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5. In an aldol condensation why must there be an H atom on the alpha carbon...
5) Why is the Aldol reaction often called an Aldol condensation? A) The initially formed b-hydroxy carbonyl compound loses water B) The initially formed b-hydroxy carbonvl compound loses an oxygen atom. C) The initially formed b-hydroxy carbonyl compound loses a hydrogen atom D) The initially formed b-hydroxy carbonyl compound loses a hydroxyl group. 6) When is a crossed Aldol reaction said to be synthetically useful? A) When both carbonyl compounds have a hydrogens B) When one carbonyl compound has no...
Consider the following crossed aldol condensation. Which statement explains why a single cross condensation product is formed? 2,2-dimethylcyclohexanone "CH₃ H₂C, CH, H NaOCH.CH H3C thanol benzaldehyde 2,2-Dimethylcyclohexanone has only one alpha carbon which can form an enolate. Benzaldehyde has no hydrogens attached to the alpha carbon which eliminates the self-condenstation reaction. 2,2-Dimethylcyclohexanone is sterically hindered which limits the self-condenstation reaction. All of the above
5) Draw the Structure of ALL the alpha/beta unsaturated carbon obtained as the dehydration products from the following aldol cond ůco + nsaturated carbonyl products that would be he following aldol condensation: NaOEt 6) The Aldol Condensation below provides only ONE PRODUCT. Provide the structure of the Aldol Dehydration Product and a Full Mechanism to account for its formation. C. –
Question 1 Match each reagent with its role in aldol condensation reaction. Not yet answered D-anisaldehyde Choose... Points out of 10.00 dium hydroxide Choose... P Flag question acetophenone Choose... ethanol Choose... Question 2 Not yet answered To purify the aldol condensation product you will have to recrystallize it from methanol. Give the steps in recrystallization procedure the appropriate order numbering. Points out of 10.00 The compound is kept under vacuum for 10 min Choose... + P Flag question The solution...
The following Aldol Condensation produces a mixture of SIX -alpha, beta-unsaturated carbonyl products. DRAW the structure of all Six the alpha, beta-unsaturated products obtained.
please give correct answer to these 5 questions with
explanations if possible, thankyou
During a nucleophilic addition reaction between LiAlHe and a carbonyl compound, what atom is the nucleophile? Select one The proton (H) atom The hydrogen atom of the lithium aluminium hydride. The aluminium atom. The carbon atom of the carbonyl group. The oxygen atom of the carbonyl group Why do carbonyl compounds undergo nucleophilic addition reactions ? Select one: The compound the carbonyl group is reacting with is...
Which of the following statements about the Aldol reaction is correct. Select all that apply. The aldol condensation reaction requires only a catalytic amount of base to form the a, -unsaturated carbonyl product In an Aldol reaction, the enolate is the electrophile that reacts with a neutral carbonyl nucleophile. Reacting 1 equivalent of LDA (lithium diisopropylamide) with 3-pentanone, the enolate will be formed quantitatively. Two equivalents of a ketone can be reacted with NaOH to form a B-hydroxycarbonyl product. Aldol...
Product was formed successfully based on the exp. below (about
85% yield), please interpret/discuss HNMR/IR in as much detail as
possible and assign peaks on HNMR (which peak represents which
protons of which group, etc). Note: I already know how you
determine the formation of the product so you can skip that part of
part b).
Based on this exp:
Discuss the IR spectrum and what is the peak in IR that you can see for a specific functional group...
QUESTION 1 Which of the following will not undergo an aldol condensation reaction? butanal C 2-methylbutanal C 2,2-dimethylbutanal 3,3-dimethyl-2-butanone QUESTION 2 Which of the following constitutes a difference between an aldol and a Claisen condensation? basic conditions Ctetrahedral intermediate Cenolate ion formation protonation of the intermediate QUESTION 3 The product of an aldol condensation reaction is generally favored if Can unsymmetrical ketone and aldehyde are used Can unsymmetrical ester and ketone are used Cone of the carbonyl partners contains no...
Which one of these carbonyl compounds can not undergo aldol condensation with it self? Organometallic compounds such as CH_3MgBr behave chemically as CH_3^+ CH_3^- CH_3^+ CH_4 Which one of the following will undergo the mass spectral cleavage called the McLafferty rearrangement?