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Substance s has λmax = 485 nm. Two 50 mL aliquots of an aqueous solution S...

Substance s has λmax = 485 nm. Two 50 mL aliquots of an aqueous solution S are transferred to two different 100 mL volumetric flasks. 25.0 mL of 200.0 ppm S are added to the second flask. Both flasks are then diluted to 100.0 mL with distilled water. At 485 nm, the first flask has A = 0.589 and the second has A = 3.72. Calculate the concentration of S in the original solution.

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