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(4 pts each, unless otherwise noted, 47 pts total) 9-17. Syntheses: draw / provide the likely...
(4 pts each, unless otherwise noted, 45 pts total) 10-18. Syntheses: draw / provide the likely...
(4 pts each, unless otherwise noted, 45 pts total) 10-18. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond(s) formed). Indicate ALL likely products: where one product does not predominate, label / indicate the MAJOR or predominant product(s). Where a product mix results, indicate the MINOR or TRACE...
9-17. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or...
9-17. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond[s] formed). Indicate ALL likely products; where one product does not predominate, label / indicate the MAJOR product(s). Where a product mix results, indicate the MINOR or TRACE product(s). (12 pts) 9. First, exhaustively alkylate, then add Ag20 and...
Organic chemistry mechanisms i need help with systheses questions 6,7,8,9 2-hydroxybenzoic (3 pts) 5. Provide an...
Organic chemistry mechanisms
i need help with systheses questions 6,7,8,9
2-hydroxybenzoic (3 pts) 5. Provide an appropriate structure for: 3,3-dimethylcyclobutanecarbonitrile. (4 pts each, unless otherwise noted, 12 pts total) 6-8. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond(s) formed). Indicate ALL likely products: where one product does...
pts) 9. First, exhaustively alkylate, then add Ag20 and heat. After providing ALL intermediates a products,...
pts) 9. First, exhaustively alkylate, then add Ag20 and heat. After providing ALL intermediates a products, then, name the overall reaction. (Hint: "look left, look right, look top, look bottom." H3C N CH CH,CHI (excess) H
(3 pts each, unless otherwise noted, 17 pts total) 1-5. Nomenclature: provide an acceptable name for...
(3 pts each, unless otherwise noted, 17 pts total) 1-5. Nomenclature: provide an acceptable name for each of the following compounds, but do NOT Google. 1. 2. 3. -CO No HN -CO,H COM 5. (5 pts) Name IUPAC ONLY. i HN-CHE H-C-N(CH)2 (4 pts each, unless otherwise noted, 16 pts total) 6-9. Structures: provide an acceptable structure for: 6. the isobutyl diester of B-bromopimelic acid (5 pts) 7. N-ethyl-B-ethyl-y-valerylactam. 8. benzoic B-chloropropionic anhydride (3 pts) 9. o-bromobenzoyl chloride
3. (a) (35 pts, pts each) Provide All of the organic products for each of the...
3. (a) (35 pts, pts each) Provide All of the organic products for each of the reactions below. If more than one organic product is formed, provide them all and indicate which product is major (where appropriate). Also indicate the stereochemistry (single enantiomer. racemic mixture, meso, etc.) of the products where appropriate. 1 eq HI MeOH heat NaOEt EtOH, heat 1 eq HB +40°C H,SO heat 1. BH; 2. HO, NaOH, H20 NaOme MeOH, heat
) (30 Pts) Provide the structure(s) of the expected major organic product(s). Unless mentioned otherwise, you...
) (30 Pts) Provide the structure(s) of the expected major organic product(s). Unless mentioned otherwise, you can assume that all reagents are present in one mole. Show stereochemistry where needed and write NR if there is no reaction. о ОН E) NaOH, H2O АллОН ОН F) СН2ОНО. ОСН3 H НО H2O, HNO3, 60 °C Н. ОН CH2OH H
help! 18. (2 pts.) The equations for organic reactions usually focus on the desired transformation from...
help!
18. (2 pts.) The equations for organic reactions usually focus on the desired transformation from reactant to product, other possible products such as byproducts and/or side products are often not included, even though it is understood that these are also formed in almost every organic reaction. Shown below is a complete equation for the ester synthesis reaction for the case of 2-pentanol, that includes all possible products, including the desired product, side product(s) and in this case some byproducts...
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following...
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state No Reaction'. H, Pd/C Cl2, hv A) Br CH, OH B) CH3CH2CH2OH H2SO4 D NaBH, CH3CH2OH SOCI TEA H OTS CH,SNa DMSO OH F) OH PCC...
