Estimate the Henry’s law constant of TCE using its water solubility and vapor pressure using the temperature dependent values listed below.
MW=131.38g/mol, Water solubility=1.1*10^3mg/L, T=25 degrees cel.
The vapor pressure of water at 298 K is 23.756 mmHg/0.0307 atm
The solublity of the water=henry constant *partial pressure of water.
1.1*10^3mg/L=0.0307 atm*H
henry constant=3.58*10^4 mg/L atm
Estimate the Henry’s law constant of TCE using its water solubility and vapor pressure using the...
Problem 2: a) Find the dimensionless Henry's Law constant for (i) phenanthrene and (ii) TCE (hint: use the solubility and vapor pressure to estimate Henry's law constant). (b) Which compound is more volatile? Justify your answer using the vapor pressure and Henry's constant values. Phenanthrene | TCE Solubility (mol/L) 6.3E-6 | 8.32E-3 Vapor Pressure (atm) | 2.2E-7 9.87E-2
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