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The scheme below shows the synthesis of an antihypertensitive agent (drug used to treat high blood...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
b. acid chloride c. ester For each of the terms on the left, provide the best...
b. acid chloride c. ester For each of the terms on the left, provide the best match from the choices on the right. (each choice is only used once). (2@) 1. hydrazone 2. NaBH4 3. lithium dialkylcuprate 4. Haloform reaction 5. hydrazone 6. Li[(t-Bu0)AIH] 7. Trans-esterification 8. Silyl ether 9. Concerted Reaction 10. BH; 11. Arenium ion 12. acetal 13. Wolff-Kishner 14. Acyl substitution 15. DIBAL-H 16. Sandmeyer Reaction 17. Diazotization 18. Wittig Reaction 19. Claisen Condensation __20. Baeyer-Villiger A....
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number...
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
a cari b. acid chloride c. ester For each of the terms on the left, provide...
a cari b. acid chloride c. ester For each of the terms on the left, provide the best match from the choices on the right. (each choice is only used once). (2@) 1. hydrazone 2. NaBH 3. lithium dialkylcuprate 4. Haloform reaction 5. hydrazone 6. Li[(-Bu0);AIH] 7. Trans-esterification 8. Silyl ether 9. Concerted Reaction 10. BH; 11. Arenium ion 12. acetal 13. Wolff-Kishner 14. Acyl substitution 15. DIBAL-H __16. Sandmeyer Reaction _17. Diazotization _18. Wittig Reaction 19. Claisen Condensation 20....
practice questions ③ show the product on products Expected for the reactions below a) + CH₃OH...
practice questions
③ show the product on products Expected for the reactions below a) + CH₃OH alcohol c-c-c aldehyde c-c-c acid C b) 014 + CH3 CH alcohol ÖH c) -10 kmnog LOH heat (Excess) cox - Bonus! 0: CEN: d) -10- H₂ Pd/c. (Excess H2) (Red) H -Bones! e) ÖH ć. + -10 alcohol он acid croch Grid x + CH₃ CH₂ 0 4 (drohol) -10 NH₂ 3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH...
need help, convert them like below pic S. OH- t. 10 w. CIO2 2- X. CO24...
need help, convert them like below pic
S. OH- t. 10 w. CIO2 2- X. CO24 y. HSO3 z. CIO, u. HCO3- v. 104 5. Ionic Compounds with Polyatomic lons & Constant Charge lons a. CaCO3 i. potassium hydroxide b. KCIO j. beryllium hydroxide C. CASO k. strontium acetate d. Li2SO3 I. ammonium oxide e. Ag3PO4 m. silver cyanide f. NH,F n. zinc carbonate g. Al(NO2)3 0. aluminum bicarbonate h. Ba(HCO3)2- p. magnesium phosphate b. NiP04 6. Tonic Compounds with...
Give a detailed mechanism for this reaction and give a separation scheme NUCLEOPHILIC ACYL SUBSTITUTION: Synthesis...
Give a detailed mechanism for this reaction and give a separation
scheme
NUCLEOPHILIC ACYL SUBSTITUTION: Synthesis of an Ester Isoamyl acetate (Banana Oil) Purpose This experiment demonstrat and alcohol. The technique of refluxing the reaction mixture is introduced. es the procedure for the synthesis of an ester from a carboxylic acid Esters are an important functional group in organic chemistry, and esters are found widely distributed in nature. Many lower molecular weight esters are associated with natural fuit flavors and...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
CHEM 242L Exp. 4 Report/ Synthesis of Oil of Wintergreen Name Score: 20 1) Assess the effectivene...
please answer all these questions, thank you.
CHEM 242L Exp. 4 Report/ Synthesis of Oil of Wintergreen Name Score: 20 1) Assess the effectiveness of the experiment and your technique by A) reporting the yield of each step in grams and percent as well as the overall percent yield (What is "overall percent yield?). SHOW ALL CALCULATIONS! B) Give a complete analysis of the identity and purity of your final product and any isolated intermediates 2 What was the purpose...
Based on the document below, 1. Describe the hypothesis Chaudhuri et al ids attempting to evaluate;...
Based on the document below,
1. Describe the hypothesis Chaudhuri et al ids attempting to
evaluate; in other words, what is the goal of this paper? Why is he
writing it?
2. Does the data presented in the paper support the hypothesis
stated in the introduction? Explain.
3.According to Chaudhuri, what is the potential role of thew
alkaline phosphatase in the cleanup of industrial waste.
