![5. The complex [Cu(CN).]* undergoes tetragonal elongation due to Jahn-Teller distortion Draw the Crystal field splitting diag](http://img.homeworklib.com/questions/a86c6dd0-d6e5-11ea-aa7b-35803d238afc.png?x-oss-process=image/resize,w_560)
Homework Answers
Add Answer to:
5. The complex [Cu(CN).]* undergoes tetragonal elongation due to Jahn-Teller distortion Draw the Crystal field splitting...
Using the crystal field theory approach, draw the d-orbital splitting diagram for octahedral [Cu(...
Using the crystal field theory approach, draw the d-orbital splitting diagram for octahedral [Cu(OH2)6+, properly label each of the orbitals (i.e. dky etc.), and fill in the electrons. Show the changes in energy of all the d-orbitals under the influence of Jahn-Teller distortions resulting in both axial elongation and in axial compression (tetragonal distortions).
Using the crystal field theory approach, draw the d-orbital splitting diagram for octahedral [Cu(OH2)6+, properly label each of the orbitals (i.e. dky etc.), and fill in...
(ii) Explain the Jahn-Teller distortion in [Cu(H2O)2 (ii) If a solution with a dissolved octahedral complex...
(ii) Explain the Jahn-Teller distortion in [Cu(H2O)2 (ii) If a solution with a dissolved octahedral complex appears yellow to the eye, what wavelength of light does it absorb? Is this complex expected to be low spin or high spin?
a. Predict the structure of [Cr(OH2)6]2+ - I wrote that the complex will undergo Jahn-Teller distortion,...
a. Predict the structure of [Cr(OH2)6]2+ - I wrote that the complex will undergo Jahn-Teller distortion, making the octahedral complex become tetragonal (don't know if that's correct) b. Account for the variation in the lattice enthalpy of Mn (2780 kJ/mol), Fe (2926 kJ/mol), Co (2976 kJ/mol), Ni (3060 kJ/mol), and Zn (2985 kJ/mol) flouride given that the metal center in all of the flourides is surrounded by an octahedral array of F-ions. c. Explain the effect on the d-orbital energies...
Would a 5-coordinate trigonal bipyramidal Copper(II) complex exhibit Jahn-Teller distortion?
Would a 5-coordinate trigonal bipyramidal Copper(II) complex exhibit Jahn-Teller distortion?
(8 pts) 13. a. Give the crystal field splitting diagram for the complex ion, [Cr(CN)! with...
(8 pts) 13. a. Give the crystal field splitting diagram for the complex ion, [Cr(CN)! with all d orbitals labeled and correct placement of electrons. b. Is the complex ion paramagnetic or diamagnetic? c. List the compounds in order of increasing wavelength that they would absorb light. (longest 2) (shortest A) [Cr(H2O)6]2. [CMNHJs产 [CrF6]4-, ,
2. a. Draw and show the crystal field splitting of the d orbitals in an octahedral...
2. a. Draw and show the crystal field splitting of the d orbitals in an octahedral complex, a tetrahedral complex, and in a square planar complex.(clearly label the orbitals) b. Explain the difference in the following crystal field splitting values (1) Co(NH3).]2+ 10200 cm"! : [CO(NH3).]* 22,900 cm (ii) [Cr(H20).]** 17,400 cm. ; [Cr(CN).]3-26,600 cm (iii) [MnF6]?- 22,200 cm-"; [ReF.]?- 27,800 cm- (iv) [Co(NH3).]2+ 10,200 cm '; [Co(NH3)4]2+ 5,900 cm c. Draw and show the filling of 6 d electrons...
2.) Starting with the octahedral (ML6) crystal field splitting pattern below: A.) Draw the d-orbital splitting...
2.) Starting with the octahedral (ML6) crystal field splitting pattern below: A.) Draw the d-orbital splitting for a tetragonally compressed compound (ML6). This is where the ligands along the z-axis are pushed closer to the metal center, and the ligands along the x and y-axis are pulled further from the metal center (10 marks). B.) Continue this trend until the ligands along the x and y axes are completely removed, and show the d-orbital splitting for the resulting linear complex...
can anyone please confirm my answers for 5&6? And can you explain how to fill in...
can
anyone please confirm my answers for 5&6? And can you explain
how to fill in the electrons for 7? Please and Thank you.
5. The values of A, for some coordination complexes are given below. (a) [Fe(ox)) --- 14,100 cm-1 (ox-oxalato ligand-----weak ligand] (b) [Fe(CN).-----35,000 cm ©) [Fe(CN)6]* -----33,800 cm (1) Explain reason(s) why A. of complex (a) and (b) are different (ii) Explain reason(s) why 4, of complex (b) and (c) are different 6. Answer the following questions...
4 NCi ICN NC NC CN 5. CN CN CN NC NC 3 For each of...
4 NCi ICN NC NC CN 5. CN CN CN NC NC 3 For each of the complexes above, draw an energy diagram showing the relative energies of the d-orbitals in each complex and fill these orbitals with d-electrons
-Drawing a crystal field theory energy level diagram Using crystal field theory, draw an electron box...
