Lab Report: Determination of Kc for a Complex Ion Formation
| tube | 2.00e-3 Fe3+ (mL) | 2.00E-3M SCN- (mL) | water (mL) | initial conc. Fe3+ | initial conc. SCN- |
| 1 | 5.00 | 5.00 | 0 | 1.00e-3M | 1.00E-3M |
| 2 | 5.00 | 4.00 | 1.00 | 1.00E-3M | 8.00E-3M |
| 3 | 5.00 | 3.00 | 2.00 | 1.00E-3, | 6.00E-3M |
| 4 | 5.00 | 2.00 | 3.00 | 1.00E-3M | 4.00E-3M |
| 5 | 5.00 | 1.00 | 4.00 | 1.00E-3M | 2.00E-3M |
10ml of 0.200M Fe3+, 2.00ml of 0.00200M SCN-, AND 8.00ml of water results in an eq. [FeSCN2+] IN Standard Soln.:2.00E-4M
![Calibration Curve Data (Spectrophotometric Method, Part D) Show a sample dilution calculation for Tube Absorbance [FeSCN] (M](http://img.homeworklib.com/questions/c0f69160-076c-11eb-948f-99058ca581b7.png?x-oss-process=image/resize,w_560)
Could you please explain how to do one calculation of the [FeSCN2+] for the Tubes using 4ml stock solution and 1ml H2O?
The reaction that is assumed to occur in this experiment is: Fe3+ (aq) + SCN– (aq) =FeSCN2+ (aq)
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Lab Report: Determination of Kc for a Complex Ion Formation
tube
2.00e-3 Fe3+ (mL)
2.00E-3M SCN-...
A student made solution #3 using the experimental method in this lab, and measured an absorbance of 0.559. The starting...
A student made solution #3 using the experimental method in this
lab, and measured an absorbance of 0.559. The starting reagents are
2.00 x 10-3 M Fe(NO3)3 and 2.00 x
10-3 M KSCN.
The amount of absorption is proportional to the concentration
of
FeSCN2+. This relationship – true for many solutions – is called
“Beer’s Law”, and has the simple equation:
A = bc
where “A” is the absorption, “b” is 5174.6 for FeSCN2+ and “c”
is molarity
Make Five...
#1, #3, and #5-7 please!!! Pre-Lab Questions 1. Write the balanced chemical equation for the formation...
#1, #3, and #5-7 please!!!
Pre-Lab Questions 1. Write the balanced chemical equation for the formation of FeSCN2" from Fe(NO3)3-9H:0 and NaSCN. 2. In this experiment a dilute solution of 0.1 M HNO is used to maintain the ionic strength and low pH needed for the reaction to occur. How is nitric acid classified in terms of MSDS? What are some of the safety concerns regarding the handling of nitric acid? 3. Look at the procedure for making the standard...
1) Consider the following equilibrium: Fe3+(aq) + SCN-(aq) ⇌ FeSCN2+(aq) Initial concentrations: [Fe3+] = 0.590; [SCN-]...
1) Consider the following equilibrium: Fe3+(aq) + SCN-(aq) ⇌ FeSCN2+(aq) Initial concentrations: [Fe3+] = 0.590; [SCN-] = 1.239; [FeSCN2+] = 0 The equilibrium concentration of [FeSCN2+]eq = 0.454 M. What is the numerical value of KC for this equilibrium? KC = __________________ 2) Consider the following equilibrium: Fe3+(aq) + SCN-(aq) ⇌ FeSCN2+(aq) Initial concentrations: [Fe3+] = 0.370; [SCN-] = 0.777; [FeSCN2+] = 0 The equilibrium concentration of [FeSCN2+]eq = 0.285 M. What is the equilibrium concentration of Fe3+? [Fe3+]eq =...
fill out the chart Lab Notebook Initial concentrations of Feº and SCN KSCN, mL Di water,...
fill out the chart
Lab Notebook Initial concentrations of Feº and SCN KSCN, mL Di water, mL (Fe) Solution Fe(NO3). mL M [SCN] initia M Spectrophotometric determination of (FeSCN) (Calibration curve: A =1269.6c) Solution Measured absorbance Calculated (FeSCN).M alvo Instructions In separate test tubes, make the 5 solutions according to the table below. Then stir each solution. Solution Fe(NO3)3, mL KSCN, mL 2.00 x 10M 2.00 x 10M Dl water, ml 5.0 5.0 0.0 5.0 4.0 1.0 5.0 3.0 2.0...
please help answer questions for mixture 1 AND mixture 2 thank you! Table 23.1 Test Tube...
please help answer questions for mixture 1 AND mixture 2 thank
you!
