Predict the major products (A, B, C) for the following reactions. t CI A CH2CH2CI AICI:...
Question 2 8 pts Predict the major products (A, B, C) for the following reactions. CI A CH2CH2CI AICI: B excess 1. KMnO4/NaOH/H2O → C 2. H30+ AICI:
Show all work for both please.
1.
2.
Predict the major products (A, B, C) for the following reactions. La A CH2CH2C1 AICI: B excess 1. KMnO4/NaOH/H2O 2. H30* AICI: Predict the major product for the following reaction. Explain why this is the major product and write the reaction mechanism. HNO3/H2SO4
Predict the products of the following reactions.
a.
b.
c.
(1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H30 OCH (1) DIBAL-H (-78 °C) (2) H2O
Predict the products of the following reactions.
a.
b.
c.
(1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H30 OCH (1) DIBAL-H (-78 °C) (2) H2O
2. Predict the products when each of the following compounds is treated with CH,CI/AICI, assume conditions are controlled for mono-alkylation: „„Coor 7. When isopropylbenzene is subjected to the following reactions, the major product that results gives rise to the 1H NMR spectrum below. Using this information, draw the major product of the reaction sequence. 1. SO, H2SO4 2. Chy, FeCly 3. H, H2O
8. Predict the major product or products for the following reactions. Assume reagents are present in excess amounts unless otherwise indicated. Clearly depict any stereochemistry. "No Reaction is a possible answer. (4 points) each So, H2SO4 CH,CH,C1 AICI, NO Br2 FeBry OH 어 CI AICI, FeB NOH 100 °C 2.HO die HCI HO
2. Predict the products of the following Grignard reactions. 1. excess EtMgBr 2. H2O Och3 B. o 1. excess CH3MgCI 2. H30*
predict the major products of the following reactions with
appeopriate stereochemistry
mCPBA lal H2O OH (b) H2SO4 EtOH zo (c) H2SO4 tor Br (d) 1) O₃ lel 2) DMS H₂ (f) PI HTML Editores BIU A- A - IX E 33 x X, TTT 12pt
Predict the product(s) of the following reactions. Only need A, C
and D.
1) HNO3/H2SO4 2) Zn, HCI 3) NaOH (a) Br 1) AICIZ, CI 2) Zn(Hg), HCl, heat 1) CH, CI, AICI 2) KMnO4, H2O, heat 3) H307 1) CH,CI, AICI 2) Excess NBS (d)
Study Pr 3 Predict the major products of the following reactions. (a) 2,4-dinitrochlorobenzene + NaOCH3 (c) nitrobenzene + fuming sulfuric acid (e) p-methylanisole + acetyl chloride AICI, (g) 1,2-dichloro-4-nitrobenzene NaNH2 (i) p-ethyibenzenesulfonic acid +steam/H (b) phenol + tert-butyl chloride + AICl, (d) nitrobenzene + acetyl chloride +AlC1 (f) p-methylanisole + Br2, light (h) p-nitrotoluene + Zn + dilute HCl j) p-ethylbenzenesulfonic acid + HNO3, H2S + hot, concd. KMnO Ph-C-NHPh + CH,CH,-C-CI, AICI3 indane
Study Pr 3 Predict the major...