-Drawing a crystal field theory energy level diagram Using crystal field theory, draw an electron box energy level diagram for the valence d orbitals on the vanadium atom in a complex. Your diagram should show the relative energy of each orbital, and the number of electrons in each orbital. Note: to make your diagram easier to read, label the d orbitals with just the subscript. For example, label the d.2 orbital with just z energy
Using the crystal field theory approach, draw the d-orbital splitting diagram for octahedral [Cu(OH2)6+, properly label each of the orbitals (i.e. dky etc.), and fill in the electrons. Show the changes in energy of all the d-orbitals under the influence of Jahn-Teller distortions resulting in both axial elongation and in axial compression (tetragonal distortions).
Using the crystal field theory approach, draw the d-orbital splitting diagram for octahedral [Cu(OH2)6+, properly label each of the orbitals (i.e. dky etc.), and fill in...
(ii) Explain the Jahn-Teller distortion in [Cu(H2O)2 (ii) If a solution with a dissolved octahedral complex appears yellow to the eye, what wavelength of light does it absorb? Is this complex expected to be low spin or high spin?
(8 pts) 13. a. Give the crystal field splitting diagram for the complex ion, [Cr(CN)! with all d orbitals labeled and correct placement of electrons. b. Is the complex ion paramagnetic or diamagnetic? c. List the compounds in order of increasing wavelength that they would absorb light. (longest 2) (shortest A) [Cr(H2O)6]2. [CMNHJs产 [CrF6]4-, ,
2. a. Draw and show the crystal field splitting of the d orbitals in an octahedral complex, a tetrahedral complex, and in a square planar complex.(clearly label the orbitals) b. Explain the difference in the following crystal field splitting values (1) Co(NH3).]2+ 10200 cm"! : [CO(NH3).]* 22,900 cm (ii) [Cr(H20).]** 17,400 cm. ; [Cr(CN).]3-26,600 cm (iii) [MnF6]?- 22,200 cm-"; [ReF.]?- 27,800 cm- (iv) [Co(NH3).]2+ 10,200 cm '; [Co(NH3)4]2+ 5,900 cm c. Draw and show the filling of 6 d electrons...
2.) Starting with the octahedral (ML6) crystal field splitting pattern below: A.) Draw the d-orbital splitting for a tetragonally compressed compound (ML6). This is where the ligands along the z-axis are pushed closer to the metal center, and the ligands along the x and y-axis are pulled further from the metal center (10 marks). B.) Continue this trend until the ligands along the x and y axes are completely removed, and show the d-orbital splitting for the resulting linear complex...
can
anyone please confirm my answers for 5&6? And can you explain
how to fill in the electrons for 7? Please and Thank you.
5. The values of A, for some coordination complexes are given below. (a) [Fe(ox)) --- 14,100 cm-1 (ox-oxalato ligand-----weak ligand] (b) [Fe(CN).-----35,000 cm ©) [Fe(CN)6]* -----33,800 cm (1) Explain reason(s) why A. of complex (a) and (b) are different (ii) Explain reason(s) why 4, of complex (b) and (c) are different 6. Answer the following questions...
4 NCi ICN NC NC CN 5. CN CN CN NC NC 3 For each of the complexes above, draw an energy diagram showing the relative energies of the d-orbitals in each complex and fill these orbitals with d-electrons
-Drawing a crystal field theory energy level diagram Using crystal field theory, draw an electron box energy level diagram for the valence d orbitals on the vanadium atom in a complex. Your diagram should show the relative energy of each orbital, and the number of electrons in each orbital. Note: to make your diagram easier to read, label the d orbitals with just the subscript. For example, label the d.2 orbital with just z energy
Most questions answered within 3 hours.
-
cell in human body reproduces. what process does it use? describe
the steps in the cell...
asked 36 minutes ago -
The cheetah is one of the fastest accelerating animals, for it
can go from rest to...
asked 1 hour ago -
CaCO3 (s) ⇌ CaO (s) + CO2 (g)
At 637 °C, the reaction reaches equilibrium.
If...
asked 2 hours ago -
The condensate from a steam distillation contains 12.0 g of
compound A and 18.0 g of...
asked 5 hours ago -
A major economic benefit of fixed exchange rates compared to
floating rates is that
a. the...
asked 5 hours ago -
1) For this reaction,
SiCl4 (l)+ 2H2O(g) <->
SiO2 (s) + 4HCl (g) DeltaH = -127 KJ...
asked 5 hours ago -
Which of the following does NOT add to US GDP? A. Saudi Arabia
buys fighter jets...
asked 7 hours ago -
2. Describe market equilibrium in terms of the following
characteristics
d.
How supply and demand interactions...
asked 7 hours ago -
1a. Create a class named Computer
- Separate declaration from implementation (i.e. Header and CPP
files)...
asked 7 hours ago -
A medical researcher
believes that a drug changes the body's temperature. Seven test
subjects are randomly...
asked 7 hours ago -
A call option on Project Cash Flow Consulting Inc.'s stock (PCF)
has a market price of...
asked 7 hours ago -
A study on the latest fad diet claimed that the amounts of
weight lost by all...
asked 8 hours ago