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BV HIV What are the major organic products in the following reaction мана сно 2 CPA...
Draw the organic products of the following below reactions Please answer the following questions - 11...
Draw the organic products of the following below
reactions
Please answer the following questions - 11 &12
Slide 10
14. Draw the organic product of the following reactions. NaOH OH SOCl2 OH 800°C OH 11. Why do aldehydes and ketones undergo nucleophilic addition undergo nucleophilic substitution? and carboxylic acid derivatives lain the reactivity trend shown in Slide 10 (acid chlorides>anhydridessestersoamides). Relative Reactivity of Carboxylic Acid Derivatives Substitution in Synthesis Nucleophiles react more readily with unhindered carbonyl groups More electrophilic carbonyl...
1. Predict the major organic products of the following reactions. For each problem you are asked...
1. Predict the major organic products of the following reactions. For each problem you are asked to list factors that you considered in your decisions of what product is made. 1. PBr3 2. OH SNa Collect Information: i. Characteristics of starting material that may be important: ii. Characteristics of reagents in step 1 iii. Characteristics of reagents in step 2 Identify Products Identify possible first steps, follow reaction pathway and draw mechanisms, circle reactive intermediates Distinguishing/Deciding on products Consider regioselectivity,...
Spid deri 7. What is the order of DECREASING reactivity toward nucleophilic acyl substitution for these...
Spid deri 7. What is the order of DECREASING reactivity toward nucleophilic acyl substitution for these carboxylic acid derivatives (most reactive first)? 9. Using your knowledge of organic chemistry, what is the order from most reactive to least reactive of these esters toward a nucleophile? och la NHCH I NHCH 1 2 (a) II, IV, III, I (b) I, II, III, IV (a) 1 > 2 > 3 (b) 3 >1 > 2 (c) 2 > 3 > 1 >2...
Question 31 (2 points) What are the expected major products of the reaction sequence shown below?...
Question 31 (2 points) What are the expected major products of the reaction sequence shown below? 1. O 2. H70 OH o OH 11 III IV v Oa) I and IV ob) I and II oc) I, III and IV od) II, III and IV Question 32 (2 points) Which one of the following dienophiles is least reactive in the Diels-Alder reaction? NO, phony HCO 11 IV Oa) III ob) IV Oc) 1 od) 11
1. What is the IUPAC name for the following molecule? 2. What is the IUPAC name...
1. What is the IUPAC name for the following molecule? 2. What is the IUPAC name for the following molecule? 3. Which of the following is most reactive in nucleophilic acyl substitution reactions? HO 4. What is the major organic product of the following reaction? SOCI2 HO но HS ClI ClI 5. What is the major organic product of the following reaction? CI H2O OH ClI Ho HO HO ClI
What is the major Organic product expected from the following reaction? OH On C1 CH3CH OH...
What is the major Organic product expected from the following reaction? OH On C1 CH3CH OH OCHCH CI (6) (d) OH OH HECH.CO (e) (1) What is the major Organic product of the following sequence of reactions? OH ОН H Br (a) 1) 2 equiv KOH, MOHA 2) HgSOH SOHO Br OH OCH (1) (d) What two products are expected in the following reaction? CH; HB: H H Br CH, CH; CH Вт Н II Br III Bi H H...
9. What is the product of the following reaction? CI O Na o O Na* IV...
9. What is the product of the following reaction? CI O Na o O Na* IV A)I 11 C) 111 D)IV 10. Which of the following substrates cannot be used as an immediate precursor to synthesize an ester? он A) I BII C) III D) Iv 11. Ethyl p-nitrobenzoate is more reactive towards nucleophilic acyl substitution that ethyl p- methyoxybenzoate. Explain this reactivity difference using both words and structures. ес v‘ソ .to nllew nucleerLilit/acyl rubrimin-, Jeer net Criteria for Satisfactory...
Provide the missing reagent or major organic product from the following reaction sequence. Take note of...
Provide the missing reagent or major organic product from the following reaction sequence. Take note of the direction of the arrows. Write only the corresponding letters or numbers in the space provided. If the reagent or product is not available then write NONE. Assume aqueous workup is applied at the end of the reaction except for deprotonation reactions. Br 2 PhMgBr х Dess Martin (CH3)2Culi Y REAGENT BANK A. PBrz, Br2 D. NaOEt, EtOH G. CH3OH B. HBr, Br2 E....
Which is the product from the following reaction? Question 7 Not yet answered Marked out of...
Which is the product from the following reaction? Question 7 Not yet answered Marked out of 1.00 2) H20 Select one: O b. — ОН СН2СН2СН NH2 OH CHỊCHANH Question 8 Not yet answered What is the order of decreasing reactivity toward nucleophilic acyl substitution for these carboxylic acid derivatives (most reactive first)? Marked out of CH3COCH2CH2CCI CHONH, CH3COCCH; Select one: O a. II, IV, Ob.ll, c. IV, I, II, III d. I, II, III, IV
What is the major organic product obtained from the following reaction? Cl2 FeCl3 CHCI IV Multiple...
What is the major organic product obtained from the following reaction? Cl2 FeCl3 CHCI IV Multiple Choice I IV 11 What is the product of the following reaction? KMnO4 OH II III Multiple Choice None of these 11 What is the major organic product of the following reaction? CH3 1. (R)-CBS reagent 2. H20 OH OH HO OH II IV Multiple Choice О IV = Be sure to answer all parts. Give the IUPAC name for the following compound. COOH...
Draw the organic products of the following below
reactions
Please answer the following questions - 11 &12
Slide 10
14. Draw the organic product of the following reactions. NaOH OH SOCl2 OH 800°C OH 11. Why do aldehydes and ketones undergo nucleophilic addition undergo nucleophilic substitution? and carboxylic acid derivatives lain the reactivity trend shown in Slide 10 (acid chlorides>anhydridessestersoamides). Relative Reactivity of Carboxylic Acid Derivatives Substitution in Synthesis Nucleophiles react more readily with unhindered carbonyl groups More electrophilic carbonyl...
1. Predict the major organic products of the following reactions. For each problem you are asked to list factors that you considered in your decisions of what product is made. 1. PBr3 2. OH SNa Collect Information: i. Characteristics of starting material that may be important: ii. Characteristics of reagents in step 1 iii. Characteristics of reagents in step 2 Identify Products Identify possible first steps, follow reaction pathway and draw mechanisms, circle reactive intermediates Distinguishing/Deciding on products Consider regioselectivity,...
Spid deri 7. What is the order of DECREASING reactivity toward nucleophilic acyl substitution for these carboxylic acid derivatives (most reactive first)? 9. Using your knowledge of organic chemistry, what is the order from most reactive to least reactive of these esters toward a nucleophile? och la NHCH I NHCH 1 2 (a) II, IV, III, I (b) I, II, III, IV (a) 1 > 2 > 3 (b) 3 >1 > 2 (c) 2 > 3 > 1 >2...
Question 31 (2 points) What are the expected major products of the reaction sequence shown below? 1. O 2. H70 OH o OH 11 III IV v Oa) I and IV ob) I and II oc) I, III and IV od) II, III and IV Question 32 (2 points) Which one of the following dienophiles is least reactive in the Diels-Alder reaction? NO, phony HCO 11 IV Oa) III ob) IV Oc) 1 od) 11
1. What is the IUPAC name for the following molecule? 2. What is the IUPAC name for the following molecule? 3. Which of the following is most reactive in nucleophilic acyl substitution reactions? HO 4. What is the major organic product of the following reaction? SOCI2 HO но HS ClI ClI 5. What is the major organic product of the following reaction? CI H2O OH ClI Ho HO HO ClI
What is the major Organic product expected from the following reaction? OH On C1 CH3CH OH OCHCH CI (6) (d) OH OH HECH.CO (e) (1) What is the major Organic product of the following sequence of reactions? OH ОН H Br (a) 1) 2 equiv KOH, MOHA 2) HgSOH SOHO Br OH OCH (1) (d) What two products are expected in the following reaction? CH; HB: H H Br CH, CH; CH Вт Н II Br III Bi H H...
9. What is the product of the following reaction? CI O Na o O Na* IV A)I 11 C) 111 D)IV 10. Which of the following substrates cannot be used as an immediate precursor to synthesize an ester? он A) I BII C) III D) Iv 11. Ethyl p-nitrobenzoate is more reactive towards nucleophilic acyl substitution that ethyl p- methyoxybenzoate. Explain this reactivity difference using both words and structures. ес v‘ソ .to nllew nucleerLilit/acyl rubrimin-, Jeer net Criteria for Satisfactory...
Provide the missing reagent or major organic product from the following reaction sequence. Take note of the direction of the arrows. Write only the corresponding letters or numbers in the space provided. If the reagent or product is not available then write NONE. Assume aqueous workup is applied at the end of the reaction except for deprotonation reactions. Br 2 PhMgBr х Dess Martin (CH3)2Culi Y REAGENT BANK A. PBrz, Br2 D. NaOEt, EtOH G. CH3OH B. HBr, Br2 E....
Which is the product from the following reaction? Question 7 Not yet answered Marked out of 1.00 2) H20 Select one: O b. — ОН СН2СН2СН NH2 OH CHỊCHANH Question 8 Not yet answered What is the order of decreasing reactivity toward nucleophilic acyl substitution for these carboxylic acid derivatives (most reactive first)? Marked out of CH3COCH2CH2CCI CHONH, CH3COCCH; Select one: O a. II, IV, Ob.ll, c. IV, I, II, III d. I, II, III, IV
What is the major organic product obtained from the following reaction? Cl2 FeCl3 CHCI IV Multiple Choice I IV 11 What is the product of the following reaction? KMnO4 OH II III Multiple Choice None of these 11 What is the major organic product of the following reaction? CH3 1. (R)-CBS reagent 2. H20 OH OH HO OH II IV Multiple Choice О IV = Be sure to answer all parts. Give the IUPAC name for the following compound. COOH...
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