CHAUDHURI et al: KINETIC BEHAVIOUR OF CALF INTESTINAL ALP WITH PNPP 8.5, 9, 9.5, 10,...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
b. acid chloride c. ester For each of the terms on the left, provide the best match from the choices on the right. (each choice is only used once). (2@) 1. hydrazone 2. NaBH4 3. lithium dialkylcuprate 4. Haloform reaction 5. hydrazone 6. Li[(t-Bu0)AIH] 7. Trans-esterification 8. Silyl ether 9. Concerted Reaction 10. BH; 11. Arenium ion 12. acetal 13. Wolff-Kishner 14. Acyl substitution 15. DIBAL-H 16. Sandmeyer Reaction 17. Diazotization 18. Wittig Reaction 19. Claisen Condensation __20. Baeyer-Villiger A....
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
a cari b. acid chloride c. ester For each of the terms on the left, provide the best match from the choices on the right. (each choice is only used once). (2@) 1. hydrazone 2. NaBH 3. lithium dialkylcuprate 4. Haloform reaction 5. hydrazone 6. Li[(-Bu0);AIH] 7. Trans-esterification 8. Silyl ether 9. Concerted Reaction 10. BH; 11. Arenium ion 12. acetal 13. Wolff-Kishner 14. Acyl substitution 15. DIBAL-H __16. Sandmeyer Reaction _17. Diazotization _18. Wittig Reaction 19. Claisen Condensation 20....
practice questions
③ show the product on products Expected for the reactions below a) + CH₃OH alcohol c-c-c aldehyde c-c-c acid C b) 014 + CH3 CH alcohol ÖH c) -10 kmnog LOH heat (Excess) cox - Bonus! 0: CEN: d) -10- H₂ Pd/c. (Excess H2) (Red) H -Bones! e) ÖH ć. + -10 alcohol он acid croch Grid x + CH₃ CH₂ 0 4 (drohol) -10 NH₂ 3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH...
need help, convert them like below pic
S. OH- t. 10 w. CIO2 2- X. CO24 y. HSO3 z. CIO, u. HCO3- v. 104 5. Ionic Compounds with Polyatomic lons & Constant Charge lons a. CaCO3 i. potassium hydroxide b. KCIO j. beryllium hydroxide C. CASO k. strontium acetate d. Li2SO3 I. ammonium oxide e. Ag3PO4 m. silver cyanide f. NH,F n. zinc carbonate g. Al(NO2)3 0. aluminum bicarbonate h. Ba(HCO3)2- p. magnesium phosphate b. NiP04 6. Tonic Compounds with...
Give a detailed mechanism for this reaction and give a separation
scheme
NUCLEOPHILIC ACYL SUBSTITUTION: Synthesis of an Ester Isoamyl acetate (Banana Oil) Purpose This experiment demonstrat and alcohol. The technique of refluxing the reaction mixture is introduced. es the procedure for the synthesis of an ester from a carboxylic acid Esters are an important functional group in organic chemistry, and esters are found widely distributed in nature. Many lower molecular weight esters are associated with natural fuit flavors and...
18. Draw the structures of Compound 18a. and 18b. (18 pts), clearly indicate your assignments of all proton resonances (8 pts). Calculate the Unsaturation Index of each compound (4 pts) (30 points total) 30 Unsat. Index = (2C+2-H-X+NY2 = 200 25 e = 2.00 ppm, 4.90 f = 1.27 ppm, 20 720 Compound 18a: C,H,O, singlet, 2H triplet, 3H 127 15 d = 2.66 ppm, a = 7.21 ppm, b = 7.18 ppm, doublet, 2H doublet, 2H C = 4.90...
please answer all these questions, thank you.
CHEM 242L Exp. 4 Report/ Synthesis of Oil of Wintergreen Name Score: 20 1) Assess the effectiveness of the experiment and your technique by A) reporting the yield of each step in grams and percent as well as the overall percent yield (What is "overall percent yield?). SHOW ALL CALCULATIONS! B) Give a complete analysis of the identity and purity of your final product and any isolated intermediates 2 What was the purpose...
Based on the document below,
1. Describe the hypothesis Chaudhuri et al ids attempting to
evaluate; in other words, what is the goal of this paper? Why is he
writing it?
2. Does the data presented in the paper support the hypothesis
stated in the introduction? Explain.
3.According to Chaudhuri, what is the potential role of thew
alkaline phosphatase in the cleanup of industrial waste.
CHAUDHURI et al: KINETIC BEHAVIOUR OF CALF INTESTINAL ALP WITH PNPP 8.5, 9, 9.5, 10,...
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