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3. R, S Configurations Assign R, S configurations to each indicated chirality center in the molecules below. 14. OH 15. COOH ---H CH NH2 HỌN H -CH3 HO alanine norepinephrine - 18. 16. HOC / OHH HV CH; НС . H7 HO COH CH2 dihydrocarvone tartaric acid
Assign the R and S configuration at all asymmetric carbons. (The
hydrogen atoms are not shown.)
Incorrect Incorrect Incorrect Question 34 of 52 Map Assign the R and S configuration at all asymmetric carbons. (The hydrogen atoms are not shown) Assign the R and S configuration at all asymmetric carbons. (The hydrogen atoms are not shown.) CH3 CH3 CH2CH3 CH3 CH2CH3 CH3CH2 A rotated in space A ring flipped SR Incorrect. CH2CH3 CH3 CH3 CH2CH3 CH2CH3 diastereomer of B enantiomer...
g. Ph-C(O)-NH2 4 NaOH Br2 h. (HC)2CH-C(CHa)2 -> HO N(CH3)3 i. Ph-N2, CI- + CuCN --> H30* (cat) Na/ETOH j. cyclohexanone+ H2NOH Pd(OAc)2 (1 mole%) k. Ph-I + 4-O2N-C&H4-HC=CH2 Cul/Pd(PPH3)4) L. HO-CH2-CH2-CC-H +1-CH=CH-(CH2)4-CH3
Assign R, S configurations to each indicated chirality center in the molecules below. A. OH B. COOH НО. ---H co CHANH CH; HAN HO H norepinephrine alaine 0 D. C. H E. HOC OH moje H н. CH3 H2C H НО CO H CH2 tartaric acid dihydrocaryone
s. Assign the R or s stereochemistry to the chirality centers in ascorbic acid (vitamin C)? 4pts OH HO HO OH
5. Assign R and S configuration on the following asymmetric C's oo SCNH2 Ho нон Br CH3 B OH
1. Assign R or S configuration to each indicated chirality center (carbon A and B) in the following molecule (vitamin C). Which of the following assignments is correct? но OH HO H. a. carbon A (R); carbon B (S) b. carbon A (R); carbon B (R) c. carbon A (S); carbon B (R) d. carbon A (S); carbon B (S) 2. Erythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. How many chirality centers does erythronolide B have?...
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T CH2 2. ? CH2 he N(CH3)2 O2N HaC CH3 Phosgene, ? (Review a 3. O-CC2 2 CO2H PY ? HaC 4. Нас OH +CH3 NH2 ? H + excess CH30H ? 6. CH(CH2)16 heat b-(CH2)1CH3 heat ? 7. CaHs-C O-CH2 + NH2-OH hydrorylarnine O-
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T...
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CH-CHCH HBr R-O O-R FeBr 2. + Br2 heat 25°C So; conc. H2SO CH3 CI AICI H3C C- 4 CH 5. AICI CHC CI 6. 50-55°C HNO, + H,SO CH3 7. C2 heat or light CH CHCH, HBr 1.DIBAL-H, hexane, -78'C 9. CH C-OCH 2. H,0 CH3 10. light N-Br CC4 1. DIBAL-H, hexane N 2. H2O CH C 11. 1. LIAIH(O-t-Bu), -78°C 12. CH CH2C-Cl 2. H2O 12 Points...
r the recurrence relation o. Consider T(n) = Vn T(Vn) + n a. Why can't you solve this with the master theorem? b. S t involves a constant C, tell me what it is in terms of T(O), T(1), or whatever your inequality by induction. Show the base case. Then show the how that T( n)= 0(n lg ig n). First, clearly indicate the inequality that you wish to hen proceed to prove the inductive hypothesis inductive case, and clearly...