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Practice Problem ATTEMPT For each of the following. calculate As and identify the process as a...
Chapter 18 Thermodynamics Homework 1.Predict the sign of AS for each process: a) The boiling of water b)2HgO(s)-2Hg(I) + 02(s) c) CaCO, (s)CaO(s)+ CO (g) 2. Is the following process spontaneous o...
Chapter 18 Thermodynamics Homework 1.Predict the sign of AS for each process: a) The boiling of water b)2HgO(s)-2Hg(I) + 02(s) c) CaCO, (s)CaO(s)+ CO (g) 2. Is the following process spontaneous or nonspontaneous at a given temperature? NaNO,(s) ->NaNO,(aq) 3. If a reaction has ΔS < 0 and ΔΗ < 0 will the reaction always be spontaneous, spontaneous at low T, spontaneous at high T, or never spontaneous? 4.Consider this reaction: Calculate ΔG at 25 °C and determine whether the...
please show work and maybe explanations ? Practice Problem 1 Calculate AH and AS for the...
please show work and maybe explanations ?
Practice Problem 1 Calculate AH and AS for the following reaction (the Haber process for the manufacture of ammonia) and calculate if the reaction is favorable at STP. N2(g) + 3 H2(g) 2 NH3(g) (The following information may also be obtained from Appendix C in the Jespersen text.) Compound Enthalpy (kJ/mol) Entropy (J/mol-K) N2(9) H2(g) NH3(g) 0 191.61 130.68 192.45 -46.11 Practice Problem 2 Use the values of AH and AS calculated in...
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a...
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a 2 Mg(s) +,(@) 2 Mgo (s) AS b. CH206(s) → 2C,H,OH(I) + 2003(g) AS c. 2 NH3(g) + CO2(g) → H2O(l) + NH CONH3(aq) AS d. Cu(s) (at 100°C) → Cu(s) (at 25°C) AS 2. Which two variables can indicate if a reaction is spontaneous or not? 3. The second law of thermodynamics tells us that: a Energy is conserved. b. The entropy of...
Information from the appendix is attached: 5. (20 pts) Consider the following reaction OF2(g) + H2O(g)...
Information from the appendix is attached:
5. (20 pts) Consider the following reaction OF2(g) + H2O(g) ---> 2 HF(g) + O2(g) AH (kJ/mole) = -318 kJ/mole (a) Using this information along with data in the appendix of your textbook, calculate AH (OF, (g)) in kJ/mole at 25°C. (b) If 15.0 g of OF2(g) and 10.0 g of H2Og) react, how much heat, expressed in kJ is released? Hint: First calculate the limiting reagent. 6.(20 pts) Consider two Styrofoam coffee cups....
QUESTION 5 Consider the formation of solid silver chloride from aqueous silver and chloride ions. Given...
QUESTION 5
Consider the formation of solid silver chloride from aqueous
silver and chloride ions.
Given the following table of thermodynamic data at 298 K:
The value of K for the reaction at 25 °C is ________.
a)
1.8 × 104
b)
3.7 × 1010
c)
1.9 × 10-10
d)
810
e)
5.3 × 109
QUESTION 6
Consider the reaction:
NH 3 (g) + HCl (g) → NH 4Cl (s)
Given the following table of thermodynamic data,
...
10. Given the following table: Compound NO: (g) N:O (g) AHP (J mol) AGP (J mol) 51.84 33.85 9.66 98.29 For t...
10. Given the following table: Compound NO: (g) N:O (g) AHP (J mol) AGP (J mol) 51.84 33.85 9.66 98.29 For the reaction: N:Oa (g) eo 2NO: (g) (a) Use the information in the Table to calculate AG for the reaction (b) Use the information in the Table to calculate AH" for the reaction (c) Calculate K, at 25 C. (d) Calculate K, at 1600 °C. (Assume AH to be temperature independent) (e) Calculate the degree of dissociation, a, of...
4.In a electrochemical cell consisting of a silver electrode in a solution of AgNO3 and a...
4.In a electrochemical cell consisting of a silver electrode in a solution of AgNO3 and a gold electrode in a solution of Au(NO3)3 at standard conditions, the correct cell potential is 0.70 V b. 2.30 V 0.90 V d. -0.90 V 5. Predict which of the following reactions would exhibit an increase in entropy based on the nature of the reactants and products. 2H2(g) + O2(g) → 2H2O(g) 2NO2(g) → N2O4(g) H+(aq) + F-(aq) → HF(aq) BaF2(s) → Ba2+(aq) +...
20 points 2 Calculate BHOR for 2SO₂ + Na Oy 2503 (9) 100 191) 3 (9)...
20 points 2 Calculate BHOR for 2SO₂ + Na Oy 2503 (9) 100 191) 3 (9) + 2NO(g) THERMODYNAMIC PROPERTIES at 5°C and 1 com gegee999 800 stincc.edu/bbcswebdav/pid-15067640-dt-content-rid-45275191_1/courses/220U-00129-CHEM-1312-006/Pe ELEMENT ΔΗΓ" AS ELEMENT A HP AS OR COMPOUND kJ/mole kJ/molek OR COMPOUND - kJ/mole kJ/mole K AQCI (s) 127.07 0.0962 H2O -241.84 0.1887 AQCN (s) 146.02 0.1072 H,02 -187.78 0.1439 AlBts (s) -$27.18 H₂O2 -136.32 0.2326 AICI -704.17 0.1107 Hys -20.63 0.2059 AIFs - 1505.15 0.0604 Hiso -813.997 0.1500 Alls -314.6...
