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please help 8. (9 points) Draw the energy diagram for a spontaneous, exothermic reaction. Label the free energy of a...
Draw a reaction-energy diagram (energy in kJ/mol) for the last step of a free radical substitution...
Draw a reaction-energy diagram (energy in kJ/mol) for the last step of a free radical substitution mechanism. Label correctly the: - axis (with units of measures, if applicable); - energy levels of reactants, products, transition states and intermediates (if applicable); - activation energy (or energies, if applicable); - heat of reaction (including its sign).
Draw a reaction-energy diagram (energy in kJ/mol) for the last step of a free radical substitution...
Draw a reaction-energy diagram (energy in kJ/mol) for the last step of a free radical substitution mechanism. Label correctly the: - axis (with units of measures, if applicable); - energy levels of reactants, products, transition states and intermediates (if applicable); - activation energy (or energies, if applicable); - heat of reaction (including its sign).
Draw a labelled reaction coordinate diagram for the both SN reactions. Label the activation energy (free...
Draw a labelled reaction coordinate diagram for the both SN reactions. Label the activation energy (free energy of activation) and give the approximate structures of the intimal state, the transition states, the intermediate and product at the correct points along the reaction coordinate. Also, can you decide on the basis of the kinetic expression whether the t-butyl chloride-hydroxide ion reaction proceeds by a one-step or a two-step mechanism? Explain why observed kinetic expression is consistent with the mechanism you chose.
**WRITTEN WORK** Draw a detailed free energy diagram for the following Snl reaction. Include and label...
**WRITTEN WORK** Draw a detailed free energy diagram for the following Snl reaction. Include and label the overall reactants, the overall products, the intermediate(s), the axis, and the transition state(s). Br C1 Syl HTML Editore n = = X Х D
2. Draw an energy diagram for the first reaction in problem #1. Label the axis, reactants,...
2. Draw an energy diagram for the first reaction in problem #1. Label the axis, reactants, products, any intermediates (if needed) and transition states. Than indicate using dotted a line how the diagram would change if CH,CH2OH was used as the solvent instead of acetone. 3. Draw the mechanism showing how the following molecule can best be produced using a SN2 reaction (the molecule shown below is the product, you need to determine the proper reactants (RX and Nu)).
Give the complete mechanism for the radical chlorination the reaction potential energy diagram below for the...
Give the complete mechanism for the radical chlorination the reaction potential energy diagram below for the reaction from A to X, Answer the following questions: 7 points Reaction 3) Wichstponis a) Indicate the intermediate(s) on the diagram with letters. b) How many transition states are there? c) Clearly show the free energy of activation for each step. d) What is the slowest step of the reaction? e) Which reaction is fastest and exergonic? 1) Which step is fastest and endergonic?...
4. Consider the reaction energy diagram below. Consider the "potential energy" to be equal to enthalpy....
4. Consider the reaction energy diagram below. Consider the "potential energy" to be equal to enthalpy. Potential energy Reaction progress First, indicate on the diagram the activation energy, transition state, and the change of enthalpy for every step of this step-wise process, as well as the change in enthalpy for the overall reaction. Then, answer the following questions: (i) How many elementary steps are there in the mechanism of this reaction? (ii) Which of these steps is the rate-determining step?...
The reaction below proceeds through an exothermic E2 mechanism. Draw the reaction coordinate diagram for this...
The reaction below proceeds through an exothermic E2
mechanism. Draw the reaction coordinate diagram for this reaction,
and label all activation energies, delta Gs, and transition states.
Draw the structures of the starting materials, products, and any
interediates onto your chart where they belong
NaH Br
8.) (10 points) For the two-step reaction of ethylene with HBr to give bromoethane: H BrH...
8.) (10 points) For the two-step reaction of ethylene with HBr to give bromoethane: H BrH Ι H H + HBr - Ι I Draw the plot of potential energy vs. reaction progress, assuming an overall endothermic reaction. Label activation energies (AG), overall AG' value, and transition states. Put the carbocation intermediate in the proper place. Which step is rate-determining and why?
1. Sketeh the energy diagram for a spontaneous second order reaction. Clearly label all axis, the...
1. Sketeh the energy diagram for a spontaneous second order reaction. Clearly label all axis, the rate limiting step, transition state(a), intermediate(s), and enthalpy change. (4pta) Draw the mechanism given the following reaction: 2. (4pta) (3pts) Rank the following in decreasing strength (1-strongest) of the C-halogen bond: 3. 4. Of all halogens we talked about in lecture, which halogen is considered the best leaving group? Explain why (give 2 reasons). (4pts) 5. Rank the following in decreasing nucleophile quality (1-strongest)?...
Draw a reaction-energy diagram (energy in kJ/mol) for the last step of a free radical substitution mechanism. Label correctly the: - axis (with units of measures, if applicable); - energy levels of reactants, products, transition states and intermediates (if applicable); - activation energy (or energies, if applicable); - heat of reaction (including its sign).
**WRITTEN WORK** Draw a detailed free energy diagram for the following Snl reaction. Include and label the overall reactants, the overall products, the intermediate(s), the axis, and the transition state(s). Br C1 Syl HTML Editore n = = X Х D
2. Draw an energy diagram for the first reaction in problem #1. Label the axis, reactants, products, any intermediates (if needed) and transition states. Than indicate using dotted a line how the diagram would change if CH,CH2OH was used as the solvent instead of acetone. 3. Draw the mechanism showing how the following molecule can best be produced using a SN2 reaction (the molecule shown below is the product, you need to determine the proper reactants (RX and Nu)).
Give the complete mechanism for the radical chlorination the reaction potential energy diagram below for the reaction from A to X, Answer the following questions: 7 points Reaction 3) Wichstponis a) Indicate the intermediate(s) on the diagram with letters. b) How many transition states are there? c) Clearly show the free energy of activation for each step. d) What is the slowest step of the reaction? e) Which reaction is fastest and exergonic? 1) Which step is fastest and endergonic?...
4. Consider the reaction energy diagram below. Consider the "potential energy" to be equal to enthalpy. Potential energy Reaction progress First, indicate on the diagram the activation energy, transition state, and the change of enthalpy for every step of this step-wise process, as well as the change in enthalpy for the overall reaction. Then, answer the following questions: (i) How many elementary steps are there in the mechanism of this reaction? (ii) Which of these steps is the rate-determining step?...
The reaction below proceeds through an exothermic E2
mechanism. Draw the reaction coordinate diagram for this reaction,
and label all activation energies, delta Gs, and transition states.
Draw the structures of the starting materials, products, and any
interediates onto your chart where they belong
NaH Br
8.) (10 points) For the two-step reaction of ethylene with HBr to give bromoethane: H BrH Ι H H + HBr - Ι I Draw the plot of potential energy vs. reaction progress, assuming an overall endothermic reaction. Label activation energies (AG), overall AG' value, and transition states. Put the carbocation intermediate in the proper place. Which step is rate-determining and why?
1. Sketeh the energy diagram for a spontaneous second order reaction. Clearly label all axis, the rate limiting step, transition state(a), intermediate(s), and enthalpy change. (4pta) Draw the mechanism given the following reaction: 2. (4pta) (3pts) Rank the following in decreasing strength (1-strongest) of the C-halogen bond: 3. 4. Of all halogens we talked about in lecture, which halogen is considered the best leaving group? Explain why (give 2 reasons). (4pts) 5. Rank the following in decreasing nucleophile quality (1-strongest)?...
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