Table 23.1 Test Tube Number 1 2 3 4 5 5,00 1.00 5.00 2.00 Volume Fe(NO), solution (ml.) Volume KSCN solution (ml.) Volume H,O (ml.) 5.00 3.00 2.00 5.00 4.00 5.00 5.00 0.00 4.00 3.00 1.00 Mixture 2 3 4 5 Absorbance 0.079 0.165 0.246 0.311 0.400 In order to convert the absorbance values provided below into equilibrium concentrations of FeSCN?, you will need to know the slope...
Doing a Chem Review, these are just study scenarios that I need to have a good...
Doing a Chem Review, these are just study scenarios that I need
to have a good understanding of
6. To determine the concentration of SCN in our saliva, we reacted the SCN in the saliva with Fe' according to the following reaction: We measured the absorbance of the FeSCN and used the absorbance value of the FesCN2 to obtain the concentration of the FesCN2*. This was achieved by measuring the absorbance values of standard FeSCN2+ solutions and constructing a calibration...
Show a sample of the ICE table that will be used to calculate Kc. For your...
Show a sample of the ICE table that will be used to calculate Kc. For your example, use the trial one with 2.00 mL of SCN and 5.00 mL of Fets and an arbitrary absorbance value for FeSCN+2 between 0.200 -0.400. (Note: Both reactant stock solutions are 0.00200 M) Hints to consider as you are preparing the ICE table: What is the reaction being investigated? • What is the final volume of the reaction mixture? What are the initial concentrations...
help with calculating the “initial [SCN^—]” M and the Equilibrium [Fe(SCN^2+)] M. i have one. just...
help with calculating the “initial [SCN^—]” M and the Equilibrium
[Fe(SCN^2+)] M.
i
have one. just not sure how to set up the equation to find the
inital [SCN^-] . not sure if im calculating it correctly.
Data Manipulation and Calculations Calibration Solutions Data 1. Calculate the "Initial [SCN']" molarities for the solutions using the dilution equation CiVI=C2V2 2. Use the net ionic equation for the reaction, the ratio of [Fe3 [SCN'] used, and your knowledge of Le Châtelier's Principle...
Procedure 1. Label four 50.0 mL volumetric flasks.)! through 4 2. Using a buret, add 10.00 ml of ...
Procedure 1. Label four 50.0 mL volumetric flasks.)! through 4 2. Using a buret, add 10.00 ml of 2.00x10'MFeNO)D solution to each of the flasks 3. Using a buret, add 1.00 mL. 2.00 mL, 3.00 mL, and 4.00 mL of 2.00x 10 MKSCN 4. Fill each flask to the mark with 0.10 M HNO, solution. Stopper each flask and invert 5. Measure the absorbance of each solution at a wavelength of 447 nm (the absorbance reterred to in step 1...
How do I calculate [SCN-]i given that: Stock [Fe3+] = 0.00200 M Stock [SCN-] = 0.00200...
How do I calculate [SCN-]i given that:
Stock [Fe3+] = 0.00200 M
Stock [SCN-] = 0.00200 M
[Fe+3] [SCN]: of Table 2. Initial Data to Determine Keq Trial Volume Volume Total | Absorbance of Fe+3 volume KSCN(mm) (mm) (mL) hao 5.00 10.00 10.110 | 2 200 5.00 10.00 0.225 3 3.00 5.00 10.00 0.359 4 4.00 5.00 10.00 0.479 5 5.00 5.00 10.00 0.626 11.00×10 -3 2.00x104
A student made solution #3 using the experimental method in this
lab, and measured an absorbance of 0.559. The starting reagents are
2.00 x 10-3 M Fe(NO3)3 and 2.00 x
10-3 M KSCN.
The amount of absorption is proportional to the concentration
of
FeSCN2+. This relationship – true for many solutions – is called
“Beer’s Law”, and has the simple equation:
A = bc
where “A” is the absorption, “b” is 5174.6 for FeSCN2+ and “c”
is molarity
Make Five...
