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For each of the following short reaction schemes, draw the structures of the compounds that would...
draw the missing structures for the letters Scheme 1 Br S NaOH CI + A B + С H2N NH2 Scheme 2 1. MCPBA Na2Cr2O7 D E 2. H20, H30+ H30+ Scheme 3 1. LIAIH4 PBr3 F G Н 2. H30+ ether Scheme 4 1. H20, Hg(OAc)2 DMP H I 2. NaBH4 CH2Cl2 Scheme 5 OH tosyl chloride Na J K pyridine ОН
он Choose from the following list of reagents: H2, Lindlar's catalyst PCC, CH2Cl2 1) Br2 2) xs NaNH2 3) H20 1) NaNH2 2) H20 1) BH3 THF 2) H202, NaOH 9 H2CrO4 1) Hg(OAc)2, H20 dilute H2S04 H202, NaOH MCPBA 2) NaBH4 Enter the correct letter for each step of the reaction in the boxes below. (Reagents cannot be used more than once.) Step A: Step B:
NaBH4 CC Hg(OAC)2 H20, THE NaOH 1. Hg(O2CCF3)2, 'ProH 2. NaBH4, NaOH 1. BHz •THF 2. H2O2, HOⓇ R-OH + Nax — NaCN DMSO TSCI pyridine ОН MSCI pyridine NasMe DMSO cat. HA MeOH + g. Arrange in the Increasing acidity order HẠO ROH RC=CH HA NHA RH. cold KMnO4, HOor 1. Os04 2. NaHSO3 MICH3 1. mCPBA 2. H+, CH3OH, H2O 1. mCPBA 2. NaOCH3, H20 H2O / H+ Hg(OAC)2 H2O, THE NaBH4 NaOH 1. BH3 THF 2. HaO2...
Identify the reagents necessary to accomplish the following transformations: Choose from the following list of reagents: 1) xẼ NaNH, 2) H20 10 g-BBN 2) H2O2, NaOH 1) ELMgBr 2) H2O 1) Hg(OAC)2, H20 2) NaBH4 1) TSCI, pyridine 2] -B40k 1) MeMgBr 2) H20 Brz 1) t-BuOK 2) TSCI, pyridine TSCI, pyridine Na2Cr2071) NaBH4 H2SO4, H20 20 H2O2, NaOH PCC, CH2Cl2 Enter the correct letter for each step of the reaction in the boxes below. (Reagents can be used more...
Select the best reagents for each of the following transformations. You should only use each set of reagents once. You can record your answers on this worksheet, or type/write on another sheet of paper. You only need to submit the question number and the letter corresponding to the set of reagents from the table below. H2(g), Pd/C HBr HO" 1) Hg(OAc)2, H2O 1) BH; THF 2) NaBH4 2) H202, NaOH(aq) CH,OH, H+ Br2, CH2Cl2 Br2, H20 MCPBA 1) 03, -78°C...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Don't understand how you get these particular ones. RCO3H y 60,4 ignore stereochemistry NH PCC/CH2Cl2 H pH = 4 1) Mg/Et20 2) HH HOOH H30+ 3) H20+ ignore stereochemistry 1) 03 Она -- 2) Н,0 Конноллон но* Осоон зууны, COOH 1) Br2, PBrz 2) Н,0 но - ден. 1) H,Crод он —2) А „Соонд HOOC 1) V PPh3 2) Os04 3) NaHSO3 4) I /HCI 1) NaOH 2) PCC(excess)/CH2Cl2 3) pH = 4 MNH NH2 h Br 1) Mg/Et,o 2)...
Problem 3 Draw the product from each reaction shown below. OH PCC CH2CL2 - ОН PCC CH2Cl2 NaBH4 EtOH OH 1) LIAIH, Et, 2) H30*
Provide the major organic product (including stereochemistry if appropriate) for each of the following reactions: 3. 1) NaH а) (CH)-СHCH,ОН 2) (CH),СНОСH-CH,Br b) excess HI 1) Hg(OAc),/H,O 2) NaBHĄ/HO¯ 1) NaOH 2) PҺOH d) CH,CH,Br 1) BH3/THF 2) H-0,/Но" НCIZnClz он g) MCPBA h) 1) mCPBA 2) CH3O¯ 1) mCPBA 2) CH,ОН/Н"
1. Predict the product(s) for each of the following reactions: H2SO4 NH2 a. 0 1. H2N-NH2, H2S04, -H20 H 2. KOH/H2O b. MeOH, TsOH он H2O C. H2SO4, -H20 HO d. H2O, H30+ e. H20,H30+ 2. Predict the product and draw the full pushing arrow mechanism for the following reaction NH2 H20,H30+ a. b. 3. Devise an efficient synthesis for the following transformation. HO Br Br