Example Question Suppose a molecule exists as a one dimensional harmonic oscillator in a superposition state...
Quantum, 1D harmonic oscillator. Please answer in full. Thanks. Q3. The energy levels of the 1D harmonic oscillator are given by: En = (n +2)ha, n=0. 1, 2, 3, The CO molecule has a (reduced) mass of mco = 1.139 × 10-26 kg. Assuming a force constant of kco 1860 N/m, what is: a) The angular frequency, w, of the ground state CO bond vibration? b) The energy separation between the ground and first excited vibrational states? 7 marks] The...
A particle with mass m is in a one dimensional simple harmonic oscillator potential. At timet0 it is described by the superposition state where Vo, 1 and Vz are normalised energy eigenfunctions of the harmonic oscillator potential corresponding to energies Eo, E1 and E2 (a) Show that the wavefunction is normalised (b) If an observation of energy is made, what is the most likely value of energy and with what probability would it be obtained? (c) If the experiment is...
2. Consider a one-dimensional simple harmonic oscillator. Do the following algebraically. 2. Consider a one -dimensional simple harmonic oscillator. Do the following algebraically. a) Construct a linear superposition of I0) and |1) by choosing appropriate phases, such that (x) is as large as possible. i) Suppose the oscillator is in the state la) att 0. Find la) and x) ii) Evaluate the expectation value(x) at t 〉 0. ii Evaluate (A x)2) att > 0. b) Answer the same questions...
Suppose a particle is in a one-dimensional harmonic oscillator potential. Suppose that a perturbation is added at time t = 0 of the form . Assume that at time t = 0 the particle is in the ground state. Use first order perturbation theory to find the probability that at some time t1 > 0 the particle is in the first excited state of the harmonic oscillator. H' = ext.
4. What is the extent of the ground state wavefunction of the vibration (approxi- mated as a harmonic oscillator)for NO. Note that vibrational transitions in NO are observed at 5.6 × 1013 Hz and its overtones. Hint: be careful with what (1 point) effective "mass" vou use for the vibration. 4. What is the extent of the ground state wavefunction of the vibration (approxi- mated as a harmonic oscillator)for NO. Note that vibrational transitions in NO are observed at 5.6...
5. A particle in the harmonic oscillator potential has the initial wave function Psi(x, 0) = A[\psi_{0}(x) + \psi_{1}(x)] for some constant A. Here to and ₁ are the normalized ground state and the first excited state wavefunctions of the harmonic oscillator, respectively. (a) Normalize (r, 0). (b) Find the wavefunction (r, t) at a later time t and hence evaluate (x, t) 2. Leave your answers involving expressions in to and ₁. c) sing the following normalized expression of...
Estimate the ground-state energy of a one-dimensional simple harmonic oscillator using (50) = e-a-l as a trial function with a to be varied. For a simple harmonic oscillator we have H + jmwºr? Recall that, for the variational method, the trial function (HO) gives an expectation value of H such that (016) > Eo, where Eo is the ground state energy. You may use: n! dH() ||= TH(c) – z[1 – H(r)], 8(2), dx S." arcade an+1 where (x) and...
Hydrogen molecule bonded to a surface is acting as a quantized harmonic oscillator with a force constant of 300 Nm^-1. a) What is the second to the lowest possible vibrational energy of this system? b) What is the wavefunction of the photon whose energy matches the difference between these two energy levels?
A particle with mass m is in a one-dimensional simple harmonic oscillator potential. At time t = 0 it is described by the state where lo and l) are normalised energy eigenfunctions corresponding to energies E and Ey and b and c are real constants. (a) Find b and c so that (x) is as large as possible. b) Write down the wavefunction of this particle at a time t later c)Caleulate (x) for the particle at time t (d)...
Consider a particle with mass m described by the Hamilton operator for a one-dimensional harmonic oscillator 2 Zm 2 The normalized eigenfunctions for Hare φη (x) with energies E,,-(n + 2) ha. At time t-0 the wavefunction of the particle is given by у(x,0)- (V3іфі (x) + ф3(x)). Now let H' be an operator given by where k is a positive constant. 1) Show that H' is Hermitian. 2) Express H' by the step-operators a+ and a 3) Calculate the...