Draw the structure of the major organic product of these reactions. Do not write mechanisms. (e)...
Draw the structure of the major organic product of these reactions. Do not write mechanisms. НО. (h) OH + NADH two organic products; write both NH NHA KOH (i) H H20 heat N 1 H (1) O= 오 HT CH3 H, C12H160 (i) (2) PhCH CH Br (3) H20*
Draw the structure of the major organic product of these reactions. Do not write mechanisms. Но. (h) OH NADH two organic products; write both NHANH2 KOH (i) H H2O heat (1) H H+ CH3 () H.C C12H160 (2) PhCH,CH,Br (3) H307
(5) [44 points] Draw the structure of the major organic product of these reactions. Do not write mechanisms. ,,HOH PPh3 (a) + C,H1602 show dash-wedge H2C1 OH DEAD HC (1) C12 H20 (2) NaH H2C dash-wedge all chirality centers (b) нас (3) LiAlH4 (4) H20+ CH3 OH NAD+ (c) two products: show both он HC CH3 (1) PhCOH (d) C11H2002 show a chair conformation (2) CH2OH HT
Draw the structure of the FIRST MAJOR ORGANIC product/intermediate reaction. The generated in each se reactions occur in the text and in the problems at the end of the Chapters a. HsN HCI benzaldehyde] d. R-CO2H NaOH> e. Ph-NH2 + H3OICI> f. Ph-OH NaOH [aniline] [phenol C-H acetylene] h. HC NaH/liquid NH3 > + → 1. H2C-CH2 + HF m. H3C-OH + HI>
1. Draw the structure of the expected major organic product for each of the following five (5) questions Specify stereochemistry clearly. if relevant. a.) NaBH b.) dil. aq. HCI CH CH B. DMP ?? H,C CH C. CrO, OH H,C ag. H SO CH3 CH, OH PBra CH, CH1 OH SOCI CH H,c
(82Give the structure of the major organic product in each of the following reactions. Draw all C-C and C- heterostom bonds. Do not draw C-H, N-H or O-H bonds. Do not use 'C' to label the carbons. Do not draw lone pairs. Draw molecules in zig-zag. (10Pts) 1) NaBH MeOH 2) H. H20 1) NaCN C 2 ) , H2O, A 1) KMnO OH, A 2)H, H2O COOH 1) LIAIHA (excess) 2) H. H20
draw the structure for the major organic product of each of the following reactions. HOTH PHNHNH, 16. CHO HOH (3 equiv.) H-OH HO+H CHOH
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 o 11. 1) PhČCI, AICI 2) EtANH, H2, Raney-Ni, heat 12. ÇO Me 1) EtMgBr (2 equiv.) 2) H20, H30* 13. o CNH2 1) Brą, NaOH, H20 o 2) (CH3)2CHCCI, pyridine 14. CHO HO+H H-OH Br2, H20 H-HOH HO+H CH2OH
2. (16 points) Draw the major organic product for each of the following reactions. Cat - Học =CH -CH3 + H - HH HCCH + Cl2 H . Light c) HC=CH-CH3 + Brz — Acidic + HOH hinga Lito- = OH + HOH 6 two products
1. (24) Write structural formulas for the major organic product(s) for the following reactions. Be sure to indicate the stereochemistry when relevant. HC CH=CH2 H CH,OH CH2OH 1. Na, liq. NH (b) CH,CH.C=CCH CH3 HẠCH, B, P NH, 2.D2, Pt Cl2 HC CCH2CH=CH CH,CH HCC CH,Cl2 1. BH/THF (d) CH,CH,C=CH2 2. H,02, HO", H0 CH -0.47- CH; Br2 excess NaCl 1. 03,-78°C 2. (CH3)2S woboto (h) + Br₂ -