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The relative volatilities of a quaternary (4-component) mixture are known to be (alpha)21=0.8, (alpha)31=1.0, and (alpha)41=1

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Species 3 have highest mole fraction of vapour phase.

As species 3 have highest relative volatility than all the component's

Since more volatile components have higher vapor pressures than less volatile components so more numbers of vapor will be form and have high mole fraction of vapor phase.

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