(5) [44 points] Draw the structure of the major organic product of these reactions. Do not...
Complete the following reactions by drawing the structure of the major organic product. ( CH3 mCPBA CH₂O₂ show dash-wedge CH3 (1) LiAlH draw a chair conformation (2) H30+ NaB (CN) Hz H LII2 C5H1N CH2OH solvent
Draw the structure of the major organic product of these reactions. Do not write mechanisms. (e) HAN ht -NH2 HC CH3 (1) Ag OH OH (f) (2) H0+ HO NH2 NaBH (g) H pH 6
Draw the structure of the major organic product of these reactions. Do not write mechanisms. НО. (h) OH + NADH two organic products; write both NH NHA KOH (i) H H20 heat N 1 H (1) O= 오 HT CH3 H, C12H160 (i) (2) PhCH CH Br (3) H20*
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3)3 o 11. 1) PhČCI, AICI 2) EtANH, H2, Raney-Ni, heat 12. ÇO Me 1) EtMgBr (2 equiv.) 2) H20, H30* 13. o CNH2 1) Brą, NaOH, H20 o 2) (CH3)2CHCCI, pyridine 14. CHO HO+H H-OH Br2, H20 H-HOH HO+H CH2OH
Draw the structure of the FIRST MAJOR ORGANIC product/intermediate reaction. The generated in each se reactions occur in the text and in the problems at the end of the Chapters a. HsN HCI benzaldehyde] d. R-CO2H NaOH> e. Ph-NH2 + H3OICI> f. Ph-OH NaOH [aniline] [phenol C-H acetylene] h. HC NaH/liquid NH3 > + → 1. H2C-CH2 + HF m. H3C-OH + HI>
(1) Predict the major organic product of these reactions. In some cases, the formula of the major product is supplied as a hint. Do not write mechanisms. HCO MCPBA C20H1602 (a) show stereochem OH Y OH OH 2-deoxyribose (1) Ag(NH3)2 OH- (2) 1,07 130 (1) CH,Mg I (2) H30+ draw ACX AC a chair (1) NaCN HCN (2) Ni heat + CHCl NaOH + Học CH trans-pent-2-ene show dash-wedge (g)
2. (16 points) Draw the major organic product for each of the following reactions. Cat - Học =CH -CH3 + H - HH HCCH + Cl2 H . Light c) HC=CH-CH3 + Brz — Acidic + HOH hinga Lito- = OH + HOH 6 two products
Draw the major organic product that results from rach of the following reactions. 6. (15 points) in the boxes provided, draw the major organic product that results from each on the following reactions. Include dash/wedge notation to show stereochemistry as appropriate. You are not required to show any mechanisms. (cat.) Nao HO Pt. H2 (neat) H2NNH2, KOH H20 glycol (Wolff-Kishner) ОН KMnO4 H2O/acetone No o Croci (PCC) CH2Cl2
II. Draw the structure for the major organic product of each of the following reactions. 11. Ç(CH3) 30 1) PhČCI, AICI: 2) Et2NH, H2, Raney-Ni, heat 12. ÇO2Me 1) EtMgBr (2 equiv.) 2) H20, H30+ 13. o CNH2 1) Br2, NaOH, H20 O 2) (CH3)2CHČCI, pyridine 14. Br2, H20 CHO HOEH H -OH H-OH HOEH CH2OH
II. Draw the structure for the major organic product of each of the following reactions. (7.5 pts each, 45 pts) Ç(CH3) 30 1) PhČCI, AICI: 11. 2) Et2NH, H2, Raney-Ni, heat 12. ÇO,Me 1) EtMgBr (2 equiv.) 2) H20, H30* O 13. CNH2 1) Bry, NaOH, H,0 O 2) (CH3)2CHCCI, pyridine 14. Brą, H20 CHO HOEH H HOH НЕОН HO+H CH OH 15. H2N. ***** оо CO2 1) (CH3),COCOCOC(CH3)3 2) -N: C: NH- 16. CHO нон PhNHNH2 H+OH (3 equiv.)...