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17) Write the products for the following reactions? 8 PC A) excess CH3OH H2SO4 H B)...
17) Write the products for the following reactions? 8 Pt A) excess CH3OH H2SO4 B) NH2OH H2SO4 Ph3P=CHCH3 D) CH,COOH 18) Predict the steps for the following conversion with proper reagents? (Hint: Protection and deprotection chemistry) 5 Pts ل . لا OCH3 ОН
17) Write the products for the following reactions? 8 Pt A) excess сн,он. H2SO4 B) NH OH H2SO4 - C) Ph3P=CHCH3 i D) CH COOH 18) Predict the steps for the following conversion with proper reagents? (Hint: Protection and deprotection chemistry) 5 Pts осн он 5) Classify the following substituents as ELECTRON DONATING and ELECTRON WITHADRAWING? 3R -NH, -OCH, NO, -CH3 Electron Donating Electron Withdrawing 6) Classify the following compounds AROMATIC, ANTI AROMATIC and NON-AROMATIC? 2 PS con A) 7)...
ORGANIC CHEMISTRY 2:
Using condensed molecular formulas (C#H#X#Y#) for your answers, predict the products of the reactions of C6H5CH2CHO (phenylacetaldehyde) with these reagents, and identify the functional group produced in the product. Note that the Tx symbol above allows you to do a subscript. a. NaBH4 / CH3OH b. 1. CH3MgBr; 2. H20 c. Ph3P=CHCH3 d. CH3CH2OH (excess), H+ e. (CH3)2CHNH2, H+
1. Predict the products of the following reactions. excess NaNH2 THE Br Br H 1. NaNH2 2. CH3CH,Br H2SO4, H20 Hz, Pd/BaSO4 quinoline, CH3OH Na, NH3 1 equivalent HBO NaNH2 Br (excess) 1. Sia,BH, THE 2. H2O2, NaOH HgSO4 H2SO4 H2O
VOX Homework 6 - Chapter 6 1. Predict the products of the following reactions. excess NaNH2 THF Br Br H 1. NaNH, 2. CH CH Br H2SO4 H20 ♡ SOHO H2, Pd/BaSO4 quinoline, CH3OH Na, NH3
8. Predict the major product or products for the following reactions. Assume reagents are present in excess amounts unless otherwise indicated. Clearly depict any stereochemistry. "No Reaction is a possible answer. (4 points) each So, H2SO4 CH,CH,C1 AICI, NO Br2 FeBry OH 어 CI AICI, FeB NOH 100 °C 2.HO die HCI HO
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1. Hg(OAc),/H,0 2. NaBH4 1. BH; 2. H,Oz/NaOH H/Pd H2SO4/H2O 4. Provide the missing reagents or starting materials in the following reactions. OH Br HO 1. Br2 2, NaNH (excess) 3. H2O
Predict the products of the following reactions.
a.
b.
c.
(1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H30 OCH (1) DIBAL-H (-78 °C) (2) H2O
Predict the products of the following reactions.
a.
b.
c.
(1) excess CH Mg! CI (2) H30* (1) DIBAL-H (-78 °C) (2) H30 OCH (1) DIBAL-H (-78 °C) (2) H2O
Predict the products of the following reactions.
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excess NaNH2 THF Br Br H 1. NaNH2 2. CH3CH2Br H2SO4, H20 v MSO. MO H2, Pd/Baso quinoline, CH3OH Na, NH3 Na, NH, 1 equivalent HBr NaNH2 Br (excess) 1. Sia BH, THF 2. H202, NaOH h. HgSO4 H2SO4 H20