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Question Completion Status: 16 2 36 4 50 60 76 80 96 100 110 120 130 14 Question 2 Which of these compounds would exist prima
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Answer #1

Although mostly keto form is more stable but in some cases enol form is more stable than keto. ​​​​​It depends on number of factors such as: ​​​​​​ 1. Aromaticity- if after formation of enol aromaticity is developed in the molecule then enol will be stable. 2. Hydrogen bond- if any hydrogen bond is formed then enol form is more stable. Apart from these any factor which will stabilize the double bond formed will also shift the reaction towards enol side.

correct option is E, as an aromatic system is formed after enolization. Explaination is provided below:

keto Enol Tautomerism OM It is an a keto equilibrium between form and an enol form. The keto and enol forms are tautomers of

​​​​​​As we can see above the alpha H next to carbonyl is needed for enolization. (a,b,c are possible steps)

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