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2-When the following compound is treated with sodium hydride (NaH), the major product isolated has the...
2-When the following compound is treated with sodium hydride (NaH), the major product isolated has the formula CsH100. IR spectroscopy reveals no significant diagnostic absorption bands, the proton NMR shows three signals, as does the carbon NMR. Suggest a structure for the product that is consistent with the information above and show a mechanism for its formation. (5 Marks) NaH Br он CSH100 ?
When 5-bromo-1-pentanol is treated with sodium hydride in diethyl ether, the product is analyzed to be C5H10O. Propose a likely structure for this product, suggesting a reasonable mechanistic pathway for its formation. Draw the mechanism of the first step of the reaction. Include ions in the answer. Include all lone pairs in your answer.
1,2,3-Cyclohexanetriol is the major product isolated when an unknown compound is treated with osmium tetroxide in diethyl ether, catalysed by pyridine, followed by potassium hydroxide and mannitol in water. What is the unknown compound? Select one: a. 3-cyclohexen-1-ol b. cyclohexane c. 2-cyclohexen-1-ol d. 2-cyclohexen-1-one e. 2,3-cyclohexadiene If you could draw the mechanism it would be really helpful! Thankyou
Problem #23: When compound X (C,H,Br) is reacted with sodium cyanide (NaCN) forms compound Y (C,H,N). Compound Y, upon reduction with H over a Ni catalyst, yields compound Z (C,HIN. The 'H NMR spectrum of X gives two signals, a multiplet at δ = 7.3 ppm (5H) and a singlet at δ 4.25 ppm (2H). The 'H NMR spectrum of Y is similar to that of X in that it shows a multiplet at ö-7.3 ppm (5H) and a singlet...
2. (a) When the alkene below is treated with HCI, the major product obtained has the chloride on the less substituted carbon. Draw a mechanism for this reaction and provide an explanation for the observed regiochemistry. HCI (b) Provide a mechanism for the following transformation. НBr но- Br (c) Provide a mechanism for the following transformation 2 Он
3a) (5 pts) When 1,2-epoxypropane is treated with sodium ethoxide in ethanol, 1-ethoxy-2-propanol is the major product while only a trace amount of 2-ethoxy-1-propanol is produced. Propose a mechanism for the major product and explain the results based on the mechanism. OH NaOCH2CH3 OH EtOH trace major Hoc
When 3-bromo-2,2-dimethylbutane is treated with potassium tert-butoxide, a single product, A, having the formula C6H12 is formed. When 3,3-dimethyl-2-butanol is treated with sulfuric acid, the major product, B, has the formula C6H12. Given the following NMR data, what are the structures of A and B?Write reactions for the formation of A and B and draw a splitting diagram for the protons at 4.82, 4.93, and 5.83 ppm in compound A1H NMR of A: 1.01 (s, 9H), 4.82 (dd, 1H, J = 10, 1.7 Hz), 4.93 (dd,...
Practice ACS questions: Choose the compound which would be insoluble in aq. sodium hydroxide solution. а) H H -g" aф-о e о a О о This semester you learned about the Grignard reactions of aldehydes and ketones. Which of the following compounds can not be synthesized by the Grignard reaction of the corresponding aldehyde/ketone with EtMgBr followed by acidic work up. (MULTIPLE ANSWER) OCH (A) (D) OH OH OCH2CH3 OH OD ПС ПВ ОА For the following Grignard reaction, select...
50. For the following compound how many different signals would you see in the proton NMR? (Assume that you can see them all.) A) 4 B) 5 C) 6 D) 7 E) 8 . An organic compound absorbs strongly in the IR at 1687 em. Its 'H NMR spectrum consists of two signals, a singlet at 2.1 ppm and a multiplet centered at 7.1 ppm. Its mass spectrum shows significant peaks at m/z 120, m/z 105 and m/z 77. This...
Experiment Write Up Proposal You will write up a synthesis procedure for one reaction that could be potentially run in a face- to-face Chem 2321 lab session. Your proposal will include an introduction and procedure. The procedure will include step-by-step instructions for running the reaction (including reaction monitoring), work-up. (product isolation and purification), and analysis (characterization). You will need to include sample calculations for percent yield and provide sample spectra analysis. You must upload your proposal as a single document...