Homework Answers
The compound represented by (d) 3 pentanone is the ketone precursor of the aldol product.
The product formed is 5 ethyl 4 methyl hept-4-en-3-one
The -OH was at the 5th carbon.
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23.3 Give the aldehyde or ketone precursor of the aldol condensation product (a) (b) H (c)...
What is the aldol condensation product of cyclohexanone as the ketone and benzaldehyde as the aldehyde?...
What is the aldol condensation product of cyclohexanone as the ketone and benzaldehyde as the aldehyde? Show the MECHANISM, REACTION, and provide NAME of product.
Match the starting ketone or aldehyde with appropriate product of either aldol addition or adol condensation...
Match the starting ketone or aldehyde with appropriate product
of either aldol addition or adol condensation reaction.
A ketone or an aldehyde from the list undergo either aldol addition (in a case aldol addition product can not undergo further elimination) or aldol condensation reaction in protic solvent under basic catalysis. Match the starting ketone or aldehyde with appropriate product of either aldol addition or aldol condensation reaction propanal acetaldehyde 2-ethyl-2-hydroxy-hexanal 2-methylbuta ethanal Please answer 2-ethyl-4-methyl 2-hexenal Choose 2-methyl-2-pentenal 2-ethyl-3-hydroxy-2,4-dimethyl hexanal...
Be sure to answer all parts. Can the aldol addition product of the aldehyde below undergo an aldol condensation reactio...
Be sure to answer all parts.
Can the aldol addition product of the aldehyde below undergo an
aldol condensation reaction? Why or why not?
If a reaction occurs, draw the structure of the aldol
condensation product. If not, write NR.
Be sure to answer all parts. Can the aldol addition product of the aldehyde below undergo an aldol condensation reaction? Why or why not? If a reaction occurs, draw the structure of the aldol condensation product. If not, write NR....
Identify the electrophilic and nucleophilic carbons. Draw the B-hydroxy product of aldol condensation Draw the dehydration product of aldol condensation CHEMISTRY 204 CONDENSATION REACTIONS WORKSHEET...
Identify the electrophilic and nucleophilic carbons.
Draw the B-hydroxy product of aldol condensation
Draw the dehydration product of aldol condensation
CHEMISTRY 204 CONDENSATION REACTIONS WORKSHEET 1. For each of the reactions below: identify electrophilic and nucleophilic carbons draw the B-hydroxy product of aldol condensation . draw the dehydration product of aldol condensation. OH, H2O heat a) CH3CH2CHCH3CH2CH OH, H2O b) CH3CH2CH CH3CH2CH2CH heat еон, H2O heat CH OH, H2O d) heat CH3CH2CH OCH3, CH3OH H, H20 CH3CCH2CH2CH2CCH3 heat
CHEMISTRY 204...
Draw the aldehyde or ketone that the following enone could be prepared from by the aldol...
Draw the aldehyde or ketone that the following enone could be prepared from by the aldol reaction. TI FI 13 ball & stick labels • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading. • In cases where there is more than one answer, just draw one. С ору P C (1
Question 5 23.5 Draw the structure of the aldol condensation product OH (a) (b) (c) (e)...
Question 5 23.5 Draw the structure of the aldol condensation product OH (a) (b) (c) (e) 23.5 Draw the structure of the aldol condensation product. NaOEt H note-you may find it helpful to number the carbons and/or redraw the molecule
1. Each of the following compounds can be prepared by a mixed aldol condensation reaction. Give...
1. Each of the following compounds can be prepared by a mixed aldol condensation reaction. Give the structures of the aldehyde and/or ketone precursors for each aldol product, identifying the electrophilic partner and nucleophilic partner. (6 Points) Electrophilic partner Nucleophilic partner Electrophilic partner Nucleophilic partner Electrophilic partner Nucleophilic partner
Condensation Reactions Homework (Chapter 19) NAME 1. Explain why aldehyde A is more reactive to nucleophilic...
Condensation Reactions Homework (Chapter 19) NAME 1. Explain why aldehyde A is more reactive to nucleophilic addition reactions than ketone B. 2. Give the curved arrow mechanism for each aldol reaction. est NaOH, H, heat NaOH, H, heat 3. Give the major organic aldol product for each reaction, along with the dehydration produs possible) formed after heating. NaOH H,0 heat NaOH heat HO heat NaOH HO
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving tw...