16.52 Balance each of the following unbalanced equations for cell reactions in acidic conditions, then calculate...
16.52 Balance each of the following unbalanced equations for cell reactions in acidic conditions, then calculate the standard cell emf, and decide whether the equation is written in the direction of spontaneous reaction. (a) Sn2+ (aq) + Ag(s) > Sn(s) + Ag+ (aq) (b) Al(s) + Sn4+ (aq) → Sn²+ (aq) + AP+ (aq) (C) CIO3+ (aq) + Ce3+ (aq) —Cl(aq) + Ce++ (aq) (d) Cu(s) + NO3 (aq) —> Cu2+ (aq) + NO(g) 16 .1 APPENDIX F standard Reduction...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C....
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
Chapter 18 Thermodynamics Homework 1.Predict the sign of AS for each process: a) The boiling of water b)2HgO(s)-2Hg(I) + 02(s) c) CaCO, (s)CaO(s)+ CO (g) 2. Is the following process spontaneous or nonspontaneous at a given temperature? NaNO,(s) ->NaNO,(aq) 3. If a reaction has ΔS < 0 and ΔΗ < 0 will the reaction always be spontaneous, spontaneous at low T, spontaneous at high T, or never spontaneous? 4.Consider this reaction: Calculate ΔG at 25 °C and determine whether the...
please show work and maybe explanations ?
Practice Problem 1 Calculate AH and AS for the following reaction (the Haber process for the manufacture of ammonia) and calculate if the reaction is favorable at STP. N2(g) + 3 H2(g) 2 NH3(g) (The following information may also be obtained from Appendix C in the Jespersen text.) Compound Enthalpy (kJ/mol) Entropy (J/mol-K) N2(9) H2(g) NH3(g) 0 191.61 130.68 192.45 -46.11 Practice Problem 2 Use the values of AH and AS calculated in...
Thermodynamics Practice Problems 1. Predict the sign of AS.(positive or negative) for the following reactions a 2 Mg(s) +,(@) 2 Mgo (s) AS b. CH206(s) → 2C,H,OH(I) + 2003(g) AS c. 2 NH3(g) + CO2(g) → H2O(l) + NH CONH3(aq) AS d. Cu(s) (at 100°C) → Cu(s) (at 25°C) AS 2. Which two variables can indicate if a reaction is spontaneous or not? 3. The second law of thermodynamics tells us that: a Energy is conserved. b. The entropy of...
Information from the appendix is attached:
5. (20 pts) Consider the following reaction OF2(g) + H2O(g) ---> 2 HF(g) + O2(g) AH (kJ/mole) = -318 kJ/mole (a) Using this information along with data in the appendix of your textbook, calculate AH (OF, (g)) in kJ/mole at 25°C. (b) If 15.0 g of OF2(g) and 10.0 g of H2Og) react, how much heat, expressed in kJ is released? Hint: First calculate the limiting reagent. 6.(20 pts) Consider two Styrofoam coffee cups....
QUESTION 5
Consider the formation of solid silver chloride from aqueous
silver and chloride ions.
Given the following table of thermodynamic data at 298 K:
The value of K for the reaction at 25 °C is ________.
a)
1.8 × 104
b)
3.7 × 1010
c)
1.9 × 10-10
d)
810
e)
5.3 × 109
QUESTION 6
Consider the reaction:
NH 3 (g) + HCl (g) → NH 4Cl (s)
Given the following table of thermodynamic data,
...
10. Given the following table: Compound NO: (g) N:O (g) AHP (J mol) AGP (J mol) 51.84 33.85 9.66 98.29 For the reaction: N:Oa (g) eo 2NO: (g) (a) Use the information in the Table to calculate AG for the reaction (b) Use the information in the Table to calculate AH" for the reaction (c) Calculate K, at 25 C. (d) Calculate K, at 1600 °C. (Assume AH to be temperature independent) (e) Calculate the degree of dissociation, a, of...
20 points 2 Calculate BHOR for 2SO₂ + Na Oy 2503 (9) 100 191) 3 (9) + 2NO(g) THERMODYNAMIC PROPERTIES at 5°C and 1 com gegee999 800 stincc.edu/bbcswebdav/pid-15067640-dt-content-rid-45275191_1/courses/220U-00129-CHEM-1312-006/Pe ELEMENT ΔΗΓ" AS ELEMENT A HP AS OR COMPOUND kJ/mole kJ/molek OR COMPOUND - kJ/mole kJ/mole K AQCI (s) 127.07 0.0962 H2O -241.84 0.1887 AQCN (s) 146.02 0.1072 H,02 -187.78 0.1439 AlBts (s) -$27.18 H₂O2 -136.32 0.2326 AICI -704.17 0.1107 Hys -20.63 0.2059 AIFs - 1505.15 0.0604 Hiso -813.997 0.1500 Alls -314.6...
16.52 Balance each of the following unbalanced equations for cell reactions in acidic conditions, then calculate the standard cell emf, and decide whether the equation is written in the direction of spontaneous reaction. (a) Sn2+ (aq) + Ag(s) > Sn(s) + Ag+ (aq) (b) Al(s) + Sn4+ (aq) → Sn²+ (aq) + AP+ (aq) (C) CIO3+ (aq) + Ce3+ (aq) —Cl(aq) + Ce++ (aq) (d) Cu(s) + NO3 (aq) —> Cu2+ (aq) + NO(g) 16 .1 APPENDIX F standard Reduction...
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
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