1. Predict the major product for the following reaction. (12 points) CN Zn(Hg) HCI 1. LIAH...
1. Predict the major product for the following reaction. (12 points) CN Zn(Hg/HCI 1. LIAIHA 2. H3O+ a 1. LIAIH mCPBA NaN3 b 2. H20 + enantiomer С. NH2 N,CI CN COOH d NaCN 1. LIAIHA Br 2. H20 e. (CH3)2NH H2SO4 2. H30*
Which of following is the best starting material for the reaction below? 1. (CH3)2NH ? 2. LIAIHA 3. H20 'N NK CN NH2 What is the major product in the following reaction? 1. DIBAL 2. H20 O H O OH OH СІ Which reaction sequence would accomplish this transformation? CN H2SO4/HNO3 Br2 NaNO2/HCI CuCN O Br2/FeBr3 H2SO4/HNO3 KF NaNO2/HCI O H2SO4/HNO3 Zn(Hg)/HCI NaNO2/HCI CuCN o H2SO4/HNO3 Zn(Hg/HCI NaNO2/HCI HBF4
4. Predict the products for the following reaction sequences. OH H SOCI pyridine (CH3)2NH 1. LIAIHA 2. H20 CH,CH,Br NH2 base (-HBr) CH3Br base (-HBr) o cum, quod cas merea, moms outlet V i har hatteNaensen mCPBA (a) LIAIH4 (b) H20 NaBH,CN NH2 H2SO4
Predict the major product of the following reaction. NH2 1. NaNO2, HCI 2. CuCN NH2 CN NH2 CH_NH2 CN NC IV II -
Draw the major product for each reaction. он. CH3 heat N(CH3)3 a. LiAIH4, Et20 b. H30*/H20 1. NaCN, DMSO Br 2. a. LiAIH4. THF b. H3O+/H2O 1. NaN3, DMSO Br 2. a. LiAIH4, THF b. H3O /H20 1. HNO3, H2SO4 2. SnCl2 3. Br2 4. a. HNO2, H2SO4 H3C b. H2PO2 NH2 1. NaNO2, HCI, H20 но 2. HBF4
What is the major product of the following reaction? NAOH heat X X ger K OH o The best way to synthesize the following amine is: H2N- 1. HNO3 H2SO4 2. Fe, HCI 3. NaOH 1. NaCN Br 2. LiAH, 3. H0 1. Bry. FeBrz 2. NaN 3. H. Ni 1 NBS hr 2 NaNH NHI What is the major product of this reaction! CHU, Hy0°.H20 OH -OH och OH
What is the major product in the following reaction? LiAIHA N ? H2O O Quid O NH2 O NH2 O OH What is the major product in the following reaction? 1. CH31 (excess) ? NH2 2. Ag20, H20, heat HN a Which starting material would most easily be converted to the amide below through nucleophilic acyl substitution? NH2 o H O oll OH What are the best reagents for the following transformation? NH2 NH O2N 1. H2SO4, HNO3 2. CH3COCI,...
Which reaction sequence would accomplish this transformation? CN O H2SO4/HNO3 Zn(Hg)/HCL NaNO2/HCI CuCN H2SO4/HNO3 Zn(Hg)/HCI NaNO2/HCI HBF4 O H2SO4/HNO3 Br2 NaNO/HCI CuCN Br2/FeBr3 H2SO4/HNO3 KE NaNO2/HCI
Write the products of these reactions
-NH2 1. NaNO2, HCI 2. CuCN 1. N(CH3)3 2. Ag20, H20 3.A 1. LAIHA 2. H20 NaN3 1. LATHA 2. H2O NaCN 1. LIAH 2. H20 Br NaCN H. Ni HNO3 H2SO4 NaOH H20 1. NaNO2 HCI 2. HBF 4 CH3 HNO3 Na Cr207 H2SO4 H2SO4 Sn HCI 1. NaNO2 HCI 2. CuCN
Predict the structure of the major product for the following
reaction.
Chicorice CH3CH2CCI Zn (Hg) C. HCT AICI: NH2 II IV