Name 3.00 mL of 1,3-cyclohexadiene (MW -80.13, d-0.841g/mL) is dissolved in ethyl acetate and allowed to...
Critical Thinking Questions 1. Draw the structure for the product from the reaction of 1,3-cyclohexadiene and maleic acid (cis-2-butenedioic acid). 2. What is the product expected from the reaction of 1,3-butadiene and 3-sulfolene? Why is this not a major concern as a by-product? Part B, the dimer dicyclopentadiene is a possible contaminant of cyclopentadi- ene. It is also a diene. Can dicyclopentadiene undergo reaction with cyclopentadi- ene? Can dicyclopentadiene act as a diene and undergo reaction with the anhydride 3....
You are asked to prepare 500. mL of a 0.100 M acetate buffer at pH 5.00 using only pure acetic acid (MW=60.05 g/mol, pKa=4.76), 3.00 M NaOH, and water. Answer the following questions regarding the preparation of the buffer. 1. How many grams of acetic acid will you need to prepare the 500 mL buffer? Note that the given concentration of acetate refers to the concentration of all acetate species in solution. 2. What volume of 3.00 M NaOH must...
K2CO3 1.5 H20 Br он heat 2,3-dibromocinnamic acid trans-1-bromo-2-phenylethene Compound MW mp (C)bp (C) density (g/ml) mol) 2,3-dibromocinnamic acid 307.97 93-95 (threo) n'a n a 202-204 (erythro)E K CO.1.5H:O1 methylene chloride 138.21 84.93 56.11 891 na n a n'a 39.6 n a n a 1.33 n a 3 MKOH 2. a. What is the by-product formed in this reaction (not shown in given reaction equation)? b. What is the purpose of adding 3 M KOH at the beginning of the...
4-aminophenol (1.0 g) was dissolved in an inert organic solvent. Pyridine (1.50 mL) and acetyl chloride (1.40 mL) were added, and the reaction was stirred until determined to be complete by TLC. Afteworkupup and purification, you isolated 1.40 g of a product. The experimental melting point was 155 oC, and mass spec analysis indicated that the molecular weight of this product is 193.20 g mol─1. What is the structure of the isolated product? Suggest a specific procedural modification that would...
You are asked to prepare 500 ml of a 0 250 M acetate Puffer at pH 5.00 using only pure acetic acid (MW = 60.05 g/mol, pKa = 4.76). 3 00 M NaOH, water. Answer the following questions regarding the preparation of the buffer. How many grams of acetic acid will you need to prepare the 500 mL buffer? Note that the given concentration of acetate refers to the concentration of all acetate species in solution. What volume of 3.00...
8. If the reaction shown was carried out by allowing 7.50 mL of 2,2,3-trimethyl-3-pentano (MW=130.23 g/mol, d 0.857 g/mL) to react with catalytic acid to generate 3,4,4-trimethyl-2-pentene (MW=112.21 g/mol) and water, what is the theoretical yield (in grams) of the alkene product? (15 pts) OH H₂O H3PO4 + 4, 60 min 3,4,4-trimethyl-2-pentene 2,2,3-trimethyl-3-pentano 7. 50mL 15% 857 - 8.75 - 10 150.23 knool 112.215
2 dibenzalacetone acetone benzaldehyde MW- 106.13 g/mol bp-1 78°C d 1.04 g/mL MW 234.30 g/mol mp #110-1110 MW-58.08 g/mol bp 56°C d 0.79 g/mL Its bs Reaction Setup (3 pts) S. OS Initial quantity of NaOH: S. I Initial quantity of benzaldehyde: mL Initial quantity of acetone: mL Theoretical yield of dibenzalacetone based on benzaldehyde: (show calculations) Theoretical yield of dibenzalacetone based on acetone 9 (show calculations) ce tone Limiting Reagent: Product Data (10 pts) fivAL Mass: 3.3g Percent Yield:...
If cyclohexanol(mw 100) (d=0.8 g/ml) were substituted for 2-methylcycholhexanol, only one product, cyclohexane (d=0.8 g/ml) would be obtained. Distillation of the reaction mixture would occur at 85 C. Assume that the vapor pressures of cyclohexane and water are 152 mm and 608 mm respectively at 85 C. If 0.6 mol of water are obtained in the distillate what is the yield of cyclohexane? Assume that the bp of cyclohexane is 100 C and that cyclohexane is insoluble in water? a)...
q1.At the end of this reaction, the procedure asks you to add 10 mL of 2M HCl, what is the purpose of this? Use reaction schemes to illustrate your answer. q2.As part of the workup procedure for this reaction, you are asked to add 10 % NaOH to the aqueous phases before extracting with ethyl acetate. What is the purpose of this? Use structures help illustrate your answer -NH₂ H2N -ΝΗ HN- ОН Amberlyst 15 Ethanol, NaBH4 -OH HO- R...
37) IUPAC name the following structure... Cl A) Ethyl -2-Chlorobenzoate B) Ethyl-2-Chlorobenzoic acid C) Chlorobenzoic acid -2- ethyl D) Methyl-2-Chlorobenzoate E) None of the above 40) What is the major organic product of the reaction shown? ???-(CH2 ) 3-???? +CH3 CH CH3 ?? 0 0 B) CH3-(CH2 ) 3-?-?-??-(CH3)2 0 C) CH3 (CH2 )2 C-O CH (CH3)2 ?? D) CH3-(CH2 ) 3-CH-o-cH-(CH3) 2 49) When an amine reacts with a carboxylic acid at high temperature the major product is A)...