. Example reduction Reduction Potential Chart half reactions. The easiest to Ce+(aq) + 3e - Ce3+ (aq) reduce is at the top. The more Au3+ (aq) + 3e Au(s) difficult to reduce is at the bottom. Cl2(g) + 2e 2CH(ag) Ag+ (aq) + e- Ag(s) Fe3+ (aq) + e- Fe2+ (aq) AgCl(s) +...
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