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write major products for following reaction. (write only one
product unless it has both a 1,2...
4. Write the 1,2 and 1,4 products of addition of HBr to 1,3-hexadiene. Write the complete...
4. Write the 1,2 and 1,4 products of addition of HBr to 1,3-hexadiene. Write the complete stepwise mechanism. Which product is the major if the reaction is taking place at 40°C? (4 points)
Draw the major 1,2- and 1,4-addition products obtained in the reaction shown. Assume that both are...
Draw the major 1,2- and 1,4-addition products obtained in the reaction shown. Assume that both are derived from the most stable carbocation intermediate. +HBr You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. If the 1,2- and 1,4- addition products are the same due to symmetry, only draw one structure. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the +...
Draw the major 1,2-and 1,4-nddition products obtained in the reaction shown Assume that both are derivd...
Draw the major 1,2-and 1,4-nddition products obtained in the reaction shown Assume that both are derivd from the most sable carbocotion HBr You do not have to consider stereochemistry You do not have to explicitly draw H atoms If the 1,2- and 1,4- addition products are the same due to symmetry, only draw one structure . Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottorm night comer Separate multiple products using the+ sign from...
5. (8 pt) Write a mechanism for the reaction shown below. Be sure to draw all...
5. (8 pt) Write a mechanism for the reaction shown below. Be sure to draw all intermediates and BOTH the 1,2- and 1,4-addition products for the reaction. Indicate which product is the THERMODYNAMIC PRODUCT and which is the KINETIC PRODUCT. HBr
2. Write the major organic product expected from each of the following reactions: (120 pts) (a)...
2. Write the major organic product expected from each of the following reactions: (120 pts) (a) CH&CH CH2Br+ NaOH in acetone solvent (b) 1-methylcyclopentene + HCI (c) cyclopentanol+ H2SO4+heat (e) 1-pentyne+H2O H2SO4 (8) benzene + methyl iodide+AICI (i) 2-methyl-1-pentene+ BHo, then HOOH and NaOH () 2-bromobutane + CH,CH,ONa in ethanol (d) 1-pentene + HBr with trace peroxide (f) 1,2-bromopentane + NaNH2 in liquid ammonia (h) ethylbenzene + HNO, + HSO
Alder Re? 9. Draw the two major products for the following reaction. a. Identify each as...
Alder Re? 9. Draw the two major products for the following reaction. a. Identify each as either a 1,2 or 1,4 addition product. b. Write either "thermodynamic" or "kinetic" underneath each one. c. Draw the two resonance structures for the intermediate from which both form H-Br ton nroducts for the following reaction. Draw the the major product or products for the following reaction. Drow the resonance structures for the intermediate from which both form Bra/ hv NBS/ peroxides 11. Give...
ASAP 6.(8) a. The 1,2 addition product of the reaction is shown. Draw the 1,4 addition...
ASAP
6.(8) a. The 1,2 addition product of the reaction is shown. Draw the 1,4 addition product. HBr 1,2 1,4 b. Which is more stable? Circle one: the 1,2 product, the 1.4 product. c. Which product is favored at low temperatures? Circle one: the 1.2 product, the 14 product d. "The proximity effect is used to account for the formation of which product? Circle one: the 1,2 product, the 1.4 product. 7. (5) The pesticide chlordane, sold starting in 1948,...
3. Give the major product for the following reactions. Proper stereochemistry (shape, geometry) is required /...
3. Give the major product for the following reactions. Proper stereochemistry (shape, geometry) is required / chirality may be ignored. Watch out for carbocation rearrangement, and proper geometry like cis/trans. (Be sure to check your work by working out reaction mechanisms - practice, practice, practice!) a. 2-methyl-1-pentene + HBr b. 2-methyl-1-pentene + HBr/peroxide c. 3-methyl-1-pentene + H30+ d. 3-methyl-1-pentene + 1. Hg(OAc)2/ROH 2. NaBH e. 2-methyl-1-pentene + 1. BH3, THF, 2. H202/OH-/H20 f. 3-methyl-1-cyclohexene + Brz, H20 g. 3-methyl-1-cyclohexene +...
[Review Topics) Draw a structural formula for the major organic product of the following reaction: +...