Organic Chemistry 2
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving two molecules of the same aldehyde or ketone, in the presence of a base, and results in the formation of a new carbon-carbon bond joining the carbonyl carbon of one molecule to the a-position of the second. In many cases - if the reaction conditions aren't sufficiently mild - the initially formed aldol product reacts further in an elimination reaction to give what is...
5a-b 5a. Complete the reaction scheme below to show the self-aldol addition product and the self-aldol...
5a-b
5a. Complete the reaction scheme below to show the self-aldol addition product and the self-aldol condensation product of the ketone shown: Al dol 시d'hon Aldot conunsahe b. Draw the structure of the carbanion formed which leads to the elimination of water in the condensation reaction above, and the arrow push for the loss of hydroxide ion. carbanion, and loss of OH
Match the starting ketone or aldehyde with appropriate product
of either aldol addition or adol condensation reaction.
A ketone or an aldehyde from the list undergo either aldol addition (in a case aldol addition product can not undergo further elimination) or aldol condensation reaction in protic solvent under basic catalysis. Match the starting ketone or aldehyde with appropriate product of either aldol addition or aldol condensation reaction propanal acetaldehyde 2-ethyl-2-hydroxy-hexanal 2-methylbuta ethanal Please answer 2-ethyl-4-methyl 2-hexenal Choose 2-methyl-2-pentenal 2-ethyl-3-hydroxy-2,4-dimethyl hexanal...
Be sure to answer all parts.
Can the aldol addition product of the aldehyde below undergo an
aldol condensation reaction? Why or why not?
If a reaction occurs, draw the structure of the aldol
condensation product. If not, write NR.
Be sure to answer all parts. Can the aldol addition product of the aldehyde below undergo an aldol condensation reaction? Why or why not? If a reaction occurs, draw the structure of the aldol condensation product. If not, write NR....
Identify the electrophilic and nucleophilic carbons.
Draw the B-hydroxy product of aldol condensation
Draw the dehydration product of aldol condensation
CHEMISTRY 204 CONDENSATION REACTIONS WORKSHEET 1. For each of the reactions below: identify electrophilic and nucleophilic carbons draw the B-hydroxy product of aldol condensation . draw the dehydration product of aldol condensation. OH, H2O heat a) CH3CH2CHCH3CH2CH OH, H2O b) CH3CH2CH CH3CH2CH2CH heat еон, H2O heat CH OH, H2O d) heat CH3CH2CH OCH3, CH3OH H, H20 CH3CCH2CH2CH2CCH3 heat
CHEMISTRY 204...
Draw the aldehyde or ketone that the following enone could be prepared from by the aldol reaction. TI FI 13 ball & stick labels • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading. • In cases where there is more than one answer, just draw one. С ору P C (1
Question 5 23.5 Draw the structure of the aldol condensation product OH (a) (b) (c) (e) 23.5 Draw the structure of the aldol condensation product. NaOEt H note-you may find it helpful to number the carbons and/or redraw the molecule
1. Each of the following compounds can be prepared by a mixed aldol condensation reaction. Give the structures of the aldehyde and/or ketone precursors for each aldol product, identifying the electrophilic partner and nucleophilic partner. (6 Points) Electrophilic partner Nucleophilic partner Electrophilic partner Nucleophilic partner Electrophilic partner Nucleophilic partner
Condensation Reactions Homework (Chapter 19) NAME 1. Explain why aldehyde A is more reactive to nucleophilic addition reactions than ketone B. 2. Give the curved arrow mechanism for each aldol reaction. est NaOH, H, heat NaOH, H, heat 3. Give the major organic aldol product for each reaction, along with the dehydration produs possible) formed after heating. NaOH H,0 heat NaOH heat HO heat NaOH HO
Organic Chemistry 2
Experimental Outline In its simplest form, the aldol condensation is a self-addition involving two molecules of the same aldehyde or ketone, in the presence of a base, and results in the formation of a new carbon-carbon bond joining the carbonyl carbon of one molecule to the a-position of the second. In many cases - if the reaction conditions aren't sufficiently mild - the initially formed aldol product reacts further in an elimination reaction to give what is...
5a-b
5a. Complete the reaction scheme below to show the self-aldol addition product and the self-aldol condensation product of the ketone shown: Al dol 시d'hon Aldot conunsahe b. Draw the structure of the carbanion formed which leads to the elimination of water in the condensation reaction above, and the arrow push for the loss of hydroxide ion. carbanion, and loss of OH
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