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Question 10 1 pts The bond dissociation energies for the relevant bonds for each species involved...
Bond Dissociation Energies (for A-B Bond broken AH, kJ/mol Bond broken → A A4, kJ/mol + B) Bond broken mo H-H CH3CH2CH2-H (CH3)2CH-H (CH3)3C-H 436 423 413 400. H-Br 366 CH3CH2CH2-Br 294 (CH3)2CH-Br 298 (CH3)3C-Br292 Br-Br 193 H-CI 432 CH3CH2CH2-CI 354 (CH3)2CH-CI 355 (CH3)3C-CI 349 CI-CI 243 Alkane halogenation is a two-step reaction, as shown below. Using the table of bond dissociation energies, calculate the enthalpy of each step and the enthalpy of the overall reaction. Step 1: Number CH3CHCH3...
1. a) Using the bond energies below, calculate the AH 1of the toll willy lealull. Give your answer in units of kilojoules per mole. + HBO ~ + Brz kl/mol 193 Bond Br-Br (CH3),CH-Br - H-CH(CH3)2 H-Br 285 397 368 Calculations: OH =
1. Calculate AH for each reaction using bond dissociation values. Determine if the reaction is exothermic or endothermic a. CH3CH2CH3 + Br2 — CHșCH,CH,-Br + HBr ОН + H₂O + HI 498 297 aaa 720 - 698 - 22 401 andiotamie Table 6.2 Bond Dissociation Energies for Some Common Bonds IA-B - A. + .B] Bond AH kJ/mol (kcal/mol) Bond AH kJ/mol kcal/mol) 456 569 431 H-Z bonds H-F H-CI H-Br H-1 Н-ОН (136) (103) (88) 368 297 498 (71)...
1. Bond Dissociation Energies and Free Radicals Bond Bond Dissociation Energies (kJ/mol) Bond BDE Bond BDE (kJ/mol) (kJ/mol) H-H 436 CH3-H 439 H-F 570 CH3CH2-H 432 H-CI 432 (CH3CH2 413 BDE Bond (kJ/mol) 10-N 350 0-0 180 F-F O-H 0-C O-F 460 BDE (kJ/mol) | 200 180 159 | H-Br H-I 366 298 404 350 O-C1200 O-Br (CH3)3C-H C-C (sigma) C=C(pi) 210 C1-C1243 Br-Br 193 243 0 -I 220 I-I | 151 A. The enzyme methane monooxygenase catalyzes a remarkably...
Calculate the enthalpy of each propagation step and the total enthalpy of reaction for the following transformation. A table of bond dissociation energies is provided for reference. Do not include units in your answer. For example, if the answer is positive one hundred kilojoules per mole, write "+100" only. ∆HP1 = ∆HP2 = ∆HP = Average Bond Dissociation Energies, D (kJ mol) Br-Br 193 R2C-CR2 262 (π bond) H-Br 369 C-H 420 C-O 350 C-C 350 C-Br 285 O-o 180...
H2C=CH2 + CI H2C=CH + HCI Use the table of bond dissociation energies above to calculate AH for this reaction, the first step in the free radical chlorination of ethene. Table of Bond Dissociation Enthalpies Bond BDE (kJ/mol) H2C=CH-H 464 H-I 297 H-Br 368 H-C1 431 H-F 568 ΔΗ: kJ/mol This reaction is:
TABLE 6.1 BOND DISSOCIATION ENERGIES (A) OF COMMON BONDS KJ/MOL KCAL/MOL Bonds to H H2C=CH-CH2 HCC-CH, KJ/MOL KCAL/MOL 385 92 489117 HH 435 80 104 104 KJ/MOL KCAL/MOL 444 106 335 285 222 381 91 (CH3)2CH-F (CH) CH-CI (CH3)2CHBr (CH),CH (CH3)2CH-OH H-CH3 H-CH2CH3 HCH(CH3 H- CH3) 435 104 109 Bonds to methyl CH; CHEF CH3-C1 CH3-Br CH3 CH, OH CH I I 356 85 381 91 HC-c-X CHE (CH3)3C-H (CH3),C-F (CH),C-C1 (CH3)2C-Br (CH3), (CH)C-OH 381 444 331 106 111 464...
Quiz 3 (20 pts) October 30, 2019 CHEM 2401 1. For the following substitution reaction, please (a) calculate the AH endothermic process? (5 pts) . (b) is this reaction an exothermico Сн, H-C-Br сн. & H-OH . H-C-OH сн. H-Br CH3 Bond dissociation energies (CH3)2CH-Br 285 kJ/mol (CH3)2CH-OH 401 kJ/mol H-OH 498 kJ/mol H-Br 368 kJ/mol 2. For the Sn2 reaction depicted below, (a) please form all possible products and (b) draw the mechanism using curved arrow notation that explains...
1. For the following substitution reaction, please (a) calculate the AHran. (b) is this reaction an exothermic or endothermic process? (5 pts) CHE CH3 H-C-Br + H-O-H + H-Br CHE н-с-он сн. Bond dissociation energies (CH3)2CH-Br 285 kJ/mol (CH),CH-OH 401 kJ/mol H-OH 498 kJ/mol H-Br 368 kJ/mol
13. (12 pts) Using the following bond dissociation energies, estimate the enthalpy of the reaction for the reaction between acetylene and hydroiodic acid to generate 1,2-diiodoethane. нн H-CEC-H 2 H- Bond Bond Enthalpy (kJ/mol) Bond Bond Enthalpy (kJ/mol) 839 C-H 413 С-С сс 348 C-I 240 Н-1 299 7