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The electronic configuration for boron is 1s22s22p1, and the electronic configuration for aluminum is 1s22s2 2p6 352 3p1. It
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In aluminium the outermost electron is in n=3 state, which is at a larger distance from the nucleus when compared to boron where n=2 state. As distance increased the attractive force between the nucleus and the outermost electron in aluminium is less. Therefore the energy required will be less than 8.298 eV.

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