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tion, 70 pts) 3. (24 pts) Provide the structure(s) of the major product formed in the...
3. (24 pts) Provide the structure(s) of the major product formed in the following reactions. Be...
3. (24 pts) Provide the structure(s) of the major product formed in the following reactions. Be sure to show any significant stereochemical details. (a) 2 1. -OH,H,O 2.H,O", heat (b) ci AICI (C) SH HS H H,SO -OH 1. Na,Cr,O, H,SO4 2. SOCI, pyridine 3. excess (CH,CH2)2NH excess (e)
3. (24 pts) Provide the structure(s) of the major product formed in the following reactions. Be...
3. (24 pts) Provide the structure(s) of the major product formed in the following reactions. Be sure to show any significant stereochemical details. (a) 2 1. -OH, H2O H 2.H20, heat (6) CI AICI: (c ) SH HS H2SO4
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Please draw the structure of product (s) of the following reactions or write "no reaction" if...
Please draw the structure of product (s) of the following
reactions or write "no reaction" if the reaction would not proceed
as written. Circle the major organic product in reactions where
more than one product is formed. (Show stereochemical details where
necessary).
Answer them all. 32, 33 34, 35
32, 33, 34, 35
لا لا Ria و 16 32. Which reagents) would accomplish this conversion? WALL 33. Please draw the structure of product(s) of the following reactions or write "no...
3 (24 pts) Give the structure of the major organic product of each of the following...
3 (24 pts) Give the structure of the major organic product of each of the following reactions, including stereochemistry where appropriate. NaOH methanol-water Он CH-CECH 1. (Sia),BH 2. H,O NaOH OTs NaBr Acetone (OTs Tosylate) NaCN ethanol-water OH Na,Cr,O, H,SO, H,O I н.о H,SO Bra он FeBr NaBH Ethanol
7. Draw the structure of the missing major organic product(s) for each of the following reactions....
7. Draw the structure of the missing major organic product(s) for each of the following reactions. There is no “No Reaction in any of the answers. Show correct stereochemistry when needed! NO ON Na S204 (excess) NaOH, H20, heat Sebacoyl chloride PhCH OH OH (excess) 0 H2SO4, heat Aryl Bromide 1) Mg, THF 2) CH2=0 3) H20, H307 PhCH,CH,OH1 H2SO4 (catalytie) T heat H2Cro (excess)
Provide a chemical structure(s) for the major product in the structure(s) for the major product in...
Provide a chemical structure(s) for the major product in the structure(s) for the major product in the following reactions. If a chiral center is produced please give the correct stereochemical assignment at the chiral center (Q. 14,3 pts ea.). HBT 1. Peroxides HBr HO NaOH HO Eto Nat Br EtOH 5. Show how to convert cyclohexane into racemic 3-bromocyclohexene. Provide all reagents and structures of molecules synthesized along the way. (8 pts).
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following...
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state No Reaction'. H, Pd/C Cl2, hv A) Br CH, OH B) CH3CH2CH2OH H2SO4 D NaBH, CH3CH2OH SOCI TEA H OTS CH,SNa DMSO OH F) OH PCC...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. (24 pts) Provide the structure(s) of the major product formed in the following reactions. Be sure to show any significant stereochemical details. (a) 2 1. -OH,H,O 2.H,O", heat (b) ci AICI (C) SH HS H H,SO -OH 1. Na,Cr,O, H,SO4 2. SOCI, pyridine 3. excess (CH,CH2)2NH excess (e)
3. (24 pts) Provide the structure(s) of the major product formed in the following reactions. Be sure to show any significant stereochemical details. (a) 2 1. -OH, H2O H 2.H20, heat (6) CI AICI: (c ) SH HS H2SO4
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Please draw the structure of product (s) of the following
reactions or write "no reaction" if the reaction would not proceed
as written. Circle the major organic product in reactions where
more than one product is formed. (Show stereochemical details where
necessary).
Answer them all. 32, 33 34, 35
32, 33, 34, 35
لا لا Ria و 16 32. Which reagents) would accomplish this conversion? WALL 33. Please draw the structure of product(s) of the following reactions or write "no...
3 (24 pts) Give the structure of the major organic product of each of the following reactions, including stereochemistry where appropriate. NaOH methanol-water Он CH-CECH 1. (Sia),BH 2. H,O NaOH OTs NaBr Acetone (OTs Tosylate) NaCN ethanol-water OH Na,Cr,O, H,SO, H,O I н.о H,SO Bra он FeBr NaBH Ethanol
7. Draw the structure of the missing major organic product(s) for each of the following reactions. There is no “No Reaction in any of the answers. Show correct stereochemistry when needed! NO ON Na S204 (excess) NaOH, H20, heat Sebacoyl chloride PhCH OH OH (excess) 0 H2SO4, heat Aryl Bromide 1) Mg, THF 2) CH2=0 3) H20, H307 PhCH,CH,OH1 H2SO4 (catalytie) T heat H2Cro (excess)
Provide a chemical structure(s) for the major product in the structure(s) for the major product in the following reactions. If a chiral center is produced please give the correct stereochemical assignment at the chiral center (Q. 14,3 pts ea.). HBT 1. Peroxides HBr HO NaOH HO Eto Nat Br EtOH 5. Show how to convert cyclohexane into racemic 3-bromocyclohexene. Provide all reagents and structures of molecules synthesized along the way. (8 pts).
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state No Reaction'. H, Pd/C Cl2, hv A) Br CH, OH B) CH3CH2CH2OH H2SO4 D NaBH, CH3CH2OH SOCI TEA H OTS CH,SNa DMSO OH F) OH PCC...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
3. Reactions: (21 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state ‘No Reaction'. HI H) 1) CHELI 2) H30 CrOg, H2SO4 H20 (xs) 1) mCPBA J) (CH3),COK (CH3)3COH CH,CI2 K) H2SO4 180°C OH L NaH, DMSO Br...
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