#1, #3, and #5-7 please!!!
Pre-Lab Questions 1. Write the balanced chemical equation for the formation of FeSCN2" from Fe(NO3)3-9H:0 and NaSCN. 2. In this experiment a dilute solution of 0.1 M HNO is used to maintain the ionic strength and low pH needed for the reaction to occur. How is nitric acid classified in terms of MSDS? What are some of the safety concerns regarding the handling of nitric acid? 3. Look at the procedure for making the standard...
fill out the chart
Lab Notebook Initial concentrations of Feº and SCN KSCN, mL Di water, mL (Fe) Solution Fe(NO3). mL M [SCN] initia M Spectrophotometric determination of (FeSCN) (Calibration curve: A =1269.6c) Solution Measured absorbance Calculated (FeSCN).M alvo Instructions In separate test tubes, make the 5 solutions according to the table below. Then stir each solution. Solution Fe(NO3)3, mL KSCN, mL 2.00 x 10M 2.00 x 10M Dl water, ml 5.0 5.0 0.0 5.0 4.0 1.0 5.0 3.0 2.0...
please help answer questions for mixture 1 AND mixture 2 thank
you!
Table 23.1 Test Tube Number 1 2 3 4 5 5,00 1.00 5.00 2.00 Volume Fe(NO), solution (ml.) Volume KSCN solution (ml.) Volume H,O (ml.) 5.00 3.00 2.00 5.00 4.00 5.00 5.00 0.00 4.00 3.00 1.00 Mixture 2 3 4 5 Absorbance 0.079 0.165 0.246 0.311 0.400 In order to convert the absorbance values provided below into equilibrium concentrations of FeSCN?, you will need to know the slope...
Doing a Chem Review, these are just study scenarios that I need
to have a good understanding of
6. To determine the concentration of SCN in our saliva, we reacted the SCN in the saliva with Fe' according to the following reaction: We measured the absorbance of the FeSCN and used the absorbance value of the FesCN2 to obtain the concentration of the FesCN2*. This was achieved by measuring the absorbance values of standard FeSCN2+ solutions and constructing a calibration...
Show a sample of the ICE table that will be used to calculate Kc. For your example, use the trial one with 2.00 mL of SCN and 5.00 mL of Fets and an arbitrary absorbance value for FeSCN+2 between 0.200 -0.400. (Note: Both reactant stock solutions are 0.00200 M) Hints to consider as you are preparing the ICE table: What is the reaction being investigated? • What is the final volume of the reaction mixture? What are the initial concentrations...
help with calculating the “initial [SCN^—]” M and the Equilibrium
[Fe(SCN^2+)] M.
i
have one. just not sure how to set up the equation to find the
inital [SCN^-] . not sure if im calculating it correctly.
Data Manipulation and Calculations Calibration Solutions Data 1. Calculate the "Initial [SCN']" molarities for the solutions using the dilution equation CiVI=C2V2 2. Use the net ionic equation for the reaction, the ratio of [Fe3 [SCN'] used, and your knowledge of Le Châtelier's Principle...
Procedure 1. Label four 50.0 mL volumetric flasks.)! through 4 2. Using a buret, add 10.00 ml of 2.00x10'MFeNO)D solution to each of the flasks 3. Using a buret, add 1.00 mL. 2.00 mL, 3.00 mL, and 4.00 mL of 2.00x 10 MKSCN 4. Fill each flask to the mark with 0.10 M HNO, solution. Stopper each flask and invert 5. Measure the absorbance of each solution at a wavelength of 447 nm (the absorbance reterred to in step 1...
How do I calculate [SCN-]i given that:
Stock [Fe3+] = 0.00200 M
Stock [SCN-] = 0.00200 M
[Fe+3] [SCN]: of Table 2. Initial Data to Determine Keq Trial Volume Volume Total | Absorbance of Fe+3 volume KSCN(mm) (mm) (mL) hao 5.00 10.00 10.110 | 2 200 5.00 10.00 0.225 3 3.00 5.00 10.00 0.359 4 4.00 5.00 10.00 0.479 5 5.00 5.00 10.00 0.626 11.00×10 -3 2.00x104
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