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following...
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. Ha, Pd/C Cl2, hv A) Br CH, OH B) CH3CH,CH, OH H2SO4 D) NaBH "H CH,CH, OH SOCI TEA OTS E) CH SNa DMSO...
(4 pts each, unless otherwise noted, 45 pts total) 10-18. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond(s) formed). Indicate ALL likely products: where one product does not predominate, label / indicate the MAJOR or predominant product(s). Where a product mix results, indicate the MINOR or TRACE...
9-17. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond[s] formed). Indicate ALL likely products; where one product does not predominate, label / indicate the MAJOR product(s). Where a product mix results, indicate the MINOR or TRACE product(s). (12 pts) 9. First, exhaustively alkylate, then add Ag20 and...
Organic chemistry mechanisms
i need help with systheses questions 6,7,8,9
2-hydroxybenzoic (3 pts) 5. Provide an appropriate structure for: 3,3-dimethylcyclobutanecarbonitrile. (4 pts each, unless otherwise noted, 12 pts total) 6-8. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond(s) formed). Indicate ALL likely products: where one product does...
pts) 9. First, exhaustively alkylate, then add Ag20 and heat. After providing ALL intermediates a products, then, name the overall reaction. (Hint: "look left, look right, look top, look bottom." H3C N CH CH,CHI (excess) H
(3 pts each, unless otherwise noted, 17 pts total) 1-5. Nomenclature: provide an acceptable name for each of the following compounds, but do NOT Google. 1. 2. 3. -CO No HN -CO,H COM 5. (5 pts) Name IUPAC ONLY. i HN-CHE H-C-N(CH)2 (4 pts each, unless otherwise noted, 16 pts total) 6-9. Structures: provide an acceptable structure for: 6. the isobutyl diester of B-bromopimelic acid (5 pts) 7. N-ethyl-B-ethyl-y-valerylactam. 8. benzoic B-chloropropionic anhydride (3 pts) 9. o-bromobenzoyl chloride
3. (a) (35 pts, pts each) Provide All of the organic products for each of the reactions below. If more than one organic product is formed, provide them all and indicate which product is major (where appropriate). Also indicate the stereochemistry (single enantiomer. racemic mixture, meso, etc.) of the products where appropriate. 1 eq HI MeOH heat NaOEt EtOH, heat 1 eq HB +40°C H,SO heat 1. BH; 2. HO, NaOH, H20 NaOme MeOH, heat
) (30 Pts) Provide the structure(s) of the expected major organic product(s). Unless mentioned otherwise, you can assume that all reagents are present in one mole. Show stereochemistry where needed and write NR if there is no reaction. о ОН E) NaOH, H2O АллОН ОН F) СН2ОНО. ОСН3 H НО H2O, HNO3, 60 °C Н. ОН CH2OH H
help!
18. (2 pts.) The equations for organic reactions usually focus on the desired transformation from reactant to product, other possible products such as byproducts and/or side products are often not included, even though it is understood that these are also formed in almost every organic reaction. Shown below is a complete equation for the ester synthesis reaction for the case of 2-pentanol, that includes all possible products, including the desired product, side product(s) and in this case some byproducts...
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state No Reaction'. H, Pd/C Cl2, hv A) Br CH, OH B) CH3CH2CH2OH H2SO4 D NaBH, CH3CH2OH SOCI TEA H OTS CH,SNa DMSO OH F) OH PCC...
2. Reactions: (27 pts) Draw the structure of the expected organic product(s) formed in the following reactions including correct stereochemistry, if the product is racemic indicate this by either drawing both enantiomers or drawing one and writing racemic. Assume all reagents listed are present in excess unless otherwise noted. If no reaction occurs, state 'No Reaction'. Ha, Pd/C Cl2, hv A) Br CH, OH B) CH3CH,CH, OH H2SO4 D) NaBH "H CH,CH, OH SOCI TEA OTS E) CH SNa DMSO...
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