Please answer all! VA. Propose a pair of starting materials required for the synthesis of the...
Write the product and a complete arrow-pushing mechanism and propose (the) major product(s) for the following transformation. After a Grignard reaction. .... Each of the Grignard reactions we have studied so far produces an alcohol as the major organic product. Alcohols can be used as starting materials for a number of organic reactions. Use this exercise to consider the range of reactions that can be performed after a Grignard reaction. For each reaction sequence below, suggest a Grignard reagent and...
Please do all parts.
7. Do all parts: a. Starting with benzene propose both a retrosynthesis and a stepwise synthesis for the following compound. (12 points) LOH Br b. Provide a stepwise, curved arrow mechanism points) for the following reaction. (8 AICI3
Please solve all the problem questions
Propose a synthesis for compound with certain the following reagents. Grignard reagent Geranial, citral (3,7-dimethylocta- 2,6-dienal ) OH Product / Identify the complete reaction with all reagents and products in addition to the reaction mechanisms ✓ Reference the bibliography used, (scientific Jounal articles) ✓ Describe step by step the synthesis methodology in laboratory.
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4. Suggest an efficient synthesis of each of the following compounds, starting from the compound indicated and any other needed reagents and solvents. (72 pts) (a) 2-pentanol, from 1-chloropropane (b) 2-butanone, from 2-butanol (c) 1,3,5-tribromobenzene, from benzene (d) benzoic acid, from chlorobenzene (e) benzyl tert-butyl ether (C6H3CH2OC(CH3)3, from benzyl alcohol and tert-butyl alcohol (1) acetyl chloride, from ethanol
Show the most efficient synthesis of the product from the starting material. Show all reagents your need over each arrow, and draw all products and intermediates (do not combine steps). You do not need to show the mechanism for any steps. Show all molecules synthesized along the way, and pay attention to stereochemistry. If a racemic mixture is produced in any step, show both products formed. If you make a mixture of regioisomers in any of the steps, place a...
Be sure to answer all parts. Synthesis of the following compound can be accomplished using 1-bromobutane (CH,CH,CH,CH,Br) as the only organic starting material. Draw the products that result from each of the steps used to synthesize the following compound. Part 1: NaCN view structure Part 2 out of 3 Hot MCN- draw structure ... 3 attempts left Check my work Next part
FOR EACH QUESTION:
1. Why is the wrong answer wrong?
2. Why is the right answer right?
3. Which reaction does each problem involve?
#5 What is the correct starting material for the reaction shown? Wrong Answer A CH,COOH #6 Which combination(s) of organic bromide and carbonyl compound can be used to prepare the alcohol in the box by reaction of the Grignard reagent derived from the alkyl bromide with the carbonyl compound? Wrong Answer B a) only 1 b)...
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NaBH MOH 1.Write two starting materials (five or fewer C's) that react to form the target molecule starting from any carbonyl compound and any organometallic reagent. OH Part IV. Mechanistic Puzzlers (16 pts) 10. Reduction of cyclohexanone using lithium aluminum hydride gives a deuterated alcohol when D.O is used instead of H.O in the workup step. Account for this outcome with a mechanism, showing curved arrows, the key intermediate, and lone pairs and charges. (6 pts)...
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8. Provide an efficient multi-step synthesis of 2 starting with 1. In your forward synthesis, indicate the reagents used for each step by writing them over the arrow leading to cach of the specified products. At some point in your synthesis you must utilize the chemical(s) specified over the arrows. opo maeneo l 5. Draw the major product for each of the following reactions or reaction sequences. Show stereochemistry where appropriate. Assume aqueous workup. 1) Fe, HCI...
Please explain the mechanisms!
1. Propose a synthesis for each of the following problems starting with reagent shown and using any other organic or inorganic reagents allowed in each problem. Multiple steps are required. The number of steps you use does not matter. Reactions should give the desired product as a major product. For full credit show the product of each step (reaction). If you make use of organometallic reagents such as Grignard, Wittig, organolithium, organosodium, organocopper, etc. you must...