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Standard reduction half-cell potentials at 25°C E (V) E (V) 1.50 -0.45 0.80 -0.50 0.77 -0.73...
Use the tabulated electrode potentials to calculate K for the oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g) Express your answer using two significant figures. Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V) Half-reaction E∘ (V) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) −0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) −0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) −0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) −0.76 Cu2+(aq)+2e−→Cu(s) 0.34 Mn2+(aq)+2e−→Mn(s) −1.18 2H+(aq)+2e−→H2(g) 0.00 Al3+(aq)+3e−→Al(s) −1.66 Fe3+(aq)+3e−→Fe(s) −0.036 Mg2+(aq)+2e−→Mg(s) −2.37 Pb2+(aq)+2e−→Pb(s) −0.13 Na+(aq)+e−→Na(s) −2.71 Sn2+(aq)+2e−→Sn(s) −0.14 Ca2+(aq)+2e−→Ca(s) −2.76 Ni2+(aq)+2e−→Ni(s) −0.23 Ba2+(aq)+2e−→Ba(s) −2.90 Co2+(aq)+2e−→Co(s) −0.28 K+(aq)+e−→K(s) −2.92 Cd2+(aq)+2e−→Cd(s)...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
use tabulated standard electrode potential to calculate the standard cell potential for the reaction occurring in an electrochemical cell at 25 C. (The equation is balanced.) 3Ni^2+(aq)+2Cr(s)--->3Ni(s)2Cr^3+(aq) Express your answer to two significant figures and include the appropriate units. em 26 E (V) -0.45 -0.50 -0.73 -0.76 -1.18 Standard reduction half-cell potentials at 25°C Half-reaction E° (V) Half-reaction Aul+ (aq) + 3e +Au(s) 1.50 Fe2+ (aq) + 2eFe(s) Ag+ (aq) +e-Ag(s) 0.80 Cr3+ (aq) + Cr²+ (aq) Fe+(aq) + 3e...
Fill in the Blanks 0.34 Half Reaction E. (V) Half Reaction Erd® (V) F + 2e →2F 0+ 2H + 2e →H,02 0.68 Ag* + e → Ag Cu* + e → Cu 0.52 Co? + e Co? O2 + 2H,0 + 4e → 40H 0.40 H,O, + 2H + 2e → 2H,0 Cu2+ + 2e → Cu Cet+e → Ces Cu2+ + e → Cut 0.16 PbO, + 4H+ +50,2 +2e → PbSO, + 2H,0 2H* + 2e →...
12. Using two half reactions that have NEGATIVE standard reduction potentials results results in a battery that... Reduction Half-Reaction F2(g) + 2e →2F(aq) S2082 (aq) + 2e- → 25042 (aq) O2(g) + 4H+ (aq) + 4e → 2H2O(1) Br2(1) + 2e + 2Br (aq) Agt(aq) + e → Ag(s) Fe3+ (aq) + e- → Fe2+ (aq) 126) + 2e → 21 (aq) Cu2+ (aq) + 2e → Cu(s) Sn4+ (aq) + 2e → Sn2+ (aq) S(s) + 2H+ (aq) +...
4. (a) Use the standard reduction potentials at 25° C in Table 18.1 in Tro, Fridgen and Shaw, and calculate the standard emf E° of an electrochemical cell described by the following reaction: 3 Zn + 2 Cr3+ + 2 Cr + 3 Zn? (b) What is n? (c) What is AGº for this reaction at 25°? (d) What is the equilibrium constant for this reaction at 25°? TABLE 18.1 Standard Reduction Potentials at 25°C EV) 2.87 1.61 1.51 1.36...
A certain half-reaction has a standard reduction potential E = -0.45 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 1.00 V of electrical power. The cell will operate under standard conditions Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. 0-0 . " Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell...
the standard reduction potential is attached below Use the table of standard reduction potentials for the following exercises. 4. Predict the products of the following redox reactions, then identify which could spontaneously occur. a) H(aq) + Au (s) → b) H (aq) + Na (8) ► c) Au+ (aq) + Na (5) ► 5. Find a reagent that can oxidize Br" to Br2 but cannot oxidize CI'' to Cl? More than one reagent is possible, but you only need to...
Consider the following species. Cut Ce3+ Ag+ Zn2+ What is the standard potential for the reaction of Cut with Zn2+ to produce Cu2+ and Zn? E = 0.28 X v Will Cut be able to reduce Zn2+ to Zn? no (yes or no) What is the standard potential for the reaction of Ce3+ with Ag! to produce Ag? Ex= 0.90 x v Will Cell be able to reduce Ag! to Ag? yes (yer or no) Ered (V) 0.68 0.52 0.40...
2.87 Ered® (V) 0.68 0.52 0.40 0.34 0.16 Half Reaction F,+ 2e →2F Ag* + e → Ag Co3 + e + CO2- H2O2 + 2H+ + 2e → 2H,0 Ce4+ + e → Ce+ PbO, + 4H+ + SO42- + 2e → PbSO, + 2H,0 Mno, + 4H+ + 3e → MnO2 + 2H,0 2e + 2H+ + 10, → 103 + H2O Mn0, +8H+ + 5e → Mn2+ + 4H,0 Aul+ + 3e → Au Cl2 + 2e...