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20 3) Propose plausible mechanisms for two of the following four reactions, including arrows to describe...
Propose plauisible mechanisms of the the following reactions, including arrows to describe electron flow and all intermediates CN CH, OH منم a) H2SO4, H2O NH ۔ تی b) NH2 SOBr2 CN c) a NH2 OH HN O
1) Provide structures for A-J in the following roadmap. H NaN LiAIH SOCI, CHINH + B с D- CH,OH (xs) CH,OH E+ A CHOS 1) KOH, H20 2) H,07 NH SOCI 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. CN Oro NaOH H2O are OH
3. Provide step-by-step mechanisms to account for the product of each of the following reactions. Show the structure of each of the intermediates and use curved arrows to indicate electron flow in each of these steps. A. cat. H30 H20 OH B. H20
Extra Credit II 1) Provide structures for A-J in the following roadmap. H NaN, CHANH, LiAIH soa. B D CH,OH (xs) CH, OH E+ А H, A CHO, 1) KOH, H20 2) H30* NH, SOC, 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH
Mechanisms. (2) For each experimental result shown below, propose a step-by-step "electron-pushing" mechanism, using "curly arrows". Show all intermediates (if there are any) explicitly. (a) HCI CI (b) н" +CH OH OCH, OH
3. Provide mechanisms to explain the following reactions. Show all key intermediates and indicat4e electron flow using arrows. осн CH,OH, H H od osty 4 Hoe om o Et d. CH,OH,H", (F980, H H cat. CF,SO3H -Et H2SO4 heat . a n n-1 Et nucleophiles EtOHOEt
1. Give stepwise mechanisms for the following reactions. Clearly show all intermediates and use arrows to show electron movement. - Hop Wow Peonic plure H-Br RO-OR, heat I Br b. R oh solla Red + S02 + Hl- c. Al cu. -CH = CH –O-CH3 Hbg, 4pH OH + HCl. 0 KOEI 1. Nat o Et, Etoh il I 10, EL + C CH₂ OH 2. Hoot TOE 1.HCl, H₂O 2. Et3N, Eto ce U
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH
2. Suggest reasonable mechanisms for each of the following reactions. Use curved arrows to show electron flow. (6) CH, + H2O HO (mixture of stereoisomers) -CH OH
General Organic Chemistry Homework I) Draw mechanisms and products for the following SN2 reactions. Use arrows to show electron movement. The reaction of 1-bromobutane with: a) OH- b) CH,CH2OK Na d) e) NH