[Review Topics) Draw a structural formula for the major organic product of the following reaction: + Cl2 CH2Cl2 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. If enantiomers are formed, just draw one. @-/ - 000- F Retete Draw a structural formula for the intermediate in the following reaction: che & Biz Chick You do not have to consider stereochemistry. You do...
Acid-catalyzed dehydration of 2,2-dimethylcyclohexanol yields 1,2-dimethylcyclohexene as one of the major products. Write the complete stepwise...
Acid-catalyzed dehydration of 2,2-dimethylcyclohexanol yields 1,2-dimethylcyclohexene as one of the major products. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and show all intermediate structures. ОН CH: CH3
4. Write the 1,2 and 1,4 products of addition of HBr to 1,3-hexadiene. Write the complete stepwise mechanism. Which product is the major if the reaction is taking place at 40°C? (4 points)
Draw the major 1,2- and 1,4-addition products obtained in the reaction shown. Assume that both are derived from the most stable carbocation intermediate. +HBr You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. If the 1,2- and 1,4- addition products are the same due to symmetry, only draw one structure. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the +...
Draw the major 1,2-and 1,4-nddition products obtained in the reaction shown Assume that both are derivd from the most sable carbocotion HBr You do not have to consider stereochemistry You do not have to explicitly draw H atoms If the 1,2- and 1,4- addition products are the same due to symmetry, only draw one structure . Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottorm night comer Separate multiple products using the+ sign from...
5. (8 pt) Write a mechanism for the reaction shown below. Be sure to draw all intermediates and BOTH the 1,2- and 1,4-addition products for the reaction. Indicate which product is the THERMODYNAMIC PRODUCT and which is the KINETIC PRODUCT. HBr
2. Write the major organic product expected from each of the following reactions: (120 pts) (a) CH&CH CH2Br+ NaOH in acetone solvent (b) 1-methylcyclopentene + HCI (c) cyclopentanol+ H2SO4+heat (e) 1-pentyne+H2O H2SO4 (8) benzene + methyl iodide+AICI (i) 2-methyl-1-pentene+ BHo, then HOOH and NaOH () 2-bromobutane + CH,CH,ONa in ethanol (d) 1-pentene + HBr with trace peroxide (f) 1,2-bromopentane + NaNH2 in liquid ammonia (h) ethylbenzene + HNO, + HSO
Alder Re? 9. Draw the two major products for the following reaction. a. Identify each as either a 1,2 or 1,4 addition product. b. Write either "thermodynamic" or "kinetic" underneath each one. c. Draw the two resonance structures for the intermediate from which both form H-Br ton nroducts for the following reaction. Draw the the major product or products for the following reaction. Drow the resonance structures for the intermediate from which both form Bra/ hv NBS/ peroxides 11. Give...
ASAP
6.(8) a. The 1,2 addition product of the reaction is shown. Draw the 1,4 addition product. HBr 1,2 1,4 b. Which is more stable? Circle one: the 1,2 product, the 1.4 product. c. Which product is favored at low temperatures? Circle one: the 1.2 product, the 14 product d. "The proximity effect is used to account for the formation of which product? Circle one: the 1,2 product, the 1.4 product. 7. (5) The pesticide chlordane, sold starting in 1948,...
3. Give the major product for the following reactions. Proper stereochemistry (shape, geometry) is required / chirality may be ignored. Watch out for carbocation rearrangement, and proper geometry like cis/trans. (Be sure to check your work by working out reaction mechanisms - practice, practice, practice!) a. 2-methyl-1-pentene + HBr b. 2-methyl-1-pentene + HBr/peroxide c. 3-methyl-1-pentene + H30+ d. 3-methyl-1-pentene + 1. Hg(OAc)2/ROH 2. NaBH e. 2-methyl-1-pentene + 1. BH3, THF, 2. H202/OH-/H20 f. 3-methyl-1-cyclohexene + Brz, H20 g. 3-methyl-1-cyclohexene +...
[Review Topics) Draw a structural formula for the major organic product of the following reaction: + Cl2 CH2Cl2 • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. If enantiomers are formed, just draw one. @-/ - 000- F Retete Draw a structural formula for the intermediate in the following reaction: che & Biz Chick You do not have to consider stereochemistry. You do...
Acid-catalyzed dehydration of 2,2-dimethylcyclohexanol yields 1,2-dimethylcyclohexene as one of the major products. Write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and show all intermediate structures. ОН CH: CH3
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