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**WRITTEN WORK** Draw a detailed free energy diagram for the following Snl reaction. Include and label...
Draw a reaction-energy diagram (energy in kJ/mol) for the last step of a free radical substitution mechanism. Label correctly the: - axis (with units of measures, if applicable); - energy levels of reactants, products, transition states and intermediates (if applicable); - activation energy (or energies, if applicable); - heat of reaction (including its sign).
Draw a reaction-energy diagram (energy in kJ/mol) for the last step of a free radical substitution mechanism. Label correctly the: - axis (with units of measures, if applicable); - energy levels of reactants, products, transition states and intermediates (if applicable); - activation energy (or energies, if applicable); - heat of reaction (including its sign).
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8. (9 points) Draw the energy diagram for a spontaneous, exothermic reaction. Label the free energy of activations, the free energy of reaction, the transition states, the intermediate and the correct axis. (8 points) Sketch the mechanism of either: a). The polar addition of HBr to ethylene or b). The three steps of a radical reaction between Cl, and CH
2. Consider the following SNl reaction: H3 CHs CH3 CH3 i. Draw a mechanism using curved arrows. Show all step(s) involved in bond breaking& forming. ii. Draw an energy diagram. Label the axes, the reactants, products, Ea, and AH. Assume that the reaction is exothermic. ili Draw the structure of the intermediate product at the correct position in the energy diagram.
(a) Draw a stepwise, detailed mechanism for the following reaction. Used curved arrows to show the movement of electrons. Br CN NaCN DMF NaBr (b) Assign the configuration (Ror S) of the chiral centre in the substrate and product (c) List the bonds broken and formed in this reaction (d) Assume that this is an endothermic reaction. Draw an energy diagram for this reaction. Label the axes, reactants, products, E, and AH. Draw the structure for both transition states.
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for 7 and its parts, thank you
13. Rate data for the following substitution reaction are presented in the accompanying table. R-L + Nuc→ R-Nuc + L Based on the rate data below, does the substitution reaction above follow an Syl mechanism or an mechanism? SN Trial # (R-L] Nuc" Initial Rate (M/s) 0.1 M 0.1 M 3.1 x 10 2 0.1 M 6.2 x 10 3 0.2 M 0.2...
Choose the correct reaction coordinate diagram for a two-step reaction in which the first step is endergonic, the second step is exergonic, and the overall reaction is endergonic. Pay attention to the reactants, products, intermediates, and transition states A reactants) B = first transition state C = intermediate D = second transition state E =product(s) Free energy Progress of the action A = reactant(s) B = intermediate C = first transition state D = second transition state E = product(s)...
Energy diagrams 7. Draw an energy diagram for the reaction below. Label the axes, reactants, products, intermediates, transition state, AG, AG 5 points D (BC are intermediates!) Step A™B is rate-limiting and A three-reaction where AG®= -13 kJ A B C the energies of the species are C>B> A>D.
2. Draw an energy diagram for the first reaction in problem #1. Label the axis, reactants, products, any intermediates (if needed) and transition states. Than indicate using dotted a line how the diagram would change if CH,CH2OH was used as the solvent instead of acetone. 3. Draw the mechanism showing how the following molecule can best be produced using a SN2 reaction (the molecule shown below is the product, you need to determine the proper reactants (RX and Nu)).
2. Draw a labeled reaction-energy diagram (graph of potential energy versus reaction coordinate) for a three-step overall exothermic reaction with the A. first step being the rate-determining step B. third step being the rate-determining step Label each graph with the following: reactants (r), transition states (ts.), intermediates (int.), products (p). activation energies (Ea), and overall standard heat of reaction (AH). (Note: Each subscript, x, needs to be a number that refers to the appropriate primary mechanistic step. For example, Ea,...