3.a
1. (2 points) Silver ion, Ag+ (aq), oxidizes formaldehyde, CH2O(aq), to formic acid, HCOOH(aq). Write the...
Determine which of the following pairs of reactants will result in a spontaneous Pb2+(aq) + 2 e- - Pb(s) Eº = -0.13 V Cu+(aq) + e- - Cu(s) E = 0.52 V Ag+ (aq) + e Ag(s) Eº = 0.80 V Br2(+2 e 2 Br-(s) E° = 1.09 V reaction at 25°C. Li+(aq) + e- - Li(s) E° = -3.04 V A13+(aq) + 3 e- → Al(s) E° = -1.66 V Fe3+(aq) + 3 e" -> Fe(s) E° = -0.036...
Name: Chem 1120 Electrochemical Potentials Perform each of the following calculations, showing all work. Use the Electrochemical Potentials table provided on D2L if values are not provided. Standard State Electrochemical Cells 1. In each of the following systems two half-reactions are provided. For each system, a) write the balanced reaction occurring for a spontaneous system, and b) calculate the overall standard cell potential. a. Half Reaction Zn2+(aq) + 2e = Zn(s) Cr3+ (aq) + 38 = Cr(s) Eºred (V) -0.76...
Consider the following species. Cut Ce3+ Ag+ Zn2+ What is the standard potential for the reaction of Cut with Zn2+ to produce Cu2+ and Zn? E = 0.28 X v Will Cut be able to reduce Zn2+ to Zn? no (yes or no) What is the standard potential for the reaction of Ce3+ with Ag! to produce Ag? Ex= 0.90 x v Will Cell be able to reduce Ag! to Ag? yes (yer or no) Ered (V) 0.68 0.52 0.40...
2.87 Ered® (V) 0.68 0.52 0.40 0.34 0.16 Half Reaction F,+ 2e →2F Ag* + e → Ag Co3 + e + CO2- H2O2 + 2H+ + 2e → 2H,0 Ce4+ + e → Ce+ PbO, + 4H+ + SO42- + 2e → PbSO, + 2H,0 Mno, + 4H+ + 3e → MnO2 + 2H,0 2e + 2H+ + 10, → 103 + H2O Mn0, +8H+ + 5e → Mn2+ + 4H,0 Aul+ + 3e → Au Cl2 + 2e...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
Use the tabulated electrode potentials to calculate K for the oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g) Express your answer using two significant figures. Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V) Half-reaction E∘ (V) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) −0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) −0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) −0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) −0.76 Cu2+(aq)+2e−→Cu(s) 0.34 Mn2+(aq)+2e−→Mn(s) −1.18 2H+(aq)+2e−→H2(g) 0.00 Al3+(aq)+3e−→Al(s) −1.66 Fe3+(aq)+3e−→Fe(s) −0.036 Mg2+(aq)+2e−→Mg(s) −2.37 Pb2+(aq)+2e−→Pb(s) −0.13 Na+(aq)+e−→Na(s) −2.71 Sn2+(aq)+2e−→Sn(s) −0.14 Ca2+(aq)+2e−→Ca(s) −2.76 Ni2+(aq)+2e−→Ni(s) −0.23 Ba2+(aq)+2e−→Ba(s) −2.90 Co2+(aq)+2e−→Co(s) −0.28 K+(aq)+e−→K(s) −2.92 Cd2+(aq)+2e−→Cd(s)...
Candidate l: Zn(s) | Zn2+(aq,0.500 M) I Cu2+(aq, 1.00 M) Cu(s) Candidate 2: Pb(s) | Pb2+(aq, 0.500 M) || Cu2+(aq, 1.00 M) Cu(s) Candidate 3: Mg(s) | Mg2+(aq, 0.500 M) | Pb2+(aq, 1.00 M)| Pb(s) (a) 6 pts) Choose one of the candidate voltaic cells #1, #2, or #3. Draw a schematic cell diagram for the candidate voltaic cell of choice. Clearly label anode, cathode, electrodes, ions and their concentrations, salt bridge, and the flow of electrons. (b) (5 pts)...
Table provided below for context Please answer all parts that you can. 1. Which electrochemical cell had the greatest voltage? Identify the anode and the cathode for this pair, the measured cell potential, and the calculated Eºcell- 2. Which electrochemical cell had the smallest voltage? Identify the anode and the cathode for this pair, the measured cell potential, and the calculated Eºcell- 3. If the oxidation and reduction half-reactions are separated in a battery, this means the oxidizing agent is...
help with these please, the standard reduction are provided in the last three pictures What is the calculated value of the cell potential at 298K for an electrochemical cell with the following reaction, when the Pb2+ concentration is 9.05X10 M and the AP concentration is 1.48 M? 3Pb2+(aq) + 2Al(s) 3Pb(s) + 2A13+ (aq) Answer: The cell reaction as written above is spontaneous for the concentrations given: What is the calculated value of the cell potential at 298K for an...
Question 7 (1 point) Saved Consider these metal ion/metal standard reduction potentials Cu2(aq)|Cu(s) Ag+1(aq)|Ag(s) Co2(aq)|Co(s) Zn+2(aq)]Zn(s) +0.34 +0.80 V -0.28 V -0.76 V Based on the data above, which one of the species below is the best oxidizing agent? 0 1 Cols) O2) Zn(s) 3) Cutlaq) 04) Culs) 5) Ag